Electrode Properties of Nickel-Aluminum Layered Double Hydroxides in Aqueous Electrolyte Solutions

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Abstract:

Electrochemical properties of restacked nanosheets (RS-LDH) of nickel-aluminum layered double hydroxide were investigated for the first time. RS-LDH was prepared by delaminating nickel-aluminum layered double hydroxide powder (powder LDH) into nanosheets and restacking them. RS-LDH and powder LDH showed same discharge capacity of 230 mAhg1 at a current density of 500 mAg1, but RS-LDH showed a larger capacity than powder LDH at a large current density of 1000 mAg1. This increase in capacity was assumed to be attributed to the increased specific surface area and ion conductivity.

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115-118

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July 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] P. Oliva, J. Leonardi, J. F. Laurent, C. Delmas, J. J. Braconnier, M. Figlarz, F. Fievet and A. d. Guibert: J. Power Sources Vol. 8 (1982), p.229.

DOI: 10.1016/0378-7753(82)80057-8

Google Scholar

[2] A. Sugimoto, S. Ishida and K. Hanawa: J. Electrochem. Soc. Vol. 146 (1999), p.1251.

Google Scholar

[3] L. Lei, M. Hu, X. Gao and Y. Sun: Electrochim. Acta Vol. 54 (2008), p.671.

Google Scholar

[4] W. -K. Hu and D. Noreus: Chem. Mater. Vol. 15 (2003), p.974.

Google Scholar

[5] P. V. Kamath, M. Dixit, L. Indira, A. K. Shukla, V. G. Kumar and N. Munichandraiah: J. Electrochem. Soc. Vol. 141 (1994), p.2956.

Google Scholar

[6] L. J. Yang, X. P. Gao, Q. D. Wu, H. Y. Zhu and G. L. Pan: J. Phys. Chem. C Vol. 111 (2007), p.4614.

Google Scholar

[7] N. Iyi, T. Matsumoto, Y. Kaneko and K. Kitamura: Chem. Lett. Vol. 33 (2004), p.1122.

Google Scholar

[8] N. Iyi and T. Sasaki: J. Colloid Interface Sci. Vol. 322 (2008), p.237.

Google Scholar

[9] N. Iyi, Y. Ebina and T. Sasaki: Langmuir Vol. 24 (2008), p.5591.

Google Scholar

[10] A. I. Khan and D. O'Hare: J. Mater. Chem. Vol. 12 (2002), p.3191.

Google Scholar

[11] A. R. R: Journal of the European Ceramic Society Vol. 19 (1999), p.811.

Google Scholar

[12] H. -S. Kim, Y. Yamazaki, J. -D. Kim, T. Kudo and I. Honma: Solid State Ionics Vol. 181 p.883.

Google Scholar