DABCO-Directed Self-Assembly of Pyrene-Centered Porphyrin Pentamers

Abstract:

DABCO (1, 4-diazabicyclo [2.2.2] octane) has been used in combination with pentameric zinc porphyrin-pyrene array 1 to form well-defined supramolecular arrays through axial coordination. The self-assembly process has been investigated by a wide range of spectroscopic methods including UV-vis, fluorescence emission and ¹H NMR techniques.

• Periodical: Key Engineering Materials (Volumes 575-576)
• Pages: 123-129
• DOI: https://doi.org/10.4028/www.scientific.net/KEM.575-576.123
• Online since: September 2013
• Authors: Zhuang Dong Yuan, Jing Xia Wang, Ning Sheng
• Keywords: DABCO, Fluorescence, Porphyrin, Self-Assembly

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