Microencapsulated Phase Change Materials and its Application in Thermal-Regulated Fibers

Article Preview

Abstract:

The phase change materials (PCMs) can absorb, store or release large latent heat over a defined temperature range while the materials change phase or state, so they can be potentially used in thermal energy storage. In this paper, a series of microencapsulated phase change materials (MicroPCMs) with n-octadecane and n-dodecanol as core were successfully fabricated respectively, where the styrene-based copolymer, acrylic based copolymer, melamine-formaldehyde resin and polyurea were selected as shell materials. The morphology of these MicroPCMs was observed by scanning electron microscopy (SEM), and the core-shell structure and the shell thickness of microcapsules were also characterized by SEM. In addition, the phase change properties of MicroPCMs were investigated using differential scanning calorimetry (DSC) analysis. Furthermore, thermal-regulated calcium alginate fiber was produced by adding MicroPCMs in wet-spinning process; and the effects of various types of MicroPCMs on fiber was discussed.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

6-9

Citation:

Online since:

July 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] P. Sánchez, M.V. Sánchez-Fernandez, A. Romero, J. F. Rodríguez, L. Sánchez-Silva, Development of thermo-regulating textiles using paraffin wax microcapsules, Thermochim. Acta. 498 (2010)16-21.

DOI: 10.1016/j.tca.2009.09.005

Google Scholar

[2] X.Y Gao, N. Han, X.X. Zhang, W.Y. Yu, Melt-processable acrylonitrile-methyl acrylate copolymers and melt-spun fibers containing MicroPCMs, J. Mater. Sci. 44(2009):5877-5884.

DOI: 10.1007/s10853-009-3830-z

Google Scholar

[3] X.X. Zhang, X.C. Wang, X.M. Tao, K.L. Yick, Energy storage polymer/MicroPCMs blended chips and thermo-regulated fibers, J. Mater. Sci. 40(2005):3729-3734.

DOI: 10.1007/s10853-005-3314-8

Google Scholar

[4] Y.M. Qin, Review: alginate fibres: an overview of the production processes and applications in wound management, Polym. Int. 57(2008):171-180.

Google Scholar

[5] W. Li, G.L. Song, G.Y. Tang, X.D. Chu, S.D. Ma, Morphology, structure and thermal stability of microencapsulated phase change materials with copolymer shell, Energy. 36(2011):785-791.

DOI: 10.1016/j.energy.2010.12.041

Google Scholar

[6] W. Li, X.X. Zhang, X.C. Wang, J.J. Niu, S.Z. Wu, Preparation and characterization of microencapsulated phase change material with low remnant formaldehyde content, Mater. Chem. Phys. 106(2007):437-442.

DOI: 10.1016/j.matchemphys.2007.06.030

Google Scholar

[7] W. Li, X.X. Zhang, X.C. Wang, G.Y. Tang, H.F. Shi, Fabrication and morphological characterization of microencapsulated phase change materials (MicroPCMs) and macrocapsules containing MicroPCMs for thermal energy storage, Energy. 38 (2012) 249-254.

DOI: 10.1016/j.energy.2011.12.005

Google Scholar

[8] X.X. Zhang, Y.F. Fan, X.M. Tao, K.L. Yick, Crystallization and prevention of supercooling of microencapsulated n-alkanes, J. Colloid. Interf. Sci. 281(2005):299–306.

DOI: 10.1016/j.jcis.2004.08.046

Google Scholar