Potassium Self-Diffusion in Potassium Bismuth/Rare Earth Molybdate Crystals

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Abstract:

The anisotropy of self-diffusion of K+ ions, ionic conductivity, and static permittivity in stoichiometric disordered K5Bi1-xRx(MoO4)4 (R = Nd, Gd; x = 0, 0.92, 1) single crystals is studied. A high value of the 2-D diffusion and ionic conductivity by K+ ions is detected. The fast ionic transport is parallel to the double layers formed by MoO4 tetrahedrons.

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Periodical:

Defect and Diffusion Forum (Volumes 283-286)

Pages:

161-165

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Online since:

March 2009

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© 2009 Trans Tech Publications Ltd. All Rights Reserved

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