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Effect of P2O5 on Microstructure and Properties of Calcium Aluminoborosilicate Glasses

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Abstract:

In alkaline earth aluminoborosilicate glasses containing P2O5, the changes of structure and properties caused by variations in the ratio P2O5/B2O3 were investigated. The structure was investigated by Fourier transform infrared spectroscopy and nuclear magnetic resonance. The dielectric constant and tangent loss were measured at 1 MHz. Chemical durability was evaluated by weight losses of glass samples after immersion in water. The results indicated that the fraction of four-coordinated boron atoms (N4), chemical durability and dielectric properties increased with increasing P2O5/B2O3 replacements.

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Periodical:

Key Engineering Materials (Volume 538)

Pages:

258-261

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.538.258

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Online since:

January 2013

Authors:

X.H. Zhang, Y.L. Yue, H.T. Wu

Keywords:

Aluminoborosilicate, Chemical Durability, Dielectric Property, P2O5, Structure

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