Heterojunction Engineered FeWO4/g-C3N4 Nanocomposite Photocatalyst for Methyl Orange Degradation

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This study investigates the synergistic potential of a novel heterojunction photocatalyst for methyl orange degradation. The photocatalyst comprises iron tungstate (FeWO4) and graphitic carbon nitride (g-C3N4), engineered to exploit the distinct properties of each component for enhanced photocatalytic activity. The research systematically evaluates the performance of the synthesized FeWO4/g-C3N4 composite in degrading methyl orange, with an emphasis on optimizing catalytic efficiency. The photocatalyst was characterized using advanced techniques, including Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM) to elucidate its structural and morphological properties. Key parameters such as loading concentrations were optimized to assess their influence on the photodegradation efficiency. Among tested compositions, 1.0 wt% FeWO4/g-C3N4 achieved the highest degradation efficiency of MO at 78.04% within 180 minutes under UV irradiation. The heterojunction structure promoted effective charge separation, and further enhanced visible-light response. These results demonstrate the catalyst’s potential for sustainable water purification applications.

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43-49

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March 2026

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© 2026 Trans Tech Publications Ltd. All Rights Reserved

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[1] Patial, S., Raizada, P., Hasija, V., Singh, P., Thakur, V. K., & Nguyen, V. H. (2021). Recent advances in photocatalytic multivariate metal organic frameworks-based nanostructures toward renewable energy and the removal of environmental pollutants. Materials Today Energy, 19, 100589.

DOI: 10.1016/j.mtener.2020.100589

Google Scholar

[2] Liu, J., Liu, Q., Li, J., Zheng, X., Liu, Z., & Guan, X. (2022). Photochemical conversion of oxalic acid on heterojunction engineered FeWO4/g-C3N4 photocatalyst for high-efficient synchronous removal of organic and heavy metal pollutants. Journal of Cleaner Production, 363.

DOI: 10.1016/j.jclepro.2022.132527

Google Scholar

[3] Wang, C., Wang, G., Zhang, X., Dong, X., Chun, M., Ma, H., & Xue, M. (2018). Construction of g-C3N4 and FeWO4 Z-scheme photocatalyst: effect of contact ways on the photocatalytic performance. RSC Advances, 8(33), 18419–18426

DOI: 10.1039/c8ra02882f

Google Scholar

[4] Belousov, A. S., Fukina, D. G., & Koryagin, A. S. (2022). Metal-organic framework-based heterojunction photocatalysts for organic pollutant degradation: design, construction, and performances. Journal of Chemical Technology & Biotechnology, 97(10), 2675–2693.

DOI: 10.1002/jctb.7091

Google Scholar

[5] Bhosale, R., Jain, S., Vinod, C. P., Kumar, S., & Ogale, S. (2019). Direct Z-Scheme g-C3N4/FeWO4 Nanocomposite for Enhanced and Selective Photocatalytic CO2 Reduction under Visible Light. ACS Applied Materials and Interfaces, 11(6), 6174–6183.

DOI: 10.1021/acsami.8b22434

Google Scholar

[6] Kumar, S., Karthikeyan, S., & Lee, A. F. (2018). G-C3N4-Based nanomaterials for Visible Light-Driven photocatalysis. Catalysts, 8(2), 74.

DOI: 10.3390/catal8020074

Google Scholar

[7] Qamar, M. A., Javed, M., Shahid, S., Shariq, M., Fadhali, M. M., Ali, S. K., & Khan, M. S. (2023). Synthesis and applications of graphitic carbon nitride (g-C3N4) based membranes for wastewater treatment: A critical review. Heliyon, 9(1), e12685.

DOI: 10.1016/j.heliyon.2022.e12685

Google Scholar

[8] Liao, L., et al. (2014). Facile synthesis and photocatalytic activity of FeWO₄ nanocrystals under visible light irradiation. Materials Letters, 122, 5–8.

Google Scholar

[9] Zhang, Y., et al. (2009). Synthesis of graphitic carbon nitride (g-C₃N₄) polymers as photocatalysts for hydrogen production under visible light. Journal of Materials Chemistry, 19(29), 5689–5695.

Google Scholar

[10] Wang, L., et al. (2020). Construction of g-C₃N₄-based heterojunctions for enhanced photocatalytic activity. Applied Surface Science, 504, 144369.

Google Scholar

[11] Sirelkhatim, A., et al. (2015). Review on Zinc Oxide Nanoparticles: Antibacterial Activity and Toxicity Mechanism. Nano-Micro Letters, 7(3), 219–242.

DOI: 10.1007/s40820-015-0040-x

Google Scholar

[12] Zhang, Y., et al. (2009). Synthesis of graphitic carbon nitride (g-C₃N₄) polymers as photocatalysts. Journal of Materials Chemistry, 19(29), 5689–5695.

Google Scholar