Preparative Solid Phase Extraction for the Purification of Levoglucosan Obtained from Lignocellulose

Article Preview

Abstract:

Automated preparative scale solid phase extraction (SPE) has been used to separate levoglucosan – a valuable platform chemical from the liquid products of wood pyrolysis. The sorbent for SPE was a strongly basic anion exchange resin in OH-form. Separation of levoglucosan could be done with water as the eluent, the regeneration of the resin was done with a NaCl solution. Up-scaling the purification of levoglucosan is a step forward industrial production of this chemical.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

82-86

Citation:

Online since:

December 2016

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2017 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] J. Lian, M. Garcia-Perez, S. Chen, Fermentation of levoglucosan with oleaginous yeasts for lipid production, Bioresource Technol. 133 (2013) 183-189.

DOI: 10.1016/j.biortech.2013.01.031

Google Scholar

[2] A.F. Sviridov, Stereocontrolled synthesis of erythronolides A and B in a (C5-C9) + (C3-C4) + (C1-C2) + (C11-C13) sequence from 1. 6-anhydro-β-D-glycopyranose (levoglucosan). Part 1. Synthesis of C1-C10 and C11-C13 segments, Tetrahedron. 47 (1991).

DOI: 10.1016/s0040-4020(01)96139-3

Google Scholar

[3] A.J. Varma, J.F. Kennedy, P. Galgali, Synthetic polymers functionalized by carbohydrates: a review, Carbohyd Polym. 56 (2004) 429-445.

DOI: 10.1016/j.carbpol.2004.03.007

Google Scholar

[4] L.R. Jarboe, Hybrid thermochemical processing: Fermentation of pyrolysis-derived bio-oil, Appl Microbiol Biot. 91 (2011) 1519-1523.

DOI: 10.1007/s00253-011-3495-9

Google Scholar

[5] V. A Kozlov, Mechanism of protodesorption-exchange of heavy metal cations for protons in a heterophase system of H2O-H2SO4-MSO4-cellulose sorbent, J Hazard Mater 299 (2015) 725-732.

DOI: 10.1016/j.jhazmat.2015.08.004

Google Scholar

[6] J.M. Choi, Chemically functionalized silica gel with alkynyl terminated monolayers as an efficient new material for removal of mercury ions from water, J Ind Eng Chem. 35 (2016) 376-382.

DOI: 10.1016/j.jiec.2016.01.020

Google Scholar

[7] M. Ben Abda, O. Schäf, Y. Zerega, Ion exchange effect on asymmetric dioxins adsorption onto FAU-type X-zeolites, Micropor Mesopor Mat. 217 (2015) 178-183.

DOI: 10.1016/j.micromeso.2015.06.013

Google Scholar

[8] M. Coca, Use of weak cation exchange resin Lewatit S 8528 as alternative to strong ion exchange resins for calcium salt removal, J Food Eng. 97 (2010) 569-573.

DOI: 10.1016/j.jfoodeng.2009.12.002

Google Scholar

[9] G.J. Millar, S.J. Couperthwaite, S. Papworth, Ion exchange of sodium chloride and sodium bicarbonate solutions using strong acid cation resins in relation to coal seam water treatment, J Water Process Eng. 11 (2016) 60-67.

DOI: 10.1016/j.jwpe.2016.03.003

Google Scholar

[10] H. Susanto, A. Roihatin, I.N. Widiasa, Production of colorless liquid sugar by ultrafiltration coupled with ion exchange, Food Bioprod Process. 98 (2016) 11-20.

DOI: 10.1016/j.fbp.2015.12.002

Google Scholar

[11] Information on http: /dardel. info/IX/resin_types. html.

Google Scholar

[12] K. Meile, A. Zhurinsh. Aspects of incorporating the production of levoglucosan into a wood-based biorefinery, 12th International Conference of Young Scientists of Energy Issues (2015).

Google Scholar

[13] G. Guiochon, Preparative liquid chromatography, J Chrom A. 965 (2002) 129-161.

Google Scholar

[14] A. Zhurinsh, Effect of pre-treatment conditions on the analytical pyrolysis products from birch wood lignocellulose, J Anal Appl Pyrol. 103 (2013) 227-231.

DOI: 10.1016/j.jaap.2012.12.008

Google Scholar

[15] K. Meile, Application of ion exchange resins in the separation of valuable compounds from wood pyrolysis liquids, Trans Tech Publications Ltd. (2014) 232-235.

DOI: 10.4028/www.scientific.net/kem.604.232

Google Scholar

[16] K. Meile, A. Zhurinsh, B. Spince, Aspects of periodate oxidation of carbohydrates for the analysis of pyrolysis liquids, J Carbohyd Chem. 33 (2014) 105-116.

DOI: 10.1080/07328303.2014.885035

Google Scholar

[17] Q. Lu, Influence of pyrolysis temperature and time on the cellulose fast pyrolysis products: Analytical Py-GC/MS study, J Anal Appl Pyrol. 92 (2011) 430-438.

DOI: 10.1016/j.jaap.2011.08.006

Google Scholar

[18] C. Tessini, High performance thin layer chromatography determination of cellobiosan and levoglucosan in bio-oil obtained by fast pyrolysis of sawdust, J Chrom A. 1218 (2011) 3811-3815.

DOI: 10.1016/j.chroma.2011.04.037

Google Scholar