Titanate-Based Surface Modification of Paper Waste Particles and its Impact on Rigid Polyurethane Foam Properties

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Producing particulate filled polymer composites, even dispersion and sufficient adhesion between filler and polymer matrix is of great importance. In order to solve these issues, methodologies, such as ultrasonic dispersing and coupling agents, are proposed. The impact of particle surface modification with three different titanate coupling agents having the tradenames of TCA L44, TCA L38 and TCA K44 on paper waste sludge particles surface, polyurethane foam composite density, compressive and tensile strengths as well as water absorption and water vapour permeability is evaluated. Apparently, titanates form layer on the particle surface, thus increasing the interfacial adhesion between particles and polymer matrix. Basing on the obtained results, the optimal amount and type of titanate is 1 wt.% of TCA K44.

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58-62

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December 2016

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© 2017 Trans Tech Publications Ltd. All Rights Reserved

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[1] European Union Council (EUC), EU sustainable development strategy, Brussels, (2006).

Google Scholar

[2] Y. Lin, S. Zhou, F. Li, Y. Lin, Utilization of municipal sawage sludge as additive for the production of eco-cement, J. Hazard. Mater. 213-214 (2012) 457-465.

DOI: 10.1016/j.jhazmat.2012.02.020

Google Scholar

[3] F. Gallardo, M. Cea, G.R. Tortella, M.C. Diez, Effect of pulp mill sludge on soil characteristics, microbial community and vegetal productionof lolium perenne, J. Environ. Manage. 95 (2012) 193-198.

DOI: 10.1016/j.jenvman.2010.11.001

Google Scholar

[4] T. Bao, T. Chen, M.L. Wille, D. Chen, S. You, J. Bian, C. Qing, W. Wu, R.L. Frost, Production of zeolite composite filters using waste paper pulpa s slow release carbon source and performance investigation in a biological aerated filtre, J. Water Process Eng. 9 (2016).

DOI: 10.1016/j.jwpe.2015.11.009

Google Scholar

[5] J.A. Cusidó, L.V. Cremades, C. Soriano, M. Devant, Incorporation of paper sludge in clay brick formulation: ten years of industrial experience, Appl. Clay Sci. 108 (2015) 191-198.

DOI: 10.1016/j.clay.2015.02.027

Google Scholar

[6] H.S. Wong, R. Barakat, A. Alhiladi, M. Saleh, C.R. Cheeseman, Hydrophobic concrete using waste paper sludge ash, Cem. Conc. Res. 70 (2015) 9-20.

DOI: 10.1016/j.cemconres.2015.01.005

Google Scholar

[7] V. Ferrándiz-Mas, T. Bond, E. García-Alcocel, C.R. Cheeseman, Lightweight mortars containing expanded polystyrene and paper sludge ash, Constr. Build. Mater. 61 (2014) 285-292.

DOI: 10.1016/j.conbuildmat.2014.03.028

Google Scholar

[8] C. Jin, S. Han, J. Li, Q. Sun, Fabrication of cellulose-based aerogels from waste newspaper without any pretreatment and their use for absorbents, Carbohydr. Polym. 123 (2015) 150-156.

DOI: 10.1016/j.carbpol.2015.01.056

Google Scholar

[9] P. Bajpai, Management of Pulp and Paper Mill Waste, in: P. Bajpai, Generation of waste in pulp and paper mills, Springer International Publishing, Cham, 2015, pp.9-17.

DOI: 10.1007/978-3-319-11788-1_2

Google Scholar

[10] C.A. Wah, L.Y. Choong, G.S. Neon, Effects of titanate coupling agent on rheological behaviour, dispersion characteristics and mechanical properties of talc filled polypropylene, Eur. Polym. J. 36 (2000) 789-801.

DOI: 10.1016/s0014-3057(99)00123-8

Google Scholar

[11] M.A. Usman, S.O. Adeosun, G.O. Osifeso, Optimum calcium carbonate filler concentration for flexible polyurethane foam composite, J. Miner. Mater. Charact. Eng. 11(2012) 311-320.

DOI: 10.4236/jmmce.2012.113023

Google Scholar

[12] M. Šulcienė, A. Karalius, I. Matijošytė, Chemo-enzymatic route for the production of biopolyol from rapeseed oil, Curr. Org. Chem. 18 (2014) 3037-3043.

DOI: 10.2174/138527281823141212105146

Google Scholar

[13] H. Ismail, L. Mega, H.A. Khalil, Effect of a silane coupling agent on the properties of white rice husk ash-polypropylene/natural rubber composites, Polym. Int. 50 (2001) 606-611.

DOI: 10.1002/pi.673

Google Scholar

[14] W.L. Tham, W.S. Chow, Z.A.M. Ishak, Effect of titanate coupling agent on the mechanical, thermal and morphological properties of poly(methyl methacrylate)/hydroxyapatite denture base composites, J. Compos. Mater. 45(2011) 2335-2345.

DOI: 10.1177/0021998311401085

Google Scholar