Optimizing PVDF Membranes Performance with Rotary Spacer Membrane Filtration System for Oil/Water Emulsion

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The treatment of oily wastewater poses significant environmental and economic challenges, necessitating innovative solutions that combine effective separation technologies with enhanced antifouling properties. This study introduces the integration of a high-performance modified PVDF membrane and rotary spacer membrane filtration system for fouling mitigation in treating oily wastewater in the form of oil/water emulsion. This study shows that the modified and plain PVDF membranes achieved the highest permeabilities of 610.71±25.25, and 175.51±2.72 L.m-2.h-1.bar-1., respectively when applied in the rotary spacer membrane filtration system due to hydrodynamic effect generated by the spacer rotation. The spacer rotation speed and spacer-to-membrane gap were varied to investigate the effect of those parameters on the membrane hydraulic performance. This study reveals that increasing the spacer rotation speed up to 50 RPM improves the permeability of both membranes, but different behaviors were observed when the speed was further increased which is believed due to the distinct properties of the membranes. Meanwhile, reducing the spacer-to-membrane gap slightly enhances the permeability for both membranes. This study demonstrates that the rotary spacer filtration system is able to help the modified membrane to achieve its optimum performance thus offers a competitive approach for effective membrane fouling control.

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21-27

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March 2025

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[1] W. Guo, H.-H. Ngo, and J. J. B. t. Li, "A mini-review on membrane fouling," vol. 122, pp.27-34, 2012.

Google Scholar

[2] J. C.-T. Lin, D.-J. Lee, C. J. S. S. Huang, and Technology, "Membrane fouling mitigation: Membrane cleaning," vol. 45, no. 7, pp.858-872, 2010.

DOI: 10.1080/01496391003666940

Google Scholar

[3] S. Lin and W. J. J. o. h. m. Lan, "Waste oil/water emulsion treatment by membrane processes," vol. 59, no. 2-3, pp.189-199, 1998.

Google Scholar

[4] N. U. Barambu, M. R. Bilad, M. A. Bustam, K. A. Kurnia, M. H. D. Othman, and N. A. H. M. Nordin, "Development of membrane material for oily wastewater treatment: A review," Ain Shams Engineering Journal, vol. 12, no. 2, pp.1361-1374, 2021/06/01/ 2021.

DOI: 10.1016/j.asej.2020.08.027

Google Scholar

[5] J. Cui et al., "Bio-inspired fabrication of superhydrophilic nanocomposite membrane based on surface modification of SiO2 anchored by polydopamine towards effective oil-water emulsions separation," vol. 209, pp.434-442, 2019.

DOI: 10.1016/j.seppur.2018.03.054

Google Scholar

[6] X. Shi, G. Tal, N. P. Hankins, and V. Gitis, "Fouling and cleaning of ultrafiltration membranes: A review," Journal of Water Process Engineering, vol. 1, pp.121-138, 2014/04/01/ 2014.

DOI: 10.1016/j.jwpe.2014.04.003

Google Scholar

[7] N. F. Zulkefli et al., "Recent Mitigation Strategies on Membrane Fouling for Oily Wastewater Treatment," vol. 12, no. 1, p.26, 2022. [Online]. Available: https://www.mdpi.com/2077-0375/12/1/26.

DOI: 10.3390/membranes12010026

Google Scholar

[8] N. I. Mat Nawi et al., "Improved nylon 6, 6 nanofiber membrane in a tilted panel filtration system for fouling control in microalgae harvesting," vol. 12, no. 2, p.252, 2020.

DOI: 10.3390/polym12020252

Google Scholar

[9] M. Li, L. Wu, C. Zhang, W. Chen, and C. Liu, "Hydrophilic and antifouling modification of PVDF membranes by one-step assembly of tannic acid and polyvinylpyrrolidone," Applied Surface Science, vol. 483, pp.967-978, 2019/07/31/ 2019, doi: https://doi.org/10.1016/j.apsusc. 2019.04.057.

DOI: 10.1016/j.apsusc.2019.04.057

Google Scholar

[10] M. T. Alresheedi and O. D. J. J. o. E. C. E. Basu, "Interplay of water temperature and fouling during ceramic ultrafiltration for drinking water production," vol. 8, no. 5, p.104354, 2020.

DOI: 10.1016/j.jece.2020.104354

Google Scholar

[11] A. Dehban, A. Kargari, and F. Z. Ashtiani, "Preparation and optimization of antifouling PPSU/PES/SiO2 nanocomposite ultrafiltration membranes by VIPS-NIPS technique," Journal of Industrial and Engineering Chemistry, vol. 88, pp.292-311, 2020/08/25/ 2020.

DOI: 10.1016/j.jiec.2020.04.028

Google Scholar

[12] H. Mahdavi, M. A. Kerachian, and M. Abazari, "Synergistic effect of GO@SiO2 and GO@ZnO nano-hybrid particles with PVDF-g-PMMA copolymer in high-flux ultrafiltration membrane for oily wastewater treatment and antifouling properties," Journal of Industrial and Engineering Chemistry, vol. 108, pp.374-388, 2022/04/25/ 2022.

DOI: 10.1016/j.jiec.2022.01.016

Google Scholar

[13] W. Liu et al., "A novel smart coating with ammonia-induced switchable superwettability for oily wastewater treatment," vol. 8, no. 5, p.104164, 2020.

DOI: 10.1016/j.jece.2020.104164

Google Scholar

[14] L. Marbelia, M. R. Bilad, and I. F. Vankelecom, "Gradual PVP leaching from PVDF/PVP blend membranes and its effects on membrane fouling in membrane bioreactors," Separation and Purification Technology, vol. 213, pp.276-282, 2019.

DOI: 10.1016/j.seppur.2018.12.045

Google Scholar

[15] N. I. M. Nawi et al., "Development of Polyvinylidene Fluoride Membrane via Assembly of Tannic Acid and Polyvinylpyrrolidone for Filtration of Oil/Water Emulsion," vol. 13, no. 6, p.976, 2021.

DOI: 10.3390/polym13060976

Google Scholar

[16] M. Y. Jaffrin, L.-H. Ding, O. Akoum, and A. J. J. o. M. S. Brou, "A hydrodynamic comparison between rotating disk and vibratory dynamic filtration systems," vol. 242, no. 1-2, pp.155-167, 2004.

DOI: 10.1016/j.memsci.2003.07.029

Google Scholar

[17] S. Waqas, M. R. Bilad, Z. B. Man, C. Klaysom, J. Jaafar, and A. L. J. A. E. J. Khan, "An integrated rotating biological contactor and membrane separation process for domestic wastewater treatment," vol. 59, no. 6, pp.4257-4265, 2020.

DOI: 10.1016/j.aej.2020.07.029

Google Scholar

[18] M. Frappart, A. Massé, M. Y. Jaffrin, J. Pruvost, and P. J. D. Jaouen, "Influence of hydrodynamics in tangential and dynamic ultrafiltration systems for microalgae separation," vol. 265, no. 1-3, pp.279-283, 2011.

DOI: 10.1016/j.desal.2010.07.061

Google Scholar

[19] P. Sarkar, S. Ghosh, S. Dutta, D. Sen, and C. J. D. Bhattacharjee, "Effect of different operating parameters on the recovery of proteins from casein whey using a rotating disc membrane ultrafiltration cell," vol. 249, no. 1, pp.5-11, 2009.

DOI: 10.1016/j.desal.2009.06.007

Google Scholar

[20] N. I. Mat Nawi et al., "A Rotary Spacer System for Energy-Efficient Membrane Fouling Control in Oil/Water Emulsion Filtration," vol. 12, no. 6, p.554, 2022. [Online]. Available: https://www.mdpi.com/2077-0375/12/6/554.

DOI: 10.3390/membranes12060554

Google Scholar

[21] Z. Niu, H. Guo, Y. Zhou, and S. J. J. o. E. C. E. Xia, "Unraveling membrane fouling in anoxic/oxic membrane bioreactors treating anaerobically digested piggery wastewater," vol. 9, no. 1, p.104985, 2021.

DOI: 10.1016/j.jece.2020.104985

Google Scholar