Properties of Multilayer NTC Perovskite Thermistors Prepared by Tape Casting, Lamination and Cofiring

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The paper reports on processing and characterization of multilayer NTC (negative temperature coefficient) perovskite thermistors. Three materials La0.8Sr0.2Ti0.4Fe0.6O3, CaTi.0.8Co0.2O3 and CaTi0.9Y0.1O3 with the stable perovskite structure were synthesized by solid state reactions and used for preparation of slurries for tape casting. Green sheets with screen printed internal Pt electrodes were stacked, laminated isostatically and cofired at 1250-1350°C. SEM observations revealed dense, fine-grained microstructure of ceramic layers, lack of delaminations and cracks and a good cooperation between ceramic and Pt electrode layers. Resistance-temperature characteristics of the fabricated multilayer thermistors were measured in the temperature range 20-820°C. The temperature coefficients of resistance were high, ranging from-9.7 to-1%/°C. Two developed compositions CaTi.0.8Co0.2O3 and CaTi0.9Y0.1O3 were found to be suitable for use at a higher temperature range of 150-500°C. The endurance tests showed small resistance changes (below 1%) after long term ageing at 300-400°C.

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507-510

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April 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] A. Feltz, and Pölzl W., Spinel forming ceramics of the system FexNiyMn3-x-yO4 for high temperature NTC thermistor applications, J. Eur. Ceram. Soc. 20 (2000) 2353-2366.

DOI: 10.1016/s0955-2219(00)00140-0

Google Scholar

[2] M. Hrovat, D. Belavic, J. Kita, J. Holc, J. Cilenšek and S. Drnovšek, Thick-film NTC thermistors and LTCC materials: The dependence of the electrical and microstructural characteristics on the firing temperature, J. Eur. Ceram. Soc. 29 (2009) 3265-3271.

DOI: 10.1016/j.jeurceramsoc.2009.05.019

Google Scholar

[3] N. Tachibana, M. Yuasa, T. Kida, N. Yamazoe, K. Shimanoe, Combustion-Type H2 Gas Sensor Using a PTC Thermistor Based on Bi, Na-Co doped BaTiO3 as a Transducer, Sensor Lett. 9 (2011) 21-25.

DOI: 10.1166/sl.2011.1411

Google Scholar

[4] M.N. Muralidharan, E.K. Sunny, K.R. Dayas, A. Seema, K.R. Resmi., Optimization of process parameters for the production of Ni–Mn–Co–Fe based NTC chip thermistors through tape casting route, J. Alloys Compd. 509 (2011) 9363-9371.

DOI: 10.1016/j.jallcom.2011.07.037

Google Scholar

[5] A. Feltz, Perovskite forming ceramics of the system SrxLa1-xTiIVx+yCoIIyCoIII1-x-2yO3 for NTC thermistor applications, J. Eur. Ceram. Soc., 20 (2000) 2367-2376.

DOI: 10.1016/s0955-2219(00)00149-7

Google Scholar

[6] J. Kulawik, D. Szwagierczak, B. Gröger, A. Skwarek, Fabrication and characterization of bulk and thick film perovskite NTC thermistors, Microelectron. Int. 24 (2007) 14-18.

DOI: 10.1108/13565360710745548

Google Scholar

[7] J. Kulawik, D. Szwagierczak, K. Witek, A. Skwarek, B. Gröger, Multilayer Perovskite-Based Thermistors Fabricated by LTCC Technology, Acta Phys. Pol. A 123 (2013) 436-438.

DOI: 10.12693/aphyspola.123.436

Google Scholar