Studies on Potentiodynamic Polarization Behaviour of Cryorolled Al-Mg-Si Alloy

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Cryorolling is considered to be the prominent processing method to develop high strength light weight alloys. Even though considerable work is available on mechanical properties of cryorolled materials, no detailed studies are available on corrosion behavior of these cryorolled sheets. Al-Mg-Si alloy is cryorolled to 50% and 75% reduction at -196°C and also at room temperature. Potentiodynamic polarization studies were performed on these rolled sheets in 3.5 wt% NaCl solution and the results were compared with those of the annealed and solutionized samples of Al-Mg-Si alloy. Irrespective of the rolling temperature, all the rolled samples, except for LNR 75%, exhibited inferior corrosion resistance compared with those of the reference samples. This is attributed to the large amount of internal stresses and sub-grain network developed during rolling. The rolled samples evidenced peak shift compared to those of the annealed and solutionized samples and higher peak broadening is observed, which is due to the development of higher grain boundary area and enhanced lattice strains along with large dislocation densities. These grain boundaries and dislocation densities are the root cause for the inferior corrosion properties of the rolled samples.

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153-157

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March 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] A.K. Gupta, D.J. Lloyd, S.A. Court, Precipitation hardening processes in an Al–0. 4%Mg–1. 3%Si–0. 25%Fe aluminum alloy, Mater. Sci. Eng. A 301 (2001) 140-146.

DOI: 10.1016/s0921-5093(00)01814-1

Google Scholar

[2] D.A. Chakrabarti, D.E. Laughlin, Phase relations and precipitation in Al-Mg-Si alloys with Cu additions, Prog. Mater Sci. 49 (2004) 389-410.

DOI: 10.1016/s0079-6425(03)00031-8

Google Scholar

[3] S. Esmaeili, X. Wang, D.J. Lloyd, W.J. Poole, On the precipitation-hardening behavior of the Al−Mg−Si−Cu alloy AA6111, Metall. Mater. Trans. A 34 (2003) 751-763.

DOI: 10.1007/s11661-003-0110-4

Google Scholar

[4] R.Z. Valiev, R.K. Islamgaliev, I.V. Alexandrov, Bulk nanostructured materials from severe plastic deformation, Prog. Mater Sci. 45 (2000) 103-189.

DOI: 10.1016/s0079-6425(99)00007-9

Google Scholar

[5] Y. Wang, M. Chen, F. Zhou, E Ma, High tensile ductility in a nanostructured metal, Nature 419 (2002) 912-915.

DOI: 10.1038/nature01133

Google Scholar

[6] N. Rangaraju, T. Raghuram, B. V. Krishna, K. P. Rao, P. Venugopal, Effect of cryo-rolling and annealing on microstructure and properties of commercially pure aluminium, Mater. Sci. Eng. A. 398 (2005) 246-251.

DOI: 10.1016/j.msea.2005.03.026

Google Scholar

[7] T. Shanmugasundaram, B.S. Murty, V. S. Sarma, Development of ultrafine grained high strength Al–Cu alloy by cryorolling, Scr. Mater. 54 (2006) 2013-(2017).

DOI: 10.1016/j.scriptamat.2006.03.012

Google Scholar

[8] S.K. Panigrahi, R. Jayaganthan, Effect of rolling temperature on microstructure and mechanical properties of 6063 Al alloy, Mater. Sci. Eng. A. 492 (2008) 300-305.

DOI: 10.1016/j.msea.2008.03.029

Google Scholar

[9] N. Naga Krishna, A.K. Akash, K. Sivaprasad, R. Narayanasamy, Studies on void coalescence analysis of nanocrystalline cryorolled commercially pure aluminium formed under different stress conditions, Mater. Des. 31 (2010) 3578-3584.

DOI: 10.1016/j.matdes.2010.01.056

Google Scholar

[10] K. Gopala Krishna, Nidhi Singh, K. Venkateswarlu, K.C. Hari Kumar, Tensile behavior of ultrafine grained Al-4Zn-2Mg alloy produced by cryorolling, J. Mater. Engg. Perform. 20 (2011) 1569-1574.

DOI: 10.1007/s11665-011-9843-1

Google Scholar

[11] N. Naga Krishna, K. Sivaprasad, High temperature tensile properties of cryorolled Al-4wt%Cu-3wt%TiB2 in-situ composites, T Indian I Metals, 64 (2011) 63-66.

DOI: 10.1007/s12666-011-0012-x

Google Scholar

[12] V.L. Niranjani, K.C. Hari Kumar, V. Subramanya Sarma, Development of high strength Al-Mg-Si AA6061 alloy through cold rolling and ageing, Mater. Sci. Eng. A. 515 (2009) 169-174.

DOI: 10.1016/j.msea.2009.03.077

Google Scholar

[13] K. Sivaprasad, V. Swarnalatha, V.V. Ravi Kumar, V. Muthupandi, Influence of short annealing treatment on corrosion behavior of cryorolled commercially pure aluminium, Anti Corr. Methods and Mat. 57/1 (2010) 18-20.

DOI: 10.1108/00035591011009691

Google Scholar

[14] K. Gopala Krishna, K. Sivaprasad, T.S.N. Sankara Narayanan, K.C. Hari Kumar, Localized corrosion of an ultrafine grained Al–4Zn–2Mg alloy produced by cryorolling, Corros. Sci. (60) 2012 82-89.

DOI: 10.1016/j.corsci.2012.04.009

Google Scholar