Effect of Annealing on Dielectric Property in Ni1-xCoxFe2O4 Nanoparticles Synthesized Using Albumen (egg white)

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The nano crystalline nickel-cobalt ferrite using albumen (egg white) is synthesized by thermal evaporation method and its dielectric behaviour is analyzed for different annealing temperatures. The dielectric property of the sample is measured using impedance analyzer in the frequency range 1-100 MHz. The variation of dielectric constant and dissipation factor under different frequency for the samples at different annealing temperature are analyzed. A steady dielectric constant is observed for the sample annealed at 500°C. The dielectric constant obtained for this sample is low and it is in the range of 18.9 to 6.9 for different frequencies. This low value of dielectric constant shows the less interfacial polarization due to high resistivity which may be to the presence of a few Fe2+ ions. It is observed that the dispersion in dielectric constant by varying the annealing temperature is producing an intended result. The presence of constituent phases in Ni1-xCoxFe2O4 is confirmed by X-Ray Diffraction. The particle size for Ni1-xCoxFe2O4 obtained from Scherrer equation is found to be is 30nm. The morphology, particle size and percentage composition of elements are measured by employing Transmission Electron Microscopy (TEM), Scanning Electron Microscopy (SEM) and Energy Dispersive X-Ray Analysis spectrum (EDX).

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205-213

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S. Marutha Senthil et al., "Effect of Annealing on Dielectric Property in Ni1-xCoxFe2O4 Nanoparticles Synthesized Using Albumen (egg white)", Journal of Nano Research, Vol. 6, pp. 205-213, 2009

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June 2009

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[1] S. Solyman, Transport properties of La-doped Mn-Zn ferrite, Ceramics International, 32 (2006) 755-760.

DOI: https://doi.org/10.1016/j.ceramint.2005.05.018

[2] T. Krishnaveni, B. RajiniKanth, V. SeethaRamaRaju, S.R. Murthy, Fabrication of multilayer chip inductors using Ni-Cu-Zn ferrites, J. of Alloys and Compd., 414 (2006) 282-286.

DOI: https://doi.org/10.1016/j.jallcom.2005.07.029

[3] Xinyong Li and Charles Kutal, Synthesis and characterization of superparamagnetic CoxFe3−xO4 nanoparticles, Journal of Alloys and Compounds, 349 (2003) 264-268.

DOI: https://doi.org/10.1016/s0925-8388(02)00863-0

[4] Kakarla Raghava Reddy , Kwang-Pill Lee , Anantha Gopalan Iyengar, Synthesis and characterization of novel conducting composites of Fe3O4 nanoparticles and sulfonated polyanilines, Journal of Applied Polymer Science, 104 (2007) 4127-4134.

DOI: https://doi.org/10.1002/app.26020

[5] V.L. Mathe, R.B. Kamble, Anomalies in electrical and dielectric properties of Nanocrystalline Ni-Co spinel ferrite, Materials Research 43(2007) 8-9.

DOI: https://doi.org/10.1016/j.materresbull.2007.09.001

[6] S. Sun, C.B. Murry, D. Welle, L. Folk, Magnetic properties of Ni ferrite nanocrystals dispersed in the silica matrix by sol-gel technique, A. Moser Scie., 1989 (2002) 287-293.

[7] P. Tailhades, C. Villette, A. Rousset, G.U. Kulkarni, K.P. Kannan, C.N.R. Rao, M. Lenglet, Cation Migration and Coercivity in Mixed Copper-Cobalt Spinel Ferrite Powders, J. Solid State Chem., 141 (1998) 56-63.

DOI: https://doi.org/10.1006/jssc.1998.7914

[8] M.P. Pileni, I. Lisiecki, Nanometer metallic copper particle synthesis in reverse micelles, Colloids Surf., 80 (A) (1993) 63-68.

DOI: https://doi.org/10.1016/0927-7757(93)80224-3

[9] S. Balaji, R. Kalai selvan, L. John Berchmans, S. Angappan, K. Subramanian C.O. Augustin, Combustion synthesis and characterization of Sn4+ substituted Nanocrystalline NiFe2O4, Material Science and Engineering B 119 (2005) 119-124.

DOI: https://doi.org/10.1016/j.mseb.2005.01.021

[10] I.H. Gul, F. Amin, A.Z. Abbasi, M. Anis-ur-Rehman, A. Maqsood, Physical and magnetic characterization of co-precipitated nanosize Co-Ni ferrites, Scripta Materi., 56 (2007) 497- 500.

DOI: https://doi.org/10.1016/j.scriptamat.2006.11.020

[11] Joseph Lik Hang Chau, Ming-Kai Hsu, Chih-Chun Kao, Microwave plasma synthesis of Co and SiC-coated Co nanopowders, Mater. Lett., 60 (2006) 947-951.

DOI: https://doi.org/10.1016/j.matlet.2005.10.054

[12] H.M. Deng, J. Ding, Y. Shi, X.Y. Liu, J. Wang, Preparation of Zno Nanoparticles by Precipitation/Mechano chemical Method, J. Mater. Sci. 36 (2001) 3273-3278.

[13] K.V.P.M. Shafi, A. Gediankem, R. prozorov, Synthesis and magnetic behavior of silica-coated cobalt ferrite hollow spheres, J. Balogh. Chem. Mater., 10 (1998) 3445-3450.

[14] I.H. Gul, A.Z. Abbasi, F. Amin, M. Anis-ur-Rehman, A. Maqsood, Structural, magnetic and electrical properties of Co1-xZnxFe2O4 synthesized by co-precipitation method, Journal of Magnetism and Magnetic materials 311 (2007) 494-499.

DOI: https://doi.org/10.1016/j.jmmm.2006.08.005

[15] V.L. Mathe, R.B. Kamble, Anomalies in electrical and dielectric properties of Nanocrystalline Ni-Co spinel ferrite, Materials Research Bulletin, 43 (2008) 2160-2165.

DOI: https://doi.org/10.1016/j.materresbull.2007.09.001

[16] A. Mumtaz, K. Maaz, B. Janjua, S.K. Hasanain, M.F. Bertino, Exchange bias and vertical shift in CoFe2O4 nanoparticles Journal of magnetism and magnetic materials 313 (2007) 266-272.

DOI: https://doi.org/10.1016/j.jmmm.2007.01.007

[17] Santi Maensiri, Chivalrat Masingboon, Banjong Boonchom, Supapan Seraphin, A simple route to synthesize nickel ferrite (NiFe2O4) nanoparticles using egg white, Scripta Materi., 56 (2007) 797-800.

DOI: https://doi.org/10.1016/j.scriptamat.2006.09.033

[18] L.C. Santa Maria, M.A.S. Costa, J.G.M. Soares, S.H. Wang, M.R. Silva, Preparation and characterization of manganese, nickel and cobalt ferrites submicron particles in sulfonated crosslinked networks, polymer 46 (2005) 11288-11293.

DOI: https://doi.org/10.1016/j.polymer.2005.09.055

[19] P. Tailhades, C. Villette, A. Rousset, G.U. Kulkarni, K.P. Kannan, C.N.R. Rao, M. Lenglet, Cation Migration and Coercivity in Mixed Copper-Cobalt Spinel Ferrite Powders, J. Solid State Chem., 141 (1998) 56-63.

DOI: https://doi.org/10.1006/jssc.1998.7914

[20] Y. Ahn, E.J. Choi, S. Kim, H.N. Ok, Magnetization and Mossbauer study of cobalt ferrite particles from nanophase cobalt iron carbonate, Mater. Lett., 50 (2001) 47-52.

DOI: https://doi.org/10.1016/s0167-577x(00)00412-2

[21] S. Prasad, N.S. Gajbhiye, Magnetic studies of nanosized nickel ferrite particles synthesized by the citrate precursor technique, J. Alloys Compd., 256 (1998) 87-92.

DOI: https://doi.org/10.1016/s0925-8388(97)00431-3

[22] A. Kale, S. Gubbala, R.D.K. Misra, Magnetic behavior of nanocrystalline nickel ferrite synthesized by the reverse micelle technique, J. of Mag. and Magn. Mater. 277 (2004) 350- 358.

DOI: https://doi.org/10.1016/j.jmmm.2003.11.015

[23] Muhammad Ajmal, Asghari Maqsood, Influence of zinc substitution on structural and electrical properties of Ni1−xZnxFe2O4 ferrites, Mater. Scie. and Eng., B, 139 (2007) 164-170.

DOI: https://doi.org/10.1016/j.mseb.2007.02.004

[24] H.E. Zhang, B.F. Zhang, G.F. Wang, X.H. Dong, Y. Gao, The structure and magnetic properties of Zn1−xNixFe2O4 ferrite nanoparticles prepared by sol-gel auto-combustion J. of Mag. and Magn. Mater. 312 (2007) 126-130.

DOI: https://doi.org/10.1016/j.jmmm.2006.09.016

[25] Yan Li, Qingqing Fang, Yanmei Liu, Qingrong Lv, Ping Yin, Effect of Co 2+ ions on the microstructure and magnetic properties of Nanocrystalline CoxFe3-xO4 Films, J. Magn. Magn. Mater. 313 (2007) 57-61.

DOI: https://doi.org/10.1016/j.jmmm.2006.12.003

[26] E. M. Mohammed, K. A. Malini, Philip Kurian and M. R. Anantharaman, Modification of dielectric and mechanical properties of rubber ferrite composites containing manganese zinc ferrite, Materials Research Bulletin, 37 (2002) 753-768.

DOI: https://doi.org/10.1016/s0025-5408(02)00690-6

[27] A. Bhaskar, B. Rajini Kanth and S.R. Murthy, Electrical properties of Mn added MgCuZn ferrites prepared by microwave sintering method, Journal of Magnetism and Magnetic Materials,    283 (2004) 109-116.

DOI: https://doi.org/10.1016/j.jmmm.2004.05.039

[28] P.V. Reddy, T.S. Rao, Dielectric behaviour in Co-substituted NiSb ferrites, Journal of Materials Science Letters, 16 (1997) 1076-1079.

[29] C. Prakash, J. Bijal, Electrical properties of Mn added MgCuZn ferrites prepared by microwave sintering method, J. Less-Common Metals 107 (1985) 51-55.

[30] L. Radhapiyani, S. Phanjoubam, H.N.K. Sarma, C. Prakash, Influence of Co2+ on the electrical and magnetic properties of Li-Sb ferrites, Mater. Lett. 44 (2000) 65.

DOI: https://doi.org/10.1016/s0167-577x(00)00003-3

[31] C.G. Koops, Ferroelectricity in zinc cadmium telluride, Phys. Rev. 83 (1951) 121-126.

[32] A. Thakur, P. Mathur, M. Singh, Study of dielectric behaviour of Mn-Zn nano ferrites, Journal of Physics and Chemistry of solids 68 (2007) 378-381.

DOI: https://doi.org/10.1016/j.jpcs.2006.11.028

[33] A. Bhaskar, B. Rajini Kanth, S.R. Murthy, Electrical Properties of Mn added MgCuZn ferrites prepared by microwave sintering method, J. Magn. Magn. Mater. 283 (2004) 109-116.

DOI: https://doi.org/10.1016/j.jmmm.2004.05.039