Synthesis and Lithium Ion Conductivity of MP2O7-Based Solid Electrolytes

Abstract:

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Phase studies and ac-conductivity measurements were carried out in the compositions M0.8In0.2Li0.2P2O7 [MILP] (M=Sn, Zr, Ti). The bulk conductivities were of the order of ~10-5 Scm-1 at 623 K and higher in the order of TiILP≥ZrILP>SnILP. The activation energies, as expected, became lower in the order of ZrILPSnILP in bulk conductivities were not correlated with that of the activation energies probably because of the impureness of the ZrILP sample.

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Periodical:

Edited by:

Kazumi Kato, Tadashi Takenaka, Masasuke Takata and Kazuo Shinozaki

Pages:

53-56

DOI:

10.4028/www.scientific.net/KEM.388.53

Citation:

A. Kato et al., "Synthesis and Lithium Ion Conductivity of MP2O7-Based Solid Electrolytes", Key Engineering Materials, Vol. 388, pp. 53-56, 2009

Online since:

September 2008

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Price:

$35.00

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