Effect of Acids on Synthesis of WO3 and their Application in Supercapacitor

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In this study, the characteristics of WO3 prepared with acidic solution were analyzed. The acidic solution was prepared by using hydrochloric acid and sulfuric acid as the solutions to be added during the hydrothermal synthesis process. SEM, XRD and electrochemical characteristics tests were performed based on the prepared samples. Samples prepared in hydrochloric acid (W1) solution can identify platelet crystals and nanospheres, and samples made from sulfuric acid (W2) solutions can identify nanospheres and nanocubes. From the XRD data, it was confirmed that all of the diffraction peaks had a hexagonal phase. Electrochemical properties showed good rate capability of W1 samples but low capacitance and W2 samples showed relatively high capacitances.

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August 2019

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© 2019 Trans Tech Publications Ltd. All Rights Reserved

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[1] Y. Huang, J. Liang, Y. Chen, An overview of the applications of graphene‐based materials in supercapacitors, Small, 8(12) (2012) 1805-1834.

DOI: 10.1002/smll.201102635

Google Scholar

[2] C. Largeot, C. Portet, J. Chmiola, P. L. Taberna, Y. Gogotsi, P. Simon, Relation between the ion size and pore size for an electric double-layer capacitor, J. Am. Chem. Society, 130(9) (2008) 2730-2731.

DOI: 10.1021/ja7106178

Google Scholar

[3] J. T. Mefford, W. G. Hardin, S. Dai, K. P. Johnston, K. J. Stevenson, Anion charge storage through oxygen intercalation in LaMnO3 perovskite pseudocapacitor electrodes, Nat. Mater. 13 (2014) 726-732.

DOI: 10.1038/nmat4000

Google Scholar

[4] J. Xu, T. Ding, J. Wang, J. Zhang, S. Wang, C. Chen et al. Tungsten oxide nanofibers self-assembled mesoscopic microspheres as high-performance electrodes for supercapacitor, Electrochimica Acta, 174 (2015) 728-734.

DOI: 10.1016/j.electacta.2015.06.044

Google Scholar

[5] M. Deepa, A. K. Srivastava, K. N. Sood, S. A. Agnihotry, Nanostructured mesoporous tungsten oxide films with fast kinetics for electrochromic smart windows, Nanotechnol. 17(10) (2006) 2625-2630.

DOI: 10.1088/0957-4484/17/10/030

Google Scholar

[6] J. Y. Zheng, Z. Haider, T. K. Van, A. U. Pawar, M. J. Kang, C. W. Kim, Y. S. Kang, Tuning of the crystal engineering and photoelectrochemical properties of crystalline tungsten oxide for optoelectronic device applications, CrystEngComm, 17(32) (2015) 6070-6093.

DOI: 10.1039/c5ce00900f

Google Scholar

[7] B. Sarma, A. L. Jurovitzki, Y. R. Smith, S. K. Mohanty, M. Misra, Redox-induced enhancement in interfacial capacitance of the titania nanotube/bismuth oxide composite electrode, ACS Appl. Mater. Interf. 5 (2013) 1688-1697.

DOI: 10.1021/am302738r

Google Scholar

[8] S. Ratha, and C. S. Rout, Supercapacitor electrodes based on layered tungsten disulfide-reduced graphene oxide hybrids synthesized by a facile hydrothermal method, ACS Appl. Mater. Interfaces, 5(5) (2013) 1688-1697.

DOI: 10.1021/am403663f

Google Scholar

[9] T. Ohba, H. Kanoh, K. Kaneko, Facilitation of water penetration through zero-dimensional gates on rolled-up graphene by cluster–chain–cluster transformations, J. Phys. Chem. 116(22) (2012) 12339-12345.

DOI: 10.1021/jp302769m

Google Scholar

[10] P. Yang, X. Xiao, Y. Li, Y. Ding, P. Qiang, X. Tan, H. Jin et al. Hydrogenated ZnO core–shell nanocables for flexible supercapacitors and self-powered systems, ACS Nano, 7(3) (2013) 2617-2626.

DOI: 10.1021/nn306044d

Google Scholar