Surface Oxidation Behaviour of Cubic BN Powders

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Abstract:

In order to improve the sinterability of the cBN, surface oxidation treatment was conducted to form a B2O3 film on the surface of the cBN powders. The cBN powders (d50 = 7.5 μm) were used as original powders. The heat treatment processes were 500, 800, 900, 950, 980 and 1000 °C holding for 30 minutes, respectively. The oxidation reactions which probably happened were calculated based on the thermodynamics. The experimental results showed that the oxidation starting temperature of cBN powders was higher than 800 °C. The higher the oxidation temperature, the greater the mass gain of the cBN powders.

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Key Engineering Materials (Volumes 602-603)

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544-547

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March 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] D. Shan, Zh. Li, Y. Zhu, H. Ye, K. Gao, Y. Yu, Influence of TiO2 on the physical properties of low-temperature ceramic vitrified bond and mechanical properties of CBN composites, Ceram. Inter. 38 (2012) 4573-4578.

DOI: 10.1016/j.ceramint.2012.02.035

Google Scholar

[2] F. Rebillat, A. Guette, L. Espitalier, C. Debieuvre, R. Naslain, Oxidation Resistance of SiC/SiC Micro and Minicomposites with a Highly Crystallised BN Interphase, J. Eur. Ceram. Soc. 18 (1998) 1809-1819.

DOI: 10.1016/s0955-2219(98)00120-4

Google Scholar

[3] V.A. de Godoy, A.E. Diniz, Turning of interrupted and continuous hardened steel surfaces using ceramic and CBN cutting tools, J. Mater. Process. Technol. 211 (2011) 1014-1025.

DOI: 10.1016/j.jmatprotec.2011.01.002

Google Scholar

[4] N.E. Stakhniv, The study of the influence of cutting conditions on machined surface roughness inturning hardened steels with cutting tools of cBN-based composite, J. Superhard Mater. 35(3) (2013) 166-174.

DOI: 10.3103/s1063457613030064

Google Scholar

[5] W. Grzesik, K. Żak, Friction quantification in the oblique cutting with CBN chamfered tools, Wear 304 (2013) 36-42.

DOI: 10.1016/j.wear.2013.04.020

Google Scholar

[6] M. Hotta, T. Goto, Densification and Phase Transformation of b-SiAlON-Cubic Boron Nitride Composites Prepared by Spark Plasma Sintering, J. Am. Ceram. Soc. 92(8) (2009) 1684-1690.

DOI: 10.1111/j.1551-2916.2009.03098.x

Google Scholar

[7] M. Hotta, T. Goto, Effect of time on microstructure and hardness of bSiAlON-cubic boron nitride composites during spark plasma sintering, Ceram. Inter. 37 (2011) 521-524.

DOI: 10.1016/j.ceramint.2010.09.051

Google Scholar

[8] F. Ye, Zh. Hou, H. Zhang, L. Liu, Y. Zhou, Spark plasma sintering of cBN/b-SiAlON composites, Mater. Sci. and Eng. A 527 (2010) 4723-4726.

DOI: 10.1016/j.msea.2010.04.034

Google Scholar

[9] X. Hou, Z. Yu, Zh. Chen, K.C. Chou, B. Zhao, The Reaction Mechanism and Kinetics of a-BN Powder in Wet Air at 1273 K, J. Am. Ceram. Soc. 96 (6) (2013)1877-1882.

DOI: 10.1111/jace.12276

Google Scholar

[10] D. Ding, W. Zhou, F. Luo, M. Chen, D. Zhu, Dip-coating of boron nitride interphase and its effects on mechanical properties of SiCf/SiC composites, Mater. Sci. and Eng. A 543 (2012) 1-5.

DOI: 10.1016/j.msea.2012.01.118

Google Scholar