Anodic Oxidation of Carbon Fiber Surfaces: Influence of Static and Dynamic Process Conditions

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We investigate the effects of static and dynamic anodic oxidation treatment on the surface chemical composition and functionality of carbon fibers. During static treatment, the electrolytic surface oxidation process is performed on a spatially fixed carbon fiber bundle, while in the dynamic process a moving, continuous carbon fiber tow is oxidized. In both treatment modes electrolytic current density and treatment time were varied. Surface chemical composition and functionality of the resulting carbon fibers were analyzed by x-ray photoelectron spectroscopy. A good agreement between the chemical composition and the functionality of fibers from static and dynamic anodic oxidation treatment is found. This suggests that results from static fiber treatment in a variable, easy to handle laboratory setup can be applied to dynamic anodic oxidation process conditions on a large scale.

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440-446

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July 2017

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© 2017 Trans Tech Publications Ltd. All Rights Reserved

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[1] Z. Li, S. Wu, Z. Zhao, L. Xu, Influence of surface properties on the interfacial adhesion in carbon fiber/epoxy composites, Surface and Interface Analysis 46 (2014) 16–23.

DOI: 10.1002/sia.5340

Google Scholar

[2] X. Qian, X. Wang, Q. Ouyang, Y. Chen, Q. Yan, Effect of ammonium-salt solutions on the surface properties of carbon fibers in electrochemical anodic oxidation, Applied Surface Science 259 (2012) 238–244.

DOI: 10.1016/j.apsusc.2012.07.025

Google Scholar

[3] J. Liu, Y. Tian, Y. Chen, J. Liang, Interfacial and mechanical properties of carbon fibers modified by electrochemical oxidation in (NH4HCO3)/(NH4)2C2O4·H2O aqueous compound solution, Applied Surface Science 256 (2010) 6199–6204.

DOI: 10.1016/j.apsusc.2010.03.141

Google Scholar

[4] D.A. Waldman, Y.L. Zou, A.N. Netravali, Ethylene/ ammonia plasma polymer deposition for controlled adhesion of graphite fibers to PEEK, Journal of Adhesion Science and Technology 9 (1995) 1475–1503.

DOI: 10.1163/156856195x00149

Google Scholar

[5] Y. Xie, P.M.A. Sherwood, X-ray photoelectron-spectroscopic studies of carbon fiber surfaces. 11. Differences in the surface chemistry and bulk structure of different carbon fibers based on poly(acrylonitrile) and pitch and comparison with various graphite samples, Chemistry of Materials 2 (1990).

DOI: 10.1021/cm00009a020

Google Scholar

[6] M.R. Alexander, F.R. Jones, Effect of electrolytic oxidation on the surface chemistry of type a carbon fibres—Part I, X-ray photoelectron spectroscopy, Carbon 32 (1994) 785–794.

DOI: 10.1016/0008-6223(94)90034-5

Google Scholar

[7] X. Qian, L. Chen, J. Huang, W. Wang, J. Guan, Effect of carbon fiber surface chemistry on the interfacial properties of carbon fibers / epoxy resin composites, Journal of Reinforced Plastics and Composites 32 (2013) 393–401.

DOI: 10.1177/0731684412468369

Google Scholar

[8] M.R. Alexander, F.R. Jones, Effect of electrolytic oxidation upon the surface chemistry of type a carbon fibres: III. Chemical state, source and location of surface nitrogen, Carbon 34 (1996) 1093–1102.

DOI: 10.1016/0008-6223(96)00061-9

Google Scholar

[9] J. Moosburger-Will, J. Jäger, J. Strauch, M. Bauer, S. Strobl, F. Linscheid, S. Horn, Interphase formation and fiber matrix adhesion in carbon fiber reinforced epoxy resin: Influence of carbon fiber surface chemistry, Composite Interfaces (2017).

DOI: 10.1080/09276440.2017.1267513

Google Scholar

[10] E. Desimoni, G.I. Casella, A. Morone, A.M. Salvi, XPS Determination of Oxygen-containing Functional Groups on Carbon-fibre Surfaces and the Cleaning of These Surfaces, Surface and Interface Analysis 15 (1990) 627–634.

DOI: 10.1002/sia.740151011

Google Scholar