Natural Gas Hydrates – A Review of the Resources Offshore Nigeria and around the Globe

Article Preview

Abstract:

Natural gas hydrates are ice-like materials which exist in permafrost regions and in the continental margins of oceans. They constitute a huge unconventional reservoir of natural gas around the globe including offshore Nigeria. The paper is a review of this important global resource with particular focus on the Nigerian deposits. The reasons for the interest on hydrates are discussed including the potential for the recovery of large quantities of methane, the climate change and ocean floor instability that may result from their dissociation. They may also be exploited for large-scale CO2 sequestration. The geographical distribution of hydrates deposits on earth, the thermodynamics of why they occur in those particular places and source of the methane gas that is eventually enchlathrated into hydrates are discussed. The natural gas in the Nigerian hydrate is essentially biogenic in origin and is almost pure methane (more than 99% methane). The hydrates exist in finely disseminated or massive aggregate forms within clay-rich sediment.

You might also be interested in these eBooks

Info:

Pages:

27-33

Citation:

Online since:

May 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Y. F Makogan, S.A. Holditch, T. Y Makogan, Natural gas hydrates – a potential energy source for the 21st century, J. Petrol. Sci. Eng. 56 (2007) 14-31.

Google Scholar

[2] U.P. Igboanusi, Properties and production of natural gas hydrates, PhD Thesis, Department of Chemical Engineering, Imperial College London, (2010).

Google Scholar

[3] K.A. Kvenvolden, Natural gas hydrates: background and history of discovery, in E. D Max (Ed. ), Natural Gas Hydrate in Oceanic and Permafrost Environments, Kluwer Academic Publishers, Netherlands, 2000, pp.9-16.

DOI: 10.1007/978-94-011-4387-5_2

Google Scholar

[4] E.D. Sloan, Fundamental principles and applications of natural gas hydrates, Nature 426, (2003) 353-359.

DOI: 10.1038/nature02135

Google Scholar

[5] I. Chatti, A. Delahaye, L. Fournaison, J. Petitet, Benefits and drawbacks of clathrate hydrates: a review of their areas of interest, Energ. Convers. Manag. 46, (2005) 1333 – 1343.

DOI: 10.1016/j.enconman.2004.06.032

Google Scholar

[6] E.D. Sloan, Clathrate Hydrate of Natural Gases, Marcel Dekker Incorporated, New York, (1998).

Google Scholar

[7] R. A Dawe, S. Thomas, A large potential methane source – natural gas hydrates, Energy Sources, Part A 29 (2007). 217-229.

DOI: 10.1080/009083190948676

Google Scholar

[8] Y.F. Makogan, Hydrates of Natural Gas, Penn Well: Oklahoma, (1997).

Google Scholar

[9] A.V. Milkov, Global estimates of hydrate-bound gas in marine sediments: how much is really out there?, Earth Sci. Rev. 46 (2004) 183 – 197.

DOI: 10.1016/j.earscirev.2003.11.002

Google Scholar

[10] J.B. Klauda, S.I. Sandler, Global Distribution of Methane Hydrate in Ocean Sediment, Energ. Fuel. 19 (2005) 459 – 470.

DOI: 10.1021/ef049798o

Google Scholar

[11] C.A. Koh, E.D. Sloan, Natural gas hydrates: recent advances and challenges in energy and environmental applications, AIChE Journal 53 (2007) 1636 – 1643.

DOI: 10.1002/aic.11219

Google Scholar

[12] P. Englezos, Clathrate hydrates, Ind. Eng. Chem. Res. 32 (2003) 1251-1274.

DOI: 10.1021/ie00019a001

Google Scholar

[13] R. Corfield, Close encounters with crystalline gas, Chem. Brit. 38 (2002) 22-25.

Google Scholar

[14] L.D. Valentine, D.C. Blanton, W.S. Reeburgh, M. Kastner, Water column methane oxidation adjacent to an area of active hydrate dissociation, Eel River Basin, Geochim. Cosmochim. Acta 65 (2001) 2633 – 2640.

DOI: 10.1016/s0016-7037(01)00625-1

Google Scholar

[15] B. Beauchamp, Natural gas hydrates: myths, facts and issues, C. R. Geosci. 336 (2004) 751-765.

DOI: 10.1016/j.crte.2004.04.003

Google Scholar

[16] C.K. Paull, W. Ussler, W.P. Dillon, Potential role of gas hydrate decomposition in generating submarine slope failures, in E.D. Max (Ed), Natural Gas Hydrate in Oceanic and Permafrost Environments, Kluwer Academic Publishers, Netherlands, 2000, 149 – 156.

DOI: 10.1007/978-94-011-4387-5_12

Google Scholar

[17] N. Sultan, P. Cochonat, J.P. Foucher, J. Mienert, Effect of gas hydrate melting on seafloor slope stability, Marine Geology 213 (2004) 379 – 401.

DOI: 10.1016/j.margeo.2004.10.015

Google Scholar

[18] C. Berndt, S. Brune, E. Nisbet, J. Zschau, S.V. Sobolev, Tsunami modelling of a submarine landslide in the Fram Strait, Geochem. Geophy. Geosys. 10 (2009) 1-9.

DOI: 10.1029/2008gc002292

Google Scholar

[19] S. Nakano, K. Yamamoto, K. Ohgaki, Natural gas exploitation by carbon dioxide from gas hydrate fields – high-pressure phase equilibrium for an ethane hydrate system, Proceed. Inst. Mech. Eng. 212 (1998) 159-163.

DOI: 10.1243/0957650981536826

Google Scholar

[20] M. Ota, Y. Abe, M. Watanabe, R.L. Smith, H. Inomata, Methane recovery from methane hydrate using pressurized CO2, Fluid Phase Equi. 228-229 (2005) 553-559.

DOI: 10.1016/j.fluid.2004.10.002

Google Scholar

[21] Y. Kaya, The role of CO2 removal and disposal, Energ. Convers. Manag. 36 (1995) 375-580.

Google Scholar

[22] K.A. Kvenvolden, Methane hydrate in the global organic carbon cycle, Terra Nova 14 (2002) 302 – 306.

DOI: 10.1046/j.1365-3121.2002.00414.x

Google Scholar

[23] M.D. Max, Hydrate resource, methane fuel, and a gas-based economy?, in M.D. Max, (Ed. ), Natural Gas Hydrate in Oceanic and Permafrost Environments, Kluwer Academic Publishers, Netherlands, 2000, p.361 – 370.

DOI: 10.1007/978-94-011-4387-5_27

Google Scholar

[24] N. Goel, In situ methane hydrate dissociation with carbon dioxide sequestration: current knowledge and issues, J. Petrol. Sci. Eng. 51 (2006) 169-184.

DOI: 10.1016/j.petrol.2006.01.005

Google Scholar

[25] P. Wellsbury, R.J. Parkes, Deep biosphere: sources of methane for oceanic hydrate, in E.D. Max (Ed. ), Natural Gas Hydrate in Oceanic and Permafrost Environments, Kluwer Academic Publishers, Netherlands, 2000, 91 – 104.

DOI: 10.1007/978-94-011-4387-5_8

Google Scholar

[26] J.M. Brooks, W.R. Bryant, B.B. Bernard, N.R. Cameron, The nature of gas hydrates on the Nigerian continental slope, Annals of the New York Academy of Science, Third International Conference on Gas Hydrates, Park City, Utah, July 18-22, (1999).

DOI: 10.1111/j.1749-6632.2000.tb06761.x

Google Scholar

[27] J.S. Booth, M.M. Rowe, K.M. Fisher, Offshore Gas Hydrate Sample Database, USGS Open-file Report (1996) 96-272.

DOI: 10.3133/ofr96272

Google Scholar