Advances in Microcellular Foam Processing of PLA

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Abstract:

PLA is a bio-based biodegradable plastic, which has excellent biocompatibility and biodegradability. Because the mechanical properties of microcellular foaming material is similar to petroleum-based plastics (PS), PLA foams have been considered as ideal alternative materials. However, PLA has several inherent drawbacks such as low melt strength and slow crystallization kinetics, which severely inhibit the PLA foaming process to produce high-density forms and uniform cell morphology. By adding a chain extender or nanoparticles, and blending with other biological materials, these ways could effectively enhance the expansion ratio and the cell density of PLA and improve the mechanical properties of PLA foams. The most current investigations on microcellular foaming of PLA were reviewed in the article, and outlook of PLA foams was raised.

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68-72

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November 2016

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© 2017 Trans Tech Publications Ltd. All Rights Reserved

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[1] ZHANG Yuxia, LIU Xue, LIU Bengang, et al. Foaming Progress biodegradable polymers. Chinese Plastic, 2012, 26(4), 4-15.

Google Scholar

[2] LEI Yanxiang. The present situation and development prospect of PLA technology and market. Petroleum &Petrochemical, 2007, 15(1), 39-43.

Google Scholar

[3] Drum right R E, Gruber P R, Henton D E. Polylactic acid technology. Advanced Materials, 2000, 12(23), 1841-1846.

DOI: 10.1002/1521-4095(200012)12:23<1841::aid-adma1841>3.0.co;2-e

Google Scholar

[4] Lim LT, Auras R, Rubino M. Processing technologies for poly (lactic acid). Prog Polym Sci, 2008, 33(8), 20-52.

Google Scholar

[5] Di Y, Iannace S, Di Maio E, Nicolais L. Reactively modified poly(lactic acid): properties and foam processing. Macromol Mater Eng, 2005, 290(11), 1083–1090.

DOI: 10.1002/mame.200500115

Google Scholar

[6] Li G, Li H, Turng LS, Gong S, Zhang C. Measurement of gas solubility and diffusivity in polylactide. Fluid Phase Equilib, 2006, 246(1-2), 158-166.

DOI: 10.1016/j.fluid.2006.05.030

Google Scholar

[7] Mahmood SH, Keshtkar M, Park CB. Determination of carbon dioxide solubility in PLA with accurate PVT properties. J Chem Thermodyn, 2013, 70, 13-23.

DOI: 10.1016/j.jct.2013.10.019

Google Scholar

[8] Takada M, Hasegawa S, Ohshima M. Crystallization kinetics of poly(l-lactide) in contact with pressurized CO2. Polym Eng Sci, 2004, 44(1), 186-196.

DOI: 10.1002/pen.20017

Google Scholar

[9] Nofar M, Zhu W, Park CB. Effect of dissolved CO2 on the crystallization behavior of linear and branched PLA. Polymer, 2012, 53, 3341-3353.

DOI: 10.1016/j.polymer.2012.04.054

Google Scholar

[10] Taki K, Kitano D, Ohshima M. Effect of growing crystalline phase on bubble nucleation in poly( l-lactide)/CO2 batch foaming. Ind Eng Chem Res, 2011, 50(6), 3247–52.

DOI: 10.1021/ie101637f

Google Scholar

[11] Corre YM, Maazouz A, Duchet J, Reignier J. Batch foaming of chain extended PLA with supercritical CO2: influence of the rheological properties and the process parameters on the cellular structure. J Supercrit Fluids, 2011, 58(1), 177-188.

DOI: 10.1016/j.supflu.2011.03.006

Google Scholar

[12] S Pilla, A Kramschuster, S Gong, A Chandra L-T, Solid and microcellular PLA-carbon nanotube nanocomposites. Intern Polymer Processing, 2007, 22(5), 418-428.

DOI: 10.3139/217.2071

Google Scholar

[13] DI Y W, Iannace S, DI M E, et al. Poly(lactic acid)/organoclay nanocomposites: Thermal, rheological properties and foam processing. Journal of Polymer Science Part B-Polymer Physics, 2005, 43(6), 689-698.

DOI: 10.1002/polb.20366

Google Scholar

[14] LU Xiuling. Preparatioa and High-Pressure Vessel Faaming of Poly(lactic acid)/ Acetylated Starch Blends and Their Nanocompasites. Guangzhou, South China University of Technology, (2012).

Google Scholar

[15] YUAN Hua, ZHAO Qiufeng, LIU Zhiyong. Research on the composite foam (I) of PLA/Starch Composites: A Study on the foaming process. FRP / Composites, 2009, 1, 42-46.

Google Scholar

[16] Andrew Chow, Esther Richards, Reza Rizvi et al. Biodegradable Composite Foams of PLA and PHBV Using subcritical CO2. J Polym Environ, 2008, 16, 258-266.

DOI: 10.1007/s10924-008-0110-y

Google Scholar

[17] Hwang SS, Hsu PP, Yeh JM, Chang KC, Lai YZ. The mechanical/thermal properties of microcellular injection-molded Poly(lactic acid) nanocomposites. Polymer Composites, 2009, 30(11), 1625-1630.

DOI: 10.1002/pc.20736

Google Scholar

[18] Adam Kramschuster, Lih-Sheng Turng. An Injection Molding Process for Manufact- -uring Highly Porous and Interconnected Biodegradable Polymer Matrices for Use as Tissue Engineering Scaffolds. Journal of Biomedical Materials Research Part B: Applied Biomaterials, 2009, 10(2), 366-376.

DOI: 10.1002/jbm.b.31523

Google Scholar

[19] Ray SS, Okamoto M. New Poly(lactic acid)/layered silicate nanocomposites. Macromol Mater Eng, 2003, 288(12), 936-944.

DOI: 10.1002/mame.200300156

Google Scholar

[20] JIANG Shanshan. Research On the preparation and foaming process of PLA/OMMT nano- -composites. Guangzhou: South China University of Technology, (2011).

Google Scholar

[21] Srikanth Pilla, Seong G. Kim, et al. Microcellular extrusion foaming of PLA/poly (butylenes adipate-co-terephthalate) blends. Materials Science and Engineering, 2010, 30(4), 255-262.

DOI: 10.1016/j.msec.2009.10.010

Google Scholar