Thermophysical Properties of Ionic Liquid with Thiocyanate and Dicynamide Anions

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Abstract:

In this work, density and viscosity of ionic liquids with dicynamide and thiocyanate anion were obtained. The thermal expansion coefficient values were obtained from the experimental density values. The density and viscosity of the ionic liquids depends on the nature of the cations. The density of the ionic liquids increases in the order of [BMIM]+ < [AMI+ < [BzMI+ < [HEMI+ for dicynamide anion. Both for thiocyanate and dicynamide anions the viscosity values increase in the order of [BMI+ < [AMI+ < [BMI+ < [HEMI+. Moreover, viscosity values of ionic liquids with dicynamide anions are less than their corresponding thiocyanate anion.

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Key Engineering Materials (Volumes 594-595)

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953-957

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December 2013

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] N.V. Plechkova, K.R. Seddon, Applications of ionic liquids in the chemical industry, Chemical Society Reviews, 37 (2008) 123-150.

Google Scholar

[2] E. Frackowiak, G. Lota, J. Pernak, Room-temperature phosphonium ionic liquids for supercapacitor application, Applied physics letters, 86 (2005) 164104-164104-164103.

DOI: 10.1063/1.1906320

Google Scholar

[3] P. Kubisa, Application of ionic liquids as solvents for polymerization processes, Progress in Polymer Science, 29 (2004) 3-12.

DOI: 10.1016/j.progpolymsci.2003.10.002

Google Scholar

[4] H. Sakaebe, H. Matsumoto, K. Tatsumi, Application of room temperature ionic liquids to Li batteries, Electrochimica Acta, 53 (2007) 1048-1054.

DOI: 10.1016/j.electacta.2007.02.054

Google Scholar

[5] S. Pandey, Analytical applications of room-temperature ionic liquids: A review of recent efforts, Analytica chimica acta, 556 (2006) 38-45.

DOI: 10.1016/j.aca.2005.06.038

Google Scholar

[6] D. Han, K.H. Row, Recent applications of ionic liquids in separation technology, Molecules, 15 (2010) 2405-2426.

DOI: 10.3390/molecules15042405

Google Scholar

[7] J.F. Brennecke, E.J. Maginn, Ionic liquids: innovative fluids for chemical processing, AIChE Journal, 47 (2001) 2384-2389.

DOI: 10.1002/aic.690471102

Google Scholar

[8] M. Freemantle, Designer solvents-Ionic liquids may boost clean technology development, Chemical & engineering news, 76 (1998) 32-37.

DOI: 10.1021/cen-v076n013.p032

Google Scholar

[9] K.J. Baranyai, Glen B Deacon, D.R. MacFarlane, J.M. Pringle, J.L. Scott, Thermal degradation of ionic liquids at elevated temperatures, 57, Aust. J. Chem (2004) 145–147.

DOI: 10.1071/ch03221

Google Scholar

[10] M. Smiglak, W.M. Reichert, J.D. Holbrey, J.S. Wilkes, L.Y. Sun, J.S. Thrasher, K. Kirichenko, S. Singh, A.R. Katritzky, R.D. Rogers, Combustible ionic liquids by design: Is laboratory safety another ionic liquid myth? , Chem. Commun., 2554–2556 (2006).

DOI: 10.1039/b602086k

Google Scholar

[11] L.P.N. Rebelo, J.N. Canongia Lopes, J.M.S.S. Esperança, E. Filipe, On the critical temperature, normal boiling point, and vapor pressure of ionic liquids, The Journal of Physical Chemistry B, 109 (2005) 6040-6043.

DOI: 10.1021/jp050430h

Google Scholar

[12] K.R. Seddon, Ionic Liquids for Clean Technology, J. Chem. Technol. Biotechnol, 68 (1997) 351–356.

DOI: 10.1002/(sici)1097-4660(199704)68:4<351::aid-jctb613>3.0.co;2-4

Google Scholar

[13] K. Matsumoto, R. Hagiwara, Y. Ito, Room-temperature ionic liquids with high conductivities and wide electrochemical windows, Electrochemical and solid-state letters, 7 (2004) 41.

DOI: 10.1149/1.1795613

Google Scholar

[14] K.N. Marsh, J.A. Boxall, R. Lichtenthaler, Room temperature ionic liquids and their mixtures—a review, Fluid phase equilibria, 219 (2004) 93-98.

DOI: 10.1016/j.fluid.2004.02.003

Google Scholar

[15] G. Gonfa, M.A. Bustam, T. Murugesan, Z. Man, M.I.A. Mutalib, Thermophysical properties of ionic liquid with thiocyanate anion: Effect of cations, Advanced Materials Engineering and Technology 626 (2012) 686-690.

DOI: 10.4028/www.scientific.net/amr.626.686

Google Scholar

[16] T.L. Greaves, A. Weerawardena, C. Fong, C.J. Drummond, Many protic ionic liquids mediate hydrocarbon-solvent interactions and promote amphiphile self-assembly, Langmuir, 23 (2007) 402-404.

DOI: 10.1021/la062895k

Google Scholar

[17] Z. Gu, J.F. Brennecke, Volume expansivities and isothermal compressibilities of imidazolium and pyridinium-based ionic liquids, Journal of Chemical & Engineering Data, 47 (2002) 339-345.

DOI: 10.1021/je010242u

Google Scholar