Effect of Structure on Water Diffusion in Hydrophilic Polymers

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Abstract:

The relationships between polymer structure and water diffusivity have been investigated in four structural series: amine-epoxyde networks (A), aromatic polysulfones (B), styrene crosslinked polyesters or vinylesters (C) and polyethylenes containing polar groups (D). In each family, it appears water diffusivity is almost inversely proportional to equilibrium water concentration. This result indicates that water diffusion is considerably slowed down by its interactions with polar sites in the polymer.

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Defect and Diffusion Forum (Volumes 258-260)

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442-446

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October 2006

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© 2006 Trans Tech Publications Ltd. All Rights Reserved

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[1] J. A. Barrie: Diffusion in Polymer, J. Crank and G. S. Park eds., chap 8 p.260, Academic Press, London, (1968).

Google Scholar

[2] K. A. Schult, D. R. Paul: J. Polym. Sci. Part B Polym Phys. Vol. 34 (1996), p.2805.

Google Scholar

[3] H. B. Hopfenberg, H. L. Frisch: Polymer letters Vol. 7 (1969), p.405.

Google Scholar

[4] G. S. Springer, B. A. Sanders, K. W. Tung: J. Composite Mater. Vol. 14 (1980), p.213.

Google Scholar

[5] A. Tcharkhtchi, P. Y. Bronnec, J. Verdu: Polymer Vol. 41 (2000), p.5777.

Google Scholar

[6] E. Gaudichet-Maurin : Ph. D thesis, ENSAM, Paris, France, (2005).

Google Scholar

[7] I . Merdas : Ph. Dthesis, ENSAM, Paris, France, (2000).

Google Scholar

[8] S. Neyertz, D. Brown, A. Douanne, C. Bas, N. D. Alberola: J. Phys. Chem B, Vol. 106(8) (2002), p.4617.

Google Scholar

[9] S. Niemelä, S., J. Leppänen, F. Sundholm: Polymer Vol. 37(18) (1996), p.4155.

Google Scholar

[10] V. Bellenger, E. Morel, J. Verdu: J. Mater. Sci. Vol. 24 (1989), p.63.

Google Scholar

[11] E. Gaudichet-Maurin, F. Thominette, J. Verdu : J. Appl. Pol. Sci. Accepted May (2006).

Google Scholar

[12] V. Bellenger, J. Verdu, M. Ganem, B. Mortaigne: Polym Polym. Composites Vol. 2 (1994), p.17.

Google Scholar

[13] V. Bellenger, B. Mortaigne, J. Verdu : J. Appli. Polym. Sci. Vol. 41, (1990), p.1225.

Google Scholar

[14] D. W. McCall, D. C. Douglass, L. L. Blyler Jr., G. E. Johnson, L. W. Jelinski, H. E. Bair: Macromol., Vol. 17 (1984), p.1644.

Google Scholar