Application of Aluminum Nanopowder for Pure Hydrogen Production

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The problems of hydrogen energetic as well as a method of high pure hydrogen obtaining are presented in the paper. It was suggested to use the reaction of aluminium nanopowder with water, as the reaction proceeds with high rate even at ambient conditions (the rate of hydrogen emission reached 18 ml/(s∙g)) and high degree of conversion (up to 100 %). The unreasonableness of the replacement of aluminium nanopowder to coarse-grained powder in this reaction due to the low efficiency is shown in the article. As a solution for pure hydrogen obtaining, a phenomenon of self-heating of aluminum nanoparticles and the resulting hydrogen, as well as the effect of its high-temperature diffusion through the membrane of ultrahigh molecular weight polyethylene were used.

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261-266

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September 2016

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© 2016 Trans Tech Publications Ltd. All Rights Reserved

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[1] B.E. Gelfand, O.E. Popov, B.B. Chayvanov, Hydrogen: the parameters of combustion and explosion, FIZMATLIT, Moscow, (2008).

Google Scholar

[2] S.V. Digonskij, V.V. Ten, Unknown hydrogen, Nauka, Saint-Petersburg, (2006).

Google Scholar

[3] Zhen-Yan Deng, Jose M.F. Ferreira, Yoshihisa Tanaka, Jinhua Ye, Physicochemical Mechanism for the Continuous Reaction of γ-Al2O3-Modified Aluminum Powder with Water, J. of the American Ceram. Soc. 90, 5 (2007) 1521-1526.

DOI: 10.1111/j.1551-2916.2007.01546.x

Google Scholar

[4] V.V. Zhilin, A.K. Lokenbakh, L.K. Lepin, Interaction ultrafine aluminum with water and aqueous solutions, Proc. of the Latvian Acad. of Scienc. Ser. Chem. 2 (1986) 151-161.

Google Scholar

[5] A.P. Lyashko, A.A. Medvinskij, G.G. Saveljev, et al., Features of the interaction of sub-micron aluminuim powder with liquid water: macrokinetics, products, appearance of self-heating, Kinetics and Catalysis. 31, 4 (1990) 967-972.

Google Scholar

[6] A.P. Astankova, A.P. Ilyin, A.Y. Godymchuk, The effect of hot hydrogen in the water boiling process, Bulletin of the Tomsk Polytech. Univers. 310, 3 (2007) 73-77.

Google Scholar

[7] O.B. Nazarenko, A.P. Ilyin, D.V. Tikhonov, Electric explosion of conductors: obtaining of metal nanopowders and refractory non-metallic compounds, LAP LAMBERT Academik Publishing, Saarbrucken, Germany, (2012).

Google Scholar

[8] W.W. Wendlandt, Thermal Methods of Analysis, John Wiley & Sons, New York, (1974).

Google Scholar

[9] A.P. Ilyin, A.V. Korshunov, L.O. Tolbanova Application of aluminum nanopowder in hydrogen energy, Bulletin of the Tomsk Polytech. Univers. 311, 4 (2007) 10-14.

Google Scholar

[10] A. Yu. Godymchuk, A.P. Ilyin, A.P. Astankova Aluminium nanopowder oxidation in liquid water at heating, Bulletin of the Tomsk Polytech. Univers. 310, 1 (2007) 102-104.

Google Scholar

[11] А.P. Ilyin, A.A. Gromov, V.G. Merkulov, A.V. Mostovshchikov Composition of impurities and trace substances in the aluminum nanopowder and its combustion products in air, Russ. Phys. J., 58, 6/2 (2015) 101-105.

DOI: 10.1063/1.5027214

Google Scholar