The Parameter Estimate Method to Determine the Optimal Thickness for DSSC Electrode

Article Preview

Abstract:

For physical structure of TiO2 films is the core of photoelectric conversion on the photovoltaic performance of DSSC, the method by parameter estimate to determine the optimal thickness of DSSC working electrode is deduced, which is consistent with the analysis of real physical meaning about the TiO2 layer thickness and the photocurrent, while gives the specific optimal value as an addition. As a mathematical proof of the optimal conclusion extracting from the complex working mechanism of DSSCs and accidental factors, the equivalent circuit parameters of each curve are estimated corresponds to the equivalent circuit method first. According to the inflection point, which obtained through the synthesis of scattered experment points to the trend curve, the optimal thickness of DSSC working electrode are optimal identified.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

57-60

Citation:

Online since:

July 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] O'Regan, B. and M. Gratzel, A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature, 1991. 353(6346): pp.737-740.

DOI: 10.1038/353737a0

Google Scholar

[2] Nazeeruddin, M.K., et al., Combined Experimental and DFT-TDDFT Computational Study of Photoelectrochemical Cell Ruthenium Sensitizers. Journal of the American Chemical Society, 2005. 127(48): pp.16835-16847.

DOI: 10.1021/ja052467l

Google Scholar

[3] Guo, W., et al., Effect of N Dopant Amount on the Performance of Dye-Sensitized Solar Cells Based on N-Doped TiO2 Electrodes. The Journal of Physical Chemistry C, 2011.

Google Scholar

[4] Yum, J.H., et al., Effect of coadsorbent on the photovoltaic performance of zinc pthalocyamine-sensitized solar cells. Langmuir, 2008. 24(10): pp.5636-5640.

DOI: 10.1021/la800087q

Google Scholar

[5] Hanmin, T.H.Z.J.T.Z.W.X.Z.X.Y.S.Y.T.Z.Z.T., Influences of Photo Current Iph on Short-circuit Current Isc of Dye-sensitized Solar Cell. ACTA SCIENTIARUM NATURALIUM UNIVERSITATIS SUNYATSENI, 2009. 48(z2).

Google Scholar

[6] 6. Gratzel, M., Photoelectrochemical cells. Nature, 2001. 414(6861): pp.338-344.

Google Scholar

[7] Gao K W , C.W.Y., Li H L. , Correspondence between hydrogen enhancing dezincification layer2induced st ress and susceptibility to SCC of brass

Google Scholar

[8] MaterialsScience and Engineering A, 2004. 371 p.6.

Google Scholar

[9] Lu H , G.K.W., Chu W Y., Determination of tensile st ress induced by dezincification layer during corrosion for brass. Corrosion Science, 1998. 40(10): p.8.

DOI: 10.1016/s0010-938x(98)00063-8

Google Scholar

[10] Hanmin, T., et al., An improved method to estimate the equivalent circuit parameters in DSSCs. Solar Energy, 2009. 83(5): pp.715-720.

DOI: 10.1016/j.solener.2008.10.019

Google Scholar