Paper Titles
Analysis of a Damaged Drill Made from Hs 2-9-1-8 Steel
p.101
Application of Metallographic Investigation in Development of Sub-Sized Specimen Testing Techniques
p.111
Characteristics of Metallographic Preparation of Heat Exchanger Austenitic Stainless Steels
p.117
Replicas Application in Non-Destructive Testing
p.123
Synthesis of Nickel Cobalt Manganese Ternary Transition Metal Oxide from Mixed Hydroxide Precipitate as a Precursor to NCM811
p.131
LiNi0.7Mn0.3O2 as a Cheap Cobalt Free Nickel Rich Cathode Material for High-Performance Li-Ion Batteries
p.141
Synthesis and Characterization of Cobalt Free LiNiO2 Substituted by Al-Doping from Beverage Cans via Solid-State Method
p.153
Electrochemical Performance of a Water-Based LiFePO4 Cathode for Li-Ion Batteries
p.163
Effects of Conductive Agents on Electrochemical Performance of Water-Based LiNi0.6Mn0.2Co0.2O2 Cathodes for Cylindrical Cell Production of Lithium-Ion Batteries
p.169

Synthesis of Nickel Cobalt Manganese Ternary Transition Metal Oxide from Mixed Hydroxide Precipitate as a Precursor to NCM811

Article Preview

Abstract:

Sustainable green new and renewable energy is continuously developed along with the development of cheap and commercially available secondary energy storage such as Li-ion batteries (LIBs). Nickel-rich cathode material obtained from cheap raw materials can significantly reduce the overall LIBs production cost and improve the overall process feasibility. For the first time, Ni-rich cathode material precursor was synthesized from mixed hydroxide precipitate (MHP). Based on MHP characterization test, the nickel content is high but have slight Mn and Mg level. NCM precursors was prepared in three facile steps, i.e., acid leaching using cheap and environmentally friendly organic acids, coprecipitation using oxalic acid, and thermal decomposition of as-prepared oxalate precipitate. Based on FTIR and XRD analysis, high crystalline oxalate dihydrate precipitates were successfully obtained. The morphological feature of the precipitate is significantly affected by the type of leaching solution. Fine metal oxides precursor powders also were successfully prepared which is confirmed by XRD, FTIR, and SEM analysis and can be readily used for Ni-rich cathode material preparation. In this study, NCM-Ox-LA have the best characteristic properties.

You might also be interested in these eBooks
Energy Storage Technology and Applications View Preview
Defect and Diffusion Forum Vol. 417 View Preview

Info:

Periodical:

Defect and Diffusion Forum (Volume 417)

Pages:

131-139

DOI:

https://doi.org/10.4028/p-483356

Citation:

Cite this paper

Online since:

June 2022

Authors:

Cornelius Satria Yudha*, Mintarsih Rahmawati, Enni Apriliyani, Shofirul Sholikhatun Nisa, Arif Jumari

Keywords:

Cathode, Characterization, Co-Precipitation, Leaching, MHP, Nickel

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2022 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

References

[1] S. Ahmed, P. A. Nelson, K. G. Gallagher, N. Susarla, and D. W. Dees, Cost and energy demand of producing nickel manganese cobalt cathode material for lithium ion batteries,, J. Power Sources, vol. 342, p.733–740, 2017,.

DOI: 10.1016/j.jpowsour.2016.12.069

Google Scholar

[2] C. S. Yudha et al., Fast production of high performance LiNi0.815Co0.15Al0.035O2 cathode material via urea-assisted flame spray pyrolysis,, Energies, vol. 13, no. 11, 2020,.

DOI: 10.3390/en13112757

Google Scholar

[3] A. Purwanto, C. S. Yudha, U. Ubaidillah, H. Widiyandari, T. Ogi, and H. Haerudin, NCA cathode material: Synthesis methods and performance enhancement efforts,, Mater. Res. Express, vol. 5, no. 12, 2018,.

DOI: 10.1088/2053-1591/aae167

Google Scholar

[4] C. Nurcahyani et al., Flame-assisted spray pyrolysis of lithium nickel cobalt aluminum oxide leaching stream,, AIP Conf. Proc., vol. 2219, no. May, 2020,.

DOI: 10.1063/5.0003156

Google Scholar

[5] S. U. Muzayanha et al., Lithium Nickel Cobalt Aluminum Oxide Material from Cathode Waste.,.

Google Scholar

[6] L. Li et al., Process for recycling mixed-cathode materials from spent lithium-ion batteries and kinetics of leaching,, Waste Manag., vol. 71, p.362–371, 2018,.

DOI: 10.1016/j.wasman.2017.10.028

Google Scholar

[7] J. Wang et al., Recycling lithium cobalt oxide from its spent batteries: An electrochemical approach combining extraction and synthesis,, J. Hazard. Mater., vol. 405, no. July 2020, 2021,.

DOI: 10.1016/j.jhazmat.2020.124211

Google Scholar

[8] G. P. Nayaka, Y. Zhang, P. Dong, D. Wang, Z. Zhou, and J. Duan, An environmental friendly attempt to recycle the spent Li-ion battery cathode through organic acid leaching Journal of Environmental Chemical Engineering An environmental friendly attempt to recycle the spent Li-ion battery cathode through organic acid le,, J. Environ. Chem. Eng., vol. 7, no. 1, p.102854, 2018,.

DOI: 10.1016/j.jece.2018.102854

Google Scholar

[9] C. Fu, Z. Zhou, Y. Liu, Q. Zhang, Y. Zheng, and G. Li, Synthesis and electrochemical properties of Mg-doped LiNi 0.6Co0.2Mn0.2O2 cathode materials for li-ion battery,, J. Wuhan Univ. Technol. Mater. Sci. Ed., vol. 26, no. 2, p.211–215, 2011,.

DOI: 10.1007/s11595-011-0199-z

Google Scholar

[10] R. Weber, H. Li, W. Chen, C.-Y. Kim, K. Plucknett, and J. R. Dahn, In Situ XRD Studies During Synthesis of Single-Crystal LiNiO 2 , LiNi 0.975 Mg 0.025 O 2 , and LiNi 0.95 Al 0.05 O 2 Cathode Materials ,, J. Electrochem. Soc., vol. 167, no. 10, p.100501, 2020,.

DOI: 10.1149/1945-7111/ab94ef

Google Scholar

[11] B. Huang, X. Li, Z. Wang, H. Guo, and X. Xiong, Synthesis of Mg-doped LiNi0.8Co0.15Al 0.05O2 oxide and its electrochemical behavior in high-voltage lithium-ion batteries,, Ceram. Int., vol. 40, no. 8 PART B, p.13223–13230, 2014,.

DOI: 10.1016/j.ceramint.2014.05.029

Google Scholar

[12] J. Seo and J. Lee, Fast growth of the precursor particles of Li(Ni0.8Co0.16Al0.04)O2 via a carbonate co-precipitation route and its electrochemical performance,, J. Alloys Compd., vol. 694, p.703–709, 2017,.

DOI: 10.1016/j.jallcom.2016.10.062

Google Scholar

[13] H. J. Noh, S. Youn, C. S. Yoon, and Y. K. Sun, Comparison of the structural and electrochemical properties of layered Li[NixCoyMnz]O2 (x = 1/3, 0.5, 0.6, 0.7, 0.8 and 0.85) cathode material for lithium-ion batteries,, J. Power Sources, vol. 233, p.121–130, 2013,.

DOI: 10.1016/j.jpowsour.2013.01.063

Google Scholar

[14] J. Li, B. R. Chen, and H. M. Zhou, Effects of washing and heat-treatment on structure and electrochemical charge/discharge property of LiNi0.8Co0.15Al0.05O2 powder,, Wuji Cailiao Xuebao/Journal Inorg. Mater., vol. 31, no. 7, p.773–778, 2016,.

Google Scholar

[15] G. V. Zhuang, G. Chen, J. Shim, X. Song, P. N. Ross, and T. J. Richardson, Li2CO3 in LiNi0.8Co0.15Al 0.05O2 cathodes and its effects on capacity and power,, J. Power Sources, vol. 134, no. 2, p.293–297, 2004,.

DOI: 10.1016/j.jpowsour.2004.02.030

Google Scholar

[16] L. Li et al., Recovery of metals from spent lithium-ion batteries with organic acids as leaching reagents and environmental assessment,, J. Power Sources, vol. 233, p.180–189, 2013,.

DOI: 10.1016/j.jpowsour.2012.12.089

Google Scholar

[17] L. Li et al., Ascorbic-acid-assisted recovery of cobalt and lithium from spent Li-ion batteries,, J. Power Sources, vol. 218, p.21–27, 2012,.

DOI: 10.1016/j.jpowsour.2012.06.068

Google Scholar

[18] T. Zhao, R. Ji, and Y. Meng, The role of precipitant in the preparation of lithium-rich manganese-based cathode materials,, Chem. Phys. Lett., vol. 730, p.354–360, 2019,.

DOI: 10.1016/j.cplett.2019.06.034

Google Scholar

[19] A. Jumari, K. Nur, R. Stulasti, R. N. Halimah, L. A. Aini, and R. Mintarsih, Production of LiNi0.6Mn0.2Co0.2.2O2 via fast oxalate precipitation for Li-ion,, in the 5Th International Conference on Industrial, Mechanical, Electrical, and Chemical Engineering 2019 (Icimece 2019), 2020, vol. 030011, no. April, p.2–7, doi: https://doi.org/10.1063/5.0000646 Published.

DOI: 10.1063/5.0000646

Google Scholar

[20] T. Zeng and C. Zhang, An effective way of co-precipitating Ni2+, Mn2+ and Co2+ by using ammonium oxalate as precipitant for Ni-rich Li-ion batteries cathode,, J. Mater. Sci., vol. 55, no. 25, p.11535–11544, 2020,.

DOI: 10.1007/s10853-020-04753-w

Google Scholar

[21] W. A. Ang, N. Gupta, R. Prasanth, and S. Madhavi, High-performing mesoporous iron oxalate anodes for lithium-ion batteries,, ACS Appl. Mater. Interfaces, vol. 4, no. 12, p.7011–7019, 2012,.

DOI: 10.1021/am3022653

Google Scholar

[22] B. Małecka, A. Małecki, E. Drozdz-Cieśla, L. Tortet, P. Llewellyn, and F. Rouquerol, Some aspects of thermal decomposition of NiC2O4·2H2O,, Thermochim. Acta, vol. 466, no. 1–2, p.57–62, 2007,.

DOI: 10.1016/j.tca.2007.10.010

Google Scholar

[23] J. Zhu et al., Efficient utilisation of rod-like nickel oxalate in lithium-ion batteries: A case of NiO for the anode and LiNiO2 for the cathode,, Scr. Mater., vol. 178, no. 3, p.51–56, 2020,.

DOI: 10.1016/j.scriptamat.2019.10.051

Google Scholar

[24] H. J. Oh et al., Nickel oxalate dihydrate nanorods attached to reduced graphene oxide sheets as a high-capacity anode for rechargeable lithium batteries,, NPG Asia Mater., vol. 8, no. 5, pp. e270-8, 2016,.

DOI: 10.1038/am.2016.59

Google Scholar

[25] S. W. Lee et al., Improved electrochemical performance of LiNi0.6Co0.2Mn0.2O2 cathode material synthesized by citric acid assisted sol-gel method for lithium ion batteries,, J. Power Sources, vol. 315, p.261–268, 2016,.

DOI: 10.1016/j.jpowsour.2016.03.020

Google Scholar

[26] J. Duan et al., Enhanced compacting density and cycling performance of Ni-riched electrode via building mono dispersed micron scaled morphology,, J. Alloys Compd., vol. 695, p.91–99, 2017,.

DOI: 10.1016/j.jallcom.2016.10.158

Google Scholar

[27] Y. Aihara, The electrochemical characteristics and applicability of an amorphous sulfide-Based solid ion conductor for the next-generation solid-state lithium secondary Batteries,, vol. 4, no. May, p.1–8, 2016,.

DOI: 10.3389/fenrg.2016.00018

Google Scholar

[28] C. S. Yudha, M. Rahmawati, A. Jumari, A. P. Hutama, and A. Purwanto, Synthesis of Zinc Oxide (ZnO) from Zinc Based-Fertilizer as Potential and Low-Cost Anode Material for Lithium Ion Batteries,, in ACM International Conference Proceeding Series, 2020, p.1–6,.

DOI: 10.1145/3429789.3429860

Google Scholar

[29] M. Y. Cheng, Y. S. Ye, T. M. Chiu, C. J. Pan, and B. J. Hwang, Size effect of nickel oxide for lithium ion battery anode,, J. Power Sources, vol. 253, p.27–34, 2014,.

DOI: 10.1016/j.jpowsour.2013.12.037

Google Scholar

[30] Z. Li et al., Effects of Nb substitution on structure and electrochemical properties of LiNi0.7Mn0.3O2 cathode materials,, J. Solid State Electrochem., vol. 22, no. 9, p.2811–2820, 2018,.

DOI: 10.1007/s10008-018-3975-2

Google Scholar

[31] Y. Zhu, C. Cao, S. Tao, W. Chu, Z. Wu, and Y. Li, Ultrathin nickel hydroxide and oxide nanosheets: Synthesis, characterizations and excellent supercapacitor performances,, Sci. Rep., vol. 4, p.1–7, 2014,.

DOI: 10.1038/srep05787

Google Scholar

[32] A. Angermann and J. Töpfer, Synthesis of magnetite nanoparticles by thermal decomposition of ferrous oxalate dihydrate,, J. Mater. Sci., vol. 43, no. 15, p.5123–5130, 2008,.

DOI: 10.1007/s10853-008-2738-3

Google Scholar