The Possibility of Deposition of Diamond and DLC Coatings by PACVD Method

Article Preview

Abstract:

The Diamond like carbon (DLC) and diamond coatings were deposited on a steel substrate using plasma assisted chemical vapor deposition (PA CVD) method. The parameters of deposition were analyzed in relation to the effectiveness of the process and the quality of coatings. It was found that the DLC coatings formed only at specific conditions of temperature and pressure of precursor gases. The characterization of coatings were performed by Raman spectromicroscopy, X-ray diffraction and infrared spectromicroscopy which allowed us to recognize the dominant phases and the distribution of bonds inside the coatings. The chemical bonds such as sp2 C-C, sp3 CH3/CH2 and sp3 CH were found in microstructure coatings. The maps of distribution of bonds in the coatings were also prepared. Additionally, their microstructure was investigated by scanning electron microscopes which have revealed a spherical grains morphology of the coatings.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

111-115

Citation:

Online since:

April 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] P.W. May, CVD Diamond – a New Technology for the Future?, Endeavour Magazine. 19 (3) (1995) 101-106.

DOI: 10.1016/0160-9327(95)97494-s

Google Scholar

[2] L.L. Regel, W.L. Wilcox, Diamond film deposition by chemical vapor transport, Acta Astronautica, 48 (2-3) (2001) 129-144.

DOI: 10.1016/s0094-5765(00)00155-7

Google Scholar

[3] H. Liu, D.S. Dandy, Studies on nucleation process in diamond CVD: an overview of recent developments, Diamond and Related Materials, 4 (1995) 1173-1188.

DOI: 10.1016/0925-9635(96)00297-2

Google Scholar

[4] Q.H. Fan, A. Fernandes, J. Gracio, Diamond coating on steel with a titanium interlayer, Diamond and Related Materials, 7 (1998) 603-606.

DOI: 10.1016/s0925-9635(97)00287-2

Google Scholar

[5] G. Negrea, g. Vermesan, Investigations of diamond layers growth on steel, Journal of Optoelectronics and Advanced Materials, 2 (5) (2000), 698-703.

Google Scholar

[6] S. Schwarz, Y. Musayev, S.M. Rosiwal, C. Schaufler, R.F. Singer, H. Meerkamm, High temperature diffusion chromizinng as a successful method for CVD-diamond coating of steel, Diamond and Related Materials, 11 (2002) 757-762.

DOI: 10.1016/s0925-9635(01)00710-5

Google Scholar

[7] Y.S. Li, A. Hirose, Direct coating of nanophase diamond films on steel substrate, Diamond and Related Materials, 433 (2006) 150-153.

DOI: 10.1016/j.cplett.2006.11.042

Google Scholar

[8] P.K. Chu, L. Li, Characterization of amorphous and nanocrystalline carbon films, Materials Chemistry and Physics, 96 (2006) 253-277.

DOI: 10.1016/j.matchemphys.2005.07.048

Google Scholar

[9] M. Poręba M., M.W. Richert, J. Sieniawski, Evaluation of DLC coatings on IN718 alloy produced by glow discharge plasma assisted CVD method, Inżynieria Materiałowa, 4 (2014) 295-298.

Google Scholar

[10] W. Kaczorowski, P. Niedzielski, M. Cłapa, S. Mitura, Characterization of carbon coatings deposited by MW-RF PACVD method, Inżynieria Materiałowa, 5 (2005) 239-241.

Google Scholar

[11] R.E. Shroder, R.J. Nemanich, J.T. Glass, Analysis of the composite structures id diamond thin films by Raman spectroscopy, Physical Review, 41 (6) (1990) 3738-3745.

DOI: 10.1103/physrevb.41.3738

Google Scholar

[12] A. C. Ferrari, Determination of bonding in diamond-like carbon by Raman spectroscopy, Diamond and Related Materials, 11 (2002) 1053-1061.

DOI: 10.1016/s0925-9635(01)00730-0

Google Scholar

[13] A. Gicquel, K. Hassouni, F. Silva, J. Achard, CVD diamond films: from growth to applications, Current Applied Physics, 1 (2001) 479-496.

DOI: 10.1016/s1567-1739(01)00061-x

Google Scholar