Effect of Small Amount BaTiO3 on Properties of K0.02Na0.98NbO3 Ceramics with Various Sintering Temperature Prepared by Molten Salt Method

Article Preview

Abstract:

In the research, the properties of potassium sodium niobate – barium titanate [(1-x)K0.02Na0.98NbO3–(x)BaTiO3: (1-x)KNN–(x)BT] ceramics prepared by molten salt method with various molecular weight of BT or x are 0 and 0.05 were investigated. The calcined powders of pure K0.02Na0.98NbO3 and (0.95) K0.02Na0.98NbO3-(0.05) BaTiO3 were pressed and sintered at 1250 – 1325 °C and 1225 – 1300 °C for 2h, respectively. It was found that, the samples showed phase structure changing from monoclinic to orthorhombic with small amount BaTiO3 addition. The densification of K0.02Na0.98NbO3 ceramics and dielectric properties were improved with the addition of BaTiO3. The (0.95)K0.02Na0.98NbO3–(0.05)BaTiO3 ceramics sintered at 1250 °C showed maximum density and dielectric constant (∼8035), which was even comparable with that of K0.02Na0.98NbO3 ceramics sintered at 1225 – 1300 °C.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

129-132

Citation:

Online since:

November 2016

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2017 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] B. Jaffe, W.R. Cook, H. Jaffe. Piezoelectric Ceramics. Academic Press: New York, (1971).

Google Scholar

[2] H. Du, S. Qu, J. Che, Z. Liu, X. Wei, Z. Pei, The Effect of Composition on Microstructure and Properties of PNW-PMS-PZT Ceramics for High-powder Pizoelectic Tansformer, Mater Sci Eng. A. 393 (2005) 36–41.

DOI: 10.1016/j.msea.2004.09.046

Google Scholar

[3] Z.P. Yang, Y.F. Chang, H. Li, Piezoelectric and Dielectric Properties of PZT-PZN-PMS Ceramics Prepared by Molten Salt Synthesis Method, Mater Res Bull. 40 (2005) 2110–2119.

DOI: 10.1016/j.materresbull.2005.07.010

Google Scholar

[4] Y. Saito, H. Takao, I. Tani, T. Nonoyama, K. Takatori, T. Homma, T. Nagaya, M. Nakamura. Lead-free Piezoceramics, Nature. 432 (2004) 84–87.

DOI: 10.1038/nature03028

Google Scholar

[5] B.Q. Ming, J.F. Wang, P. Qi, G.Z. Zang, Piezoelectric Properties of (Li, Sb, Ta) Modified (Na, K)NbO3 Lead-free Ceramics, J Appl Phys. 101 (2007) 054103: 1–054103: 4.

DOI: 10.1063/1.2436923

Google Scholar

[6] K. Wang, J.F. Li, Domain Engineering of Lead-free Li-modified (K, Na)NbO3 Polycrystals with Highly Enhanced Piezoelectricity, Adv Funct Mater 2010 (20) 1924–(1929).

DOI: 10.1002/adfm.201000284

Google Scholar

[7] S. Miyake, R. Ueda, On transitional region in phase change of barium titanate, J Phys Soc Jpn. 6 (1948) 709.

Google Scholar

[8] W.J. Merz, The electric and optical behavior of BaTiO3 single-domain crystals, Phys Rev, 76 (1949) 1221–1225.

Google Scholar

[9] J. Zeng, Zheng L, Li G, Cao Z, Zhao K, Yin Q, Politova ED. Phase Transition and Electrical Properties of (1−x)K0. 02Na0. 98NbO3–xBaTiO3 Ceramics, J. Alloys Compd. 509 (2011) 5858–5862.

DOI: 10.1016/j.jallcom.2011.02.152

Google Scholar