Electrode Characteristics of High Pressure Synthetic High Boron Doped Diamond

Jian Bing Zang; Yan Hui Wang; W. Tang; H. Huang

doi:10.4028/www.scientific.net/KEM.315-316.507

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HomeKey Engineering MaterialsKey Engineering Materials Vols. 315-316Electrode Characteristics of High Pressure...

Electrode Characteristics of High Pressure Synthetic High Boron Doped Diamond

Abstract:

B-doped diamond is an excellent grinding material owing to its high hardness, oxidation resistance and chemical inertness as well as low resistance. The recent developments of Boron doped conductive diamond has further increased the scale of diamond applications including the manufacture of electrically conductive grinding wheel or the use as an electrode in EDM. The unique electrochemical properties also attract the researchers’ attention on the applications of electrode, sensor and detectors etc. This paper presents a viable technology that high boron doped diamond is synthesized under high pressure and high temperature using B-doped GICs as carbon sources. The synthetic diamond grains with electrically resistivity of 2cm are sufficiently conductive for electrochemistry measurement. Cyclic voltammotry was performed to evaluate the electrode characteristics of diamond powder. The results shows that B-doped diamond powder electrode is electrochemically stable in the supporting electrolytes such as 0.1M KCl, 0.5M Na2SO4 and 0.1M H2SO4 over a wide potential range. The level of background current is very low. The electrode reaction is quasi-reversible in 0.5M Na2SO4 containing the ferricyanide-ferrocyanide redox couple.

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Periodical:

Key Engineering Materials (Volumes 315-316)

Pages:

507-510

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.315-316.507

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Online since:

July 2006

Authors:

Jian Bing Zang, Yan Hui Wang, W. Tang, H. Huang

Keywords:

Cyclic Voltammotry, Diamond, Electrode, GICs, High Boron Doped, High-Pressure

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References

[1] K. Suzuki and T. Uematsu: Industrial Diamond Review, (2004) No. 2, pp.60-66.

Google Scholar

[2] M. Hupert, A. Muck, J. Wang, J. Stotter, Z. Cvackova, S. Haymond, Y. Show and G. M. Swain: Diamond and Related Materials, Vol. 12 (2003), p.1940-(1949).

DOI: 10.1016/s0925-9635(03)00260-7

Google Scholar

[3] G. P. Moreno and D. J. Riley: Electrochimica Acta, Vol. 47 (2002), pp.2589-2595.

Google Scholar

[4] J.L. Davidson, W.P. Kang and A. Wisitsora: Diamond and Related Materials, Vol. 12 (2003), pp.429-433.

Google Scholar

[5] R. Kalish: Carbon, Vol. 37 (1999), pp.781-785.

Google Scholar

[6] J.B. Zang, Y.H. Wang and H. Huang: Key Engineering Materials, Vol. 259-260 (2004), pp.42-45.

Google Scholar

[7] J.A.N. Goncalves, G.M. Sandonato and K. Iha: Diamond and Related Materials, Vol. 11 (2002), pp.1578-1583.

Google Scholar

[8] R. Ramesham: Sensors and Actuators B, Vol. 50 (1998), pp.131-139.

Google Scholar