Synthesis and Structural Consideration of Metal-Organic Framework (MOF) Coordination Polymer with Various Metal Linker Ratios

Halina Misran; Atiah Mohd Adminuddin; Faizul Akmal Mohd Zini; Ramesh Singh

doi:10.4028/www.scientific.net/KEM.462-463.1103

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HomeKey Engineering MaterialsKey Engineering Materials Vols. 462-463Synthesis and Structural Consideration of...

Synthesis and Structural Consideration of Metal-Organic Framework (MOF) Coordination Polymer with Various Metal Linker Ratios

Abstract:

Metal-organic framework MOF-5 (i.e. IRMOF-1) with the chemical structure of Zn4O(BDC)3 were successfully synthesized using room temperature synthesis approach of direct-mixing method ans liquid-crystal templating method. The metal clusters organic linker used was benzenedicarboxylic acid (BDC). Direct-mixing approach resulted in MOF-5 with tetragonal cell while the liquid-crystal templating method resulted in cubic structure. The metal/linker ratios were varied from 0.1 to 1 to study the effect of metal linker on the formation of MOF-5 materials and their characteristics. The crystallinity of the evacuated framework MOF-5 materials were increased when the metal/organic linker ratios were increased from 0.3 to 0.5. However, the cubic structure of the evacuated framework was relatively disrupted at metal/linker ratio 0.7.

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Key Engineering Materials (Volumes 462-463)

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1103-1108

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https://doi.org/10.4028/www.scientific.net/KEM.462-463.1103

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January 2011

Authors:

Halina Misran, Atiah Mohd Adminuddin, Faizul Akmal Mohd Zini, Ramesh Singh

Keywords:

BDC, Liquid Crystal, Metal-Organic Framework, MOF-5, Organic Linker

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