Influences of Stirring Speed and Post Annealing Temperature on the Properties of Zinc Oxide Colloid Prepared by Sol-Gel Spin Coating Method

Article Preview

Abstract:

Zinc oxide (ZnO) colloid has drawn significant attention recently due to its wide range of potential applications such as photonic crystals, solar cells, sensors, and other optical devices. In this work, low cost sol-gel spin coating technique was employed to synthesis ZnO colloid. The influences of stirring speed and post annealing temperature on the properties of ZnO colloid was investigated. The structural and optical properties of ZnO colloid was characterized using field-emission scanning electron microscopy (FESEM) and ultraviolet-visible (UV-Vis) spectrophotometer, respectively. Subsequently, Tauc method was used to estimate the optical band gap of the ZnO colloid based on the optical transmittance data. The effects of the stirring speed and post annealing temperature on the structural and optical properties of ZnO colloid are revealed and discussed in this paper. It was found that ZnO colloid prepared by the stirring speed of 500rpm and 400°C post annealing temperature demonstrates the best dispersity quality of colloid system.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

159-163

Citation:

Online since:

July 2016

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2016 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] A. A. Ashrafi, A. Ueta, H. Kumano, and I. Suemune, Role of ZnS buffer layers in growth of zincblende ZnO on GaAs substrates by metalorganic molecular-beam epitaxy, J. Cryst. Growth, vol. 221, no. 1–4, p.435–439, Dec. (2000).

DOI: 10.1016/s0022-0248(00)00732-6

Google Scholar

[2] D. C. Look, Recent advances in ZnO materials and devices, Mater. Sci. Eng. B, vol. 80, no. 1–3, p.383–387, Mar. (2001).

Google Scholar

[3] Y. Zhang, M. Fu, J. Wang, D. He, and Y. Wang, Photonic crystal heterostructures fabricated by TiO2 and ZnO inverse opals using colloidal crystal template with single kind of microspheres, Opt. Mater. (Amst)., vol. 34, no. 11, p.1758–1761, Sep. (2012).

DOI: 10.1016/j.optmat.2012.04.014

Google Scholar

[4] H. Wang, K. P. Yan, J. Xie, and M. Duan, Fabrication of ZnO colloidal photonic crystal by spin-coating method, Mater. Sci. Semicond. Process., vol. 11, no. 2, p.44–47, Apr. (2008).

DOI: 10.1016/j.mssp.2008.08.005

Google Scholar

[5] E. Fazio, A. Cacciola, A. M. Mezzasalma, G. Mondio, F. Neri, and R. Saija, Modelling of the optical absorption spectra of PLAL prepared ZnO colloids, J. Quant. Spectrosc. Radiat. Transf., vol. 124, no. 0, p.86–93, Jul. (2013).

DOI: 10.1016/j.jqsrt.2013.02.028

Google Scholar

[6] H. Heiskanen, P. Denifl, P. Pitkänen, and M. Hurme, Effect of preparation conditions on the properties of microspheres prepared using an emulsion-solvent extraction process, Chem. Eng. Res. Des., vol. 90, no. 10, p.1517–1526, Oct. (2012).

DOI: 10.1016/j.cherd.2012.02.008

Google Scholar

[7] H.J. Zhu, X.M. Liu, H. Yang, and X.D. Shen, Effect of the stirring rate on physical and electrochemical properties of LiMnPO4 nanoplates prepared in a polyol process, Ceram. Int., vol. 40, no. 5, p.6699–6704, Jun. (2014).

DOI: 10.1016/j.ceramint.2013.11.131

Google Scholar

[8] L. Irimpan, V. P. N. Nampoori, P. Radhakrishnan, A. Deepthy, and B. Krishnan, Size dependent fluorescence spectroscopy of nanocolloids of ZnO, J. Appl. Phys., vol. 102, no. 6, (2007).

DOI: 10.1063/1.2778637

Google Scholar

[9] I. M. Krieger and F. M. O'Neill, Diffraction of light by arrays of colloidal spheres, J. Am. Chem. Soc., vol. 90, no. 12, p.3114–3120, (1968).

DOI: 10.1021/ja01014a025

Google Scholar

[10] J. Tauc, R. Grigorovici, and A. Vancu, Optical Properties and Electronic Structure of Amorphous Germanium, Phys. status solidi, vol. 15, no. 2, p.627–637, (1966).

DOI: 10.1002/pssb.19660150224

Google Scholar

[11] H. J. Chang, C. Z. Lu, Y. S. Wang, C. S. Son, S. Il Kim, Y. H. Kim, and I. H. Choi, Optical properties of ZnO nanocrystals synthesized by using sol-gel method, J. Korean Phys. Soc., vol. 45, no. 4, p.959–962, (2004).

Google Scholar

[12] M. Pudukudy, A. Hetieqa, and Z. Yaakob, Synthesis, characterization and photocatalytic activity of annealing dependent quasi spherical and capsule like ZnO nanostructures, Appl. Surf. Sci., vol. 319, no. 0, p.221–229, Nov. (2014).

DOI: 10.1016/j.apsusc.2014.07.050

Google Scholar