Study of the Degradation of Dyes by a Mononuclear Copper Complex Forming a Zigzag Chain

Abstract:

The titled mononuclear complex [Cu (L)] with the formally tetradentate schiff base ligand, [N,N’-bis (2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropan-2-ol] has been synthesized and characterized using IR spectroscopy and elemental analysis. Crystal structure has been determined by XRD which reveals the pseudo octahedral complex geometry and the use of hydroxo bridges between two neighbor units to form a 1D coordination polymer. The use of this complex as a catalyst for the degradation of two textile dyes, in the presence of the appropriate amount of H₂O₂ and a UV light source has given very good results with yields exceeding 98% after 50 minutes.

• Periodical: Engineering Chemistry (Volume 2)
• Pages: 65-74
• DOI: https://doi.org/10.4028/p-kx6jk5
• Online since: May 2023
• Authors: Fatma Darkbira, Oussama Kheireddine Nehar, Fatima Zohra Chiboub Fellah*, Thierry Roisnel, Abdelghani Chiboub Fellah
• Keywords: Mononuclear Copper Complexes, Organic Dyes, Photocatalysis, Schiff Base Complexes, X-Ray Molecular Structure

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