Influences of Working Power on Properties for Boron Films Deposited by R. F. Magnetron Sputtering

Article Preview

Abstract:

Boron and boron-rich boride has attracted considerable attention in the past few years for their wide varieties of structures and property associated with their unusual three-center electron-deficient bonds. Boron film also exhibits many unique and fascinating properties, such as high melting point (~ 2500K) with low density, high harness close to diamond, and excellent thermoelectric property. In this paper, boron (10B) films were prepared on (100) silicon substrate by radio frequency (r. f.) magnetron sputtering method under the different working pressure and power with a target of boron and boron oxide (B:B2O3 40wt%). After 3 hours sputtering deposition, the substrate was covered with boron films tightly. The morphology of deposited films under different temperature was characterized by high resolution scanning electron microscopy (HRSEM), FTIR spectrum (FTIR), Raman spectrum (Raman). The results show that the film contains boron and little oxygen. At last, the growth mechanism of B film was analyzed.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

210-213

Citation:

Online since:

November 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] J. Donohue, The Structures of the Elements, Krieger, Malabar, New Jersey, (1982).

Google Scholar

[2] Limin Cao, Ze Zhang, Liling Sun, Well-Aligned Boron Nanowire Arrays, Adv. Mater. 13 (2001) 1701-1704.

Google Scholar

[3] Koun Shirai, Shunichi Gonda, Characterization of hydrogenated amorphous boron films prepared by electron cyclotron resonance plasma chemical vapor deposition method, J. Appl. Phys. 67 (1990) 6286-6291.

DOI: 10.1063/1.345145

Google Scholar

[4] S. H. Moon, J. H. Yun, H. N. Lee, et al., High critical current densities in superconducting MgB2 thin films, Appl. Phys. Lett. 79 (2001) 2429-2431.

DOI: 10.1063/1.1407854

Google Scholar

[5] Zhongke Wan, Yoshiki Shimizu, et al., Fabrication of crystallized boron films by laser ablation, Journal of Solid State Chemistry. 177 (2004) 1639–1645.

DOI: 10.1016/j.jssc.2003.12.018

Google Scholar

[6] L.J. Oblonsky, T.M. Devine, A surface enhanced Raman spectroscopic study of The Passive films formed in borate buffer on iron, nickel, chromium and stainless steel, Corrosion Science. 37 (1995) 17-41.

DOI: 10.1016/0010-938x(94)00102-c

Google Scholar

[7] H Werheit, V Filipov, U Kuhlmann, et al., Raman effect in icosahedral boron-rich solids. Sci. Technol. Adv. Mater. 11. 2 (2010) 023001.

Google Scholar

[8] P. Salas, R. Borja-Urby, L.A. Diaz-Torresb, et al., Structural and photoluminescence study of Er-Yb codoped nanocrystalline ZrO2-B2O3 solid solution, Materials Science and Engineering B. 177 (2012) 1423-1429.

DOI: 10.1016/j.mseb.2012.01.009

Google Scholar

[9] Norman B. Colthup, Lawrence H. Daly, Stephen E. Wiberley: Introduction to Infrared and Raman Spectroscopy, (1990).

DOI: 10.1021/ed042pa322

Google Scholar