Recycled Plastics as an Alternative Carbon Nanotubes Source by Chemical Vapor Deposition

Article Preview

Abstract:

In this study, therefore, multi-walled carbon nanotubes (MWCNTs) were prepared on account of morphology, particle size and thermal properties of CNTs from high-density polyethylene (HDPE) waste and polypropylene (PP) using pyrolysis in the presence of Fe/Mn/Al catalyst. A comparison between the produced CNTs and commercially available CNTs was conducted to analyse if any deviations exist between both products. It was discovered that The commercial CNTs properties have similarities with the MWCNTs produced from plastic wastes. These materials were found to differ in purity with 1% error. The structures and morphologies of these materials are comparable as they were found to be crystalline and they revealed lattice fringes. They differ by the planes in the structural orientation. The MWCNTs synthesized from plastic wastes showed low thermal stability as opposed to the commercial CNTs.

You might also be interested in these eBooks

Info:

* - Corresponding Author

[1] Koelble, T.A., The global economy and democracy in South Africa. 1998: Rutgers University Press New Brunswick, NJ.

DOI: 10.2307/2585652

Google Scholar

[2] Rogerson, C.M. and J.M. Rogerson, City tourism in South Africa: Diversity and change. Tourism Review International, 2017. 21(2): pp.193-211.

DOI: 10.3727/154427217x14984977561745

Google Scholar

[3] Rogerson, C.M. and J.M. Rogerson, Historical urban tourism: Developmental challenges in Johannesburg 1920-1950. Urbani izziv, 2019. 30: pp.112-128.

DOI: 10.5379/urbani-izziv-en-2019-30-supplement-008

Google Scholar

[4] Ayeleru, O.O., et al., Challenges of plastic waste generation and management in sub-Saharan Africa: A review. Waste Management, 2020. 110: pp.24-42.

DOI: 10.1016/j.wasman.2020.04.017

Google Scholar

[5] Ferrari, A.C., et al., Science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems. Nanoscale, 2015. 7(11): pp.4598-4810.

Google Scholar

[6] Coville, N.J., et al., A review of shaped carbon nanomaterials. South African Journal of Science, 2011. 107(3-4): pp.01-15.

Google Scholar

[7] Ferreira, F.V., et al., Synthesis, Characterization, and Applications of Carbon Nanotubes, in Carbon-Based Nanofillers and Their Rubber Nanocomposites. 2019, Elsevier. pp.1-45.

Google Scholar

[8] Georgakilas, V., et al., Broad family of carbon nanoallotropes: classification, chemistry, and applications of fullerenes, carbon dots, nanotubes, graphene, nanodiamonds, and combined superstructures. Chemical reviews, 2015. 115(11): pp.4744-4822.

DOI: 10.1021/cr500304f

Google Scholar

[9] Dass, D., R. Prasher, and R. Vaid, Analytical study of unit cell and molecular structures of single walled carbon nanotubes. International Journal of Computational Engineering Research, 2012. 2(5).10. Prasek, J., et al., Methods for carbon nanotubes synthesis. Journal of Materials Chemistry, 2011. 21(40): pp.15872-15884.

Google Scholar

[10] Yang, Y., et al., Graphene based materials for biomedical applications. Materials today, 2013. 16(10): pp.365-373.

Google Scholar

[11] 12. Lamberti, M., et al., Carbon nanotubes: Properties, biomedical applications, advantages and risks in patients and occupationally-exposed workers. 2015, SAGE Publications Sage UK: London, England.

Google Scholar

[12] Fredriksson, T., Carbon Nanotubes: A Theoretical study of Young's modulus. (2014).

Google Scholar

[13] Kaur, J., G.S. Gill, and K. Jeet, Applications of carbon nanotubes in drug delivery: a comprehensive review, in Characterization and biology of nanomaterials for drug delivery. 2019, Elsevier. pp.113-135.

DOI: 10.1016/b978-0-12-814031-4.00005-2

Google Scholar

[14] Rashid, H.U., et al., Catalyst role in chemical vapor deposition (CVD) process: a review. Rev. Adv. Mater. Sci, 2015. 40(3): pp.235-248.

Google Scholar

[15] Roy, A. and D. Das. Low temperature growth of carbon nanotubes with aligned multiwalls by microwave plasma-CVD. in AIP Conference Proceedings. 2017. AIP Publishing LLC.

DOI: 10.1063/1.4980488

Google Scholar

[16] Eatemadi, A., et al., Carbon nanotubes: properties, synthesis, purification, and medical applications. Nanoscale research letters, 2014. 9(1): p.393.

Google Scholar

[17] 18. Armstrong, J.S. and K.C. Green, Forecasting methods and principles: Evidence-based checklists. Journal of Global Scholars of Marketing Science, 2018. 28(2): pp.103-159.

DOI: 10.1080/21639159.2018.1441735

Google Scholar

[18] Yao, D., et al., Co-production of hydrogen and carbon nanotubes from real-world waste plastics: Influence of catalyst composition and operational parameters. Applied Catalysis B: Environmental, 2018. 221: pp.584-597.

DOI: 10.1016/j.apcatb.2017.09.035

Google Scholar

[19] Aboul-Enein, A.A., et al., Synthesis of multi-walled carbon nanotubes via pyrolysis of plastic waste using a two-stage process. Fullerenes, Nanotubes and Carbon Nanostructures, 2018. 26(7): pp.443-450.

DOI: 10.1080/1536383x.2018.1447929

Google Scholar

[20] Burian, A., et al., Structural studies of multiwall carbon nanotubes by neutron diffraction. Physical Review B, 1999. 59(3): p.1665.

DOI: 10.1103/physrevb.59.1665

Google Scholar

[21] Reznik, D., et al., X-ray powder diffraction from carbon nanotubes and nanoparticles. Physical review B, 1995. 52(1): p.116.

Google Scholar

[22] El-Maghraby, A., H.A. El-Deeb, and M.A. Khattab, Influence of FeNi/Al2O3 Catalyst Compositions on the Growth of Carbon Nanotubes. Fullerenes, Nanotubes and Carbon Nanostructures, 2015. 23(1): pp.27-34.

DOI: 10.1080/1536383x.2012.702159

Google Scholar

[23] Girgsdies, F., Peak Profile Analysis in X-ray Powder Diffraction. Fritz-Haber-Institut der MPG: Berlin, Germany, (2015).

Google Scholar

[24] Liu, W.-W., et al., Synthesis of single-walled carbon nanotubes: Effects of active metals, catalyst supports, and metal loading percentage. Journal of Nanomaterials, 2013. 2013: p.63.

DOI: 10.1155/2013/592464

Google Scholar

[25] Jorio, A. and A.G. Souza Filho, Raman studies of carbon nanostructures. Annual Review of Materials Research, 2016. 46: pp.357-382.

DOI: 10.1146/annurev-matsci-070115-032140

Google Scholar

[26] Acomb, J.C., C. Wu, and P.T. Williams, The use of different metal catalysts for the simultaneous production of carbon nanotubes and hydrogen from pyrolysis of plastic feedstocks. Applied Catalysis B: Environmental, 2016. 180: pp.497-510.

DOI: 10.1016/j.apcatb.2015.06.054

Google Scholar

[27] Akselrod, L., et al., Raman studies of photochemical reactions in fullerene films. Chemical physics letters, 1993. 212(3-4): pp.384-390.

DOI: 10.1016/0009-2614(93)89342-f

Google Scholar

[28] Harris, P.J., Transmission electron microscopy of carbon: a brief history. C—Journal of Carbon Research, 2018. 4(1): p.4.

Google Scholar

[29] Escobar-Alarcón, L., et al., Two-dimensional carbon nanostructures obtained by laser ablation in liquid: effect of an ultrasonic field. Applied Physics A, 2018. 124(2): p.141.

DOI: 10.1007/s00339-018-1559-8

Google Scholar

[30] Moeck, P., et al. Lattice fringe fingerprinting in two dimensions with database support. in Technical Proceedings of the 2006 NSTI Nanotechnology Conference and Trade Show, Volume 1. (2006).

Google Scholar

[31] Yvon H. J, Raman Application Note:Carbon Nanotubes- What information does Raman Bring?, in Horiba, H.E.t. Future, Editor., Horiba: France. p.1.

Google Scholar

[32] Wang X, Wu S, Zou W, Yu S, Gui K, Dong L. Fe-Mn/Al2O3 catalysts for low temperature selective catalytic reduction of NO with NH3. Chinese Journal of Catalysis 2016;37:1314-23.

DOI: 10.1016/s1872-2067(15)61115-9

Google Scholar

[33] Wang J, Shen B, Lan M, Kang D, Wu C. Carbon nanotubes (CNTs) production from catalytic pyrolysis of waste plastics: the influence of catalyst and reaction pressure. Catalysis Today (2019).

DOI: 10.1016/j.cattod.2019.01.058

Google Scholar