Preparation of Expanded Graphite-Based Composite Electrode and Electrochemical Degradation of Phenol

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Abstract:

Expanded graphite-based carbon/carbon composite (EGC) electrode was prepared by compressed expanded graphite impregnated in sucrose-phosphoric acid solution. The porous texture and microstructure of the composite were analyzed by physical adsorption measurements of N2 adsorption at 77K and SEM. The influence of electrolytic conditions on the phenol degradation was investigated. The results indicated that the EGC electrode was comprised of a graphite framework coated by a thin layer of activated carbon. It could be used as an anode to degrade phenol effectively in the solution by electrochemical oxidation. The data in the experiment showed that the removal efficiency of phenol increased with lowering the initial phenol concentration, increasing the current density and electrolyte concentration.

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Key Engineering Materials (Volumes 562-565)

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874-881

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July 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] N. Kang, D.S. Lee, J. Yoon, Kinetic modeling of Fenton oxidation of phenol and monochlorophenols, Chemosphere 47 (2002) 915-924.

DOI: 10.1016/s0045-6535(02)00067-x

Google Scholar

[2] E. Oguz, B. Keskinler, Z. Celik, Ozonation of aqueous Bomaplex Red CR-L dye in a semi-batch reactor, Dyes Pigments 64 (2005) 101–108.

DOI: 10.1016/j.dyepig.2004.04.009

Google Scholar

[3] B.T. Jiang, S.Y. Zhang, X.Z. Guo, et al, Preparation and photocatalytic activity of CeO2/TiO2 interface composite film, Appl. Surf. Sci. 255 (2009) 5975-5978.

DOI: 10.1016/j.apsusc.2009.01.049

Google Scholar

[4] F.Y. Yi, S.X. Chen, C. Yuan, Effect of activated carbon fiber anode structure and electrolysis conditions on electrochemical degradation of dye wastewater, J. Hazard. Mater. 157 (2008) 79-87.

DOI: 10.1016/j.jhazmat.2007.12.093

Google Scholar

[5] H.S. Awad, N.A. Galwa, Electrochemical degradation of acid blue and basic brown dyes on Pb/PbO2 electrode in the presence of different conductive electrolyte and effect of various operating factors, Chemosphere 61 (2005) 1327–1335.

DOI: 10.1016/j.chemosphere.2005.03.054

Google Scholar

[6] M. Li, C.P. Feng, W.W. Hu, et al, Electrochemical degradation of phenol using electrodes of Ti/RuO2-Pt and Ti/IrO2-Pt, J. Hazard. Mater. 162 (2009) 455-462.

DOI: 10.1016/j.jhazmat.2008.05.063

Google Scholar

[7] M. Sathish, R.P. Viswanath, Electrochemical degradation of aqueous phenols using graphite electrode in divided electrolytic cell, Korean J. Chem. Eng. 22 (2005) 358-363.

DOI: 10.1007/bf02719411

Google Scholar

[8] N.B. Tahar, A. Savall, Electrochemical degradation of phenol in aqueous solution on bismuth doped lead dioxide: acomparison of the activaties of various electrode formlations, J. Appl. Electrochem. 29 (1999) 277-283.

Google Scholar

[9] C. Comninellis, C. Pulgarin, Electrochemical oxidation of phenol for wastewater treatment using SnO2 anodes, J. Appl. Electrochem. 23 (1993) 108-112.

DOI: 10.1007/bf00246946

Google Scholar

[10] F.H. Oliveira, M.E. Osugi, F.M.M. Paschoal, et al, Electrochemical oxidation of an acid dye by active chlorine generated using Ti/Sn(1-X)IrxO2 electrodes, J. Appl. Electrochem. 37 (2007) 583-592.

DOI: 10.1007/s10800-006-9289-6

Google Scholar

[11] J.X. Gao, G.H. Zhao, W. Shi, et al, Microwave activated electrochemical degradation of 2,4-dichlorophenoxyacetic acid at boron-doped diamond electrode, Chemosphere 75 (2009) 519-525.

DOI: 10.1016/j.chemosphere.2008.12.018

Google Scholar

[12] J.F. Marêché, D. Bégin, G. Furdin, et al, Monolithic activated carbons from resin impregnated expanded graphite, Carbon 39 (2001) 771-773.

DOI: 10.1016/s0008-6223(00)00292-x

Google Scholar

[13] H.Z. Zhao, Y. Sun, L.N. Xu, et al, Removal of acid orange 7 in simulated wastewater using a three-dimensional electrode reactor: Removal mechanisms and dye degradation pathway, Chemosphere 78 (2010) 46-51.

DOI: 10.1016/j.chemosphere.2009.10.034

Google Scholar

[14] L.Y. Wei, S.H. Guo, G.X. Yan, et al, Electrochemical pretreatment of heavy oil refinery wastewater using a three-dimensional electrode reactor, Electrochim. acta 55 (2010) 8615-8620.

DOI: 10.1016/j.electacta.2010.08.011

Google Scholar

[15] J.M. Friedrich, C. Ponce-de-León, G.W. Reade, et al, Reticulated vitreous carbon as an electrode material, J. Electroanal. Chem. 561 (2004) 203-217.

DOI: 10.1016/j.jelechem.2003.07.019

Google Scholar

[16] L. Fan, Y.W. Zhou, W.S. Yang, et al, Electrochemical degradation of aqueous solution of amaranth azo dye on ACF under potentiostatic model, Dye Pigments 76 (2008) 440-446.

DOI: 10.1016/j.dyepig.2006.09.013

Google Scholar

[17] Z.M. Shen, W.H. Wang, J.P. Jia, et al, Degradation of dye solution by activated carbon fiber electrode electrolysis system, J. Hazard. Mater. 84 (2001) 107-116.

DOI: 10.1016/s0304-3894(01)00201-1

Google Scholar

[18] B. Habibi, M. Jahanbakhshi, M.H. Pournaghiazar, Electrochemical oxidation and nanomolar detection of acetaminophen at a carbon-ceramic electrode modified by carbon nanotubes: a comparison between multi walled and single walled carbon nanotubes, Microchim. Acta 172 (2011) 147-154.

DOI: 10.1007/s00604-010-0475-1

Google Scholar

[19] W. Li, C. Han, W. Liu, et al, Expanded graphite applied in the catatytic process as catalyst support, Catal. Today 125 (2007) 278-281.

DOI: 10.1016/j.cattod.2007.01.035

Google Scholar

[20] PY X, DAGUERRE E, MENATD D, Composites of expanded natural graphite and in situ prepared activated carbons, Carbon 40 (2002) 1255-1265.

DOI: 10.1016/s0008-6223(01)00285-8

Google Scholar

[21] C.B. Liu, Z.G. Chen, X.L. Cheng, et al, Preparation and structure analysis of expanded graphite-based composites made by phosphoric acid activation, J. Porous Mat. 17 (2010) 425-428.

DOI: 10.1007/s10934-009-9303-6

Google Scholar