Photoresponsive Nano-Coumarin with Indole Auxin Hormone

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In this work, we designed and synthesized two photoresponsive materials with 3-indoleacetic acid (IAA) plant hormone which can be monitored from the photoreposive properties of coumarin. The varied position of the long alkoxy side chain (-OC16H33) was purposely introduced to adhesive on the plant leaves. Two coumarin-caged nanomaterials showed average particle diameter about 400 nm and gave the maximum emission wavelength at 425 and 450 nm. The formulated nanoemulsion showed good wettability (θ=48o) with Cassia fistula leave surface. Interestingly, CM2 gave the short photoresponse of photolysis within one day.

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26-30

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November 2017

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© 2017 Trans Tech Publications Ltd. All Rights Reserved

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[1] Information on http: /www. doa. go. th/ard.

Google Scholar

[2] A. Jana, B. Saha, D.R. Banerjee, S.K. Ghosh, K.T. Nguyen, X. Ma, Q. Qu, Y. Zhao, N.P. Singh, Photocontrolled Nuclear-Targeted Drug Delivery by Single Component Photoresponsive Fluorescent Organic Nanoparticles of Acridin-9-Methanol, Bioconjugate Chem. 24 (2013).

DOI: 10.1021/bc400170r

Google Scholar

[3] A. Jana, K.S.P. Devi, T.K. Maiti, N.P. Singh, Perylene-3-ylmethanol: Fluorescent Organic Nanoparticles as a Single-Component Photoresponsive Nanocarrier with Real Time Monitoring of Anticancer Drug Release, J. Am. Chem. Soc. 134 (2012) 7656-7659.

DOI: 10.1021/ja302482k

Google Scholar

[4] S. Karthik, N. Puvvada, B.P. Kumar, S. Rajput, A. Pathak, M. Mandal, N.P. Singh, Photoresponsive Coumarin-Tethered Multifunctional Magnetic Nanoparticles for Release of Anticancer Drug, ACS Appl. Mater. Interfaces. 5 (2013) 5232-5238.

DOI: 10.1021/am401059k

Google Scholar

[5] R. Subramaniam, Y. Xiao, Y. Li, S.Y. Qian, W. Sun, S. Mallik, Light-mediated and H-bond facilitated liposomal release: the role of lipid head groups in release efficiency, Tetrahedron Lett. 51 (2010) 529–532.

DOI: 10.1016/j.tetlet.2009.11.084

Google Scholar

[6] S. Atta, M. Ikbal, A. Kumar, N.P. Singh, Application of photoremovable protecting group for controlled release of plant growth regulators by sunlight, J. Photochem. Photobiol. B, Biol. 111 (2012) 39-49.

DOI: 10.1016/j.jphotobiol.2012.03.008

Google Scholar

[7] P. Bourbon, Q. Peng, G. Ferraudi, C. Stauffacher, O. Wiest, P. Helquist, Synthesis and photochemical behavior of coumarin-caged Cholesterol, Bioorg. Med. Chem. Lett. 23 (2013) 2162-2165.

DOI: 10.1016/j.bmcl.2013.01.095

Google Scholar

[8] M. Kah, S. Beulke, K. Tiede, T. Hofmann, Nanopesticides: State of Knowledge, Environmental Fate, and Exposure Modeling, Crit Rev Environ Sci Technol. 43 (2013) 1823-1867.

DOI: 10.1080/10643389.2012.671750

Google Scholar

[9] Q. Lin, C. Bao, G. Fan, S. Cheng, H. Liu, Z. Liu, L. Zhu, 7-Amino coumarin based fluorescent phototriggers coupled with nano/bio-conjugated bonds: Synthesis, labeling and photorelease, J. Mater. Chem. 22 (2012) 6680-6688.

DOI: 10.1039/c2jm30357d

Google Scholar

[10] S. Atta, A. Jana, R. Ananthakirshnan, and P. S. N. Dhuleep, Fluorescent Caged Compounds of 2, 4-Dichlorophenoxyacetic Acid (2, 4-D): Photorelease Technology for Controlled Release of 2, 4-D, J. Agric. Food. Chem. 58 (2010) 11844–11851.

DOI: 10.1021/jf1027763

Google Scholar

[11] S. Atta, A. Paul, R. Banerjee, M. Bera, M. Ikbal, D. Dhara, N.P. Singh, Photoresponsive polymers based on a coumarin moiety for the controlled release of pesticide 2, 4-D, RSC Advances. 5 (2015) 99968-99975.

DOI: 10.1039/c5ra18944f

Google Scholar