Green Approach for the Reduction of Graphene Oxide by Thai Shallot

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Abstract:

In this paper, we used shallots in the reduction of graphene oxide for the first time. Flavone, sulfur-containing compounds, and polyphenolic derivatives in the bulb of shallot acted as good reducing agent for the reduction of GO. The GO and reduced graphene oxide (RGO) were characterized by scanning electron microscopy (SEM), ultraviolet (UV)-visible spectroscopy, thermogravimetric analysis (TGA) and Raman spectroscopy. GO and RGO were the transparent sheets with the sheet edges tend to scroll and fold slightly. RGO showed a maximum absorption peak at 267 nm and had better thermal stability than graphene oxide. Raman spectra indicated removal of oxygen at the surface of GO and formation of the defect in the graphene sheet.

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Key Engineering Materials (Volumes 675-676)

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696-699

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January 2016

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© 2016 Trans Tech Publications Ltd. All Rights Reserved

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[1] D. Zhang, J. Tong, B. Xia, Humidity-sensing properties of chemically reduced graphene oxide/polymer nanocomposite film sensor based on layer-by-layer nano self-assembly, Sensors Actuat B 197 (2014) 66–72.

DOI: 10.1016/j.snb.2014.02.078

Google Scholar

[2] Y. Li, J. Song, J. Yang, Graphene models and nano-scale characterization technologies for fuel cell vehicle electrodes, Renew Sust Energ Rev 42 (2015) 66–77.

DOI: 10.1016/j.rser.2014.10.005

Google Scholar

[3] V. Sahu et al., Heavily nitrogen doped, graphene supercapacitor from silk cocoon, Electrochim Acta 160 (2015) 244–253.

DOI: 10.1016/j.electacta.2015.02.019

Google Scholar

[4] R. Justin, B. Chen, Characterisation and drug release performance of biodegradable chitosan–graphene oxide nanocomposites, Carbohyd Polym 103 (2014) 70– 80.

DOI: 10.1016/j.carbpol.2013.12.012

Google Scholar

[5] F.S. Al-Hazmi et al., One pot synthesis of graphene based on microwave assisted solvothermal technique, Synthetic Met 200 (2015) 54–57.

DOI: 10.1016/j.synthmet.2014.12.028

Google Scholar

[6] J.S.Y. Chia et al., A novel one step synthesis of graphene via sonochemical-assisted solvent exfoliation approach for electrochemical sensing application, Chem Eng J 249 (2014) 270–278.

DOI: 10.1016/j.cej.2014.03.081

Google Scholar

[7] E. Cappelli, S. Orlando, M. Servidori, C. Scilletta, Nano-graphene structures deposited by N-IR pulsed laser ablation of graphite on Si, Appl Surf Sci 254 (2007) 1273–1278.

DOI: 10.1016/j.apsusc.2007.09.098

Google Scholar

[8] N. Lisi et al., Rapid and highly efficient growth of graphene on copper by chemical vapor deposition of ethanol, Thin Solid Films 571 (2014) 139–144.

DOI: 10.1016/j.tsf.2014.09.040

Google Scholar

[9] Y. Su, X. Gao, J. Zhao, Reaction mechanisms of graphene oxide chemical reduction by sulfur-containing compounds, Carbon 67 (2014) 146–155.

DOI: 10.1016/j.carbon.2013.09.073

Google Scholar

[10] T. Kuila et al., A green approach for the reduction of graphene oxide by wild carrot root, Carbon 50 (2012) 914–921.

DOI: 10.1016/j.carbon.2011.09.053

Google Scholar

[11] S. Thakur, N. Karak, Green reduction of graphene oxide by aqueous phytoextracts, Carbon 50 (2012) 5331–5339.

DOI: 10.1016/j.carbon.2012.07.023

Google Scholar

[12] N. Leelarungrayub et al., Quantitative evaluation of the antioxidant properties of garlic and shallot preparations, Nutrition 22 (2006) 266–274.

DOI: 10.1016/j.nut.2005.05.010

Google Scholar