Fabrication of Low Cost Membrane from Anodic Aluminum Oxide

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Anodic Aluminum Oxide (AAO) membrane has been successfully fabricated from two-step anodization with aluminum low grade (Al6061). The pore density, the pore diameter, and the interpore distance can be controlled by varying anodization process conditions. However, there are limits to control the mechanical strength and growth of AAO arrays, such as pore density, pore diameter and interpore distance. In this research the self-organized two-step anodization is carried out varying time at 24, 48 and 72 hours, respectively with 40V at the low temperature 2-5°C. The optimum conditions of AAO with two-step anodization is 40V for 48 hr. Finally, AAO substrate is separated from aluminum low-grade and enlarged pore diameter with pore widening process by 5% H3PO4. The physical properties were investigated by mean of field emission scanning electron microscope (FE-SEM) show that the average pore diameter and average interpore distance increase with the anodization time. Al6061 Aluminum substrate can be used to fabricate a nanoporous AAO film with an average pore diameter and average interpore distance larger than 70 and 90 nanometers, respectively but less mechanical stability.

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August 2017

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[1] G. E. Thompson et. al., Nucleation and growth of porous anodic films on Aluminum, Nature, vol. 272, 433 - 435, Mar. (1978).

Google Scholar

[2] R. C. Furneaux, W. R. Rigby, and A. P. Davidson, The formation of controlled-porosity membranes from anodically oxidized Aluminum, Nature, vol. 337, 147-149, Jan. (1989).

DOI: 10.1038/337147a0

Google Scholar

[3] F. Li, L. Zhang and R. M. Metzger, On the Growth of Highly Ordered Pores in Anodized Aluminum Oxide, Chem. Mater, vol. 10, pp.2470-2480, May. (1998).

DOI: 10.1021/cm980163a

Google Scholar

[4] W. J. Stepniowski, M. Noreka, M. Michalska-Domanskaa, A. Bombalskab, A. Nowak-Stepniowskab, M. Kwasnyb and Z. Bojara, Fabrication of anodic aluminum oxide with incorporated chromate ions, Applied Surface Science, vol. 259, pp.324-330, Jul. (2012).

DOI: 10.1016/j.apsusc.2012.07.043

Google Scholar

[5] C. Ottone, M. Laurenti, K. Bejtka, A. Sanginario and V. Cauda, The Effects of the Film Thickness and Roughness in the Anodization Process of Very Thin Aluminum Films, Journal of Materials Science & Nanotechnology, vol. 1, pp.1-9, Jul. (2014).

Google Scholar

[6] M. Michalska-Domanskaa, M. Noreka, W. J. Stepniowskia and B. Budnerb, Fabrication of high quality anodic aluminum oxide (AAO) on low purity aluminum - A comparative study with the AAO produced on high purity aluminum, Electrochimica Acta, vol. 105, pp.424-432, Apr. (2013).

DOI: 10.1016/j.electacta.2013.04.160

Google Scholar

[7] H. Adelkhani, S. Nasoodi, A. H. Jafari, A study of the Morphology and Optical Properties of Electropolished Aluminum in the Vis-IR region, Int. J. Electrochem. Sci., vol. 4, pp.238-246, Feb. (2009).

DOI: 10.1016/s1452-3981(23)15124-8

Google Scholar

[8] G. Jai Poinern, N. Ali and D. Fawcett, Progress in Nano-Engineered Anodic Aluminum Oxide Membrane Development, Materials, vol. 4, pp.487-526, Feb. (2011).

DOI: 10.3390/ma4030487

Google Scholar

[9] K. Suk Yang, H. Jin Kim, J. Keun Ahn and D. Hyun Kim, Microfluidic chip with porous anodic alumina integrated with PDMS/glass substrate for immuno- diagnosis, Current Applied Physics, vol. 9, pp.60-65, Mar. (2009).

DOI: 10.1016/j.cap.2008.12.031

Google Scholar

[10] M. Aramesh and J. Cervenka, Surface Modification of Porous Anodic Alumina for Medical and Biological Applications, Nanomedicine, pp.439-467.

Google Scholar

[11] Masuda, H. Fukuda and K. Ordered, Metal Nanohole Arrays Made by a Two- Step Replication of Honeycomb Structures of Anodic Alumina, Science 268, 1466–1468 (1995).

DOI: 10.1126/science.268.5216.1466

Google Scholar

[12] P. Erdogan, B. Yuksel and Y. Birol, Effect of chemical etching on the morphology of anodic aluminum oxides in the two-step anodization process, Applied Surface Science, vol. 258, pp.4544-4550, Jan. (2012).

DOI: 10.1016/j.apsusc.2012.01.025

Google Scholar

[13] A. Brudzisz, A. Brzózka and G. D. Sulka, Effect of processing parameters on pore opening and mechanism of voltage pulse detachment of nanoporous anodic alumina, Electrochimica Acta, vol. 178, pp.374-384, Aug. (2015).

DOI: 10.1016/j.electacta.2015.08.005

Google Scholar

[14] Ketul C. Popat GM, Craig A. Grimes and Tejal A. Desai, Surface Modification of Nanoporous Alumina Surfaces with Poly(ethylene glycol), Langmuir : the ACS journal of surfaces and colloids. 2004; 20.

DOI: 10.1021/la049075x

Google Scholar

[15] K. Syrek, J. Kapusta-Kołodziej, M. Jarosz and G. D. Sulka, Effect of electrolyte agitation on anodic titanium dioxide (ATO) growth and its photoelectrochemical properties, Electrochimica Acta, vol. 180, pp.801-810, Sep. (2015).

DOI: 10.1016/j.electacta.2015.09.011

Google Scholar

[16] O. Jessensky, F. Muller and U. Gosele, Self-organized formation of hexagonal pore arrays in anodic alumina, Applied physics letters, vol. 72, pp.1173-1175, Mar. (1998).

DOI: 10.1063/1.121004

Google Scholar

[17] Kwang Hong Lee, and C. C. Wong, Decoupling two-step anodization in anodic aluminum oxide, Journal of Applied Physics, 106, 104305 (2009).

DOI: 10.1063/1.3257261

Google Scholar

[18] W. J. Stepniowski and Z. Bojar, Synthesis of anodic aluminum oxide (AAO) at relatively high temperatures, Surface & Coatings Technology, vol. 206, pp.265-272, Jul. (2011).

DOI: 10.1016/j.surfcoat.2011.07.020

Google Scholar

[19] Y. Li, Y. Chen, M. Qiu, H. Yu, X. Zhang, X. Wei Sun and R. Chen, Preparation of Aluminum Nanomesh Thin Films from an Anodic Aluminum Oxide Template as Transparent Conductive Electrodes, Nature Scientific Reports, vol. 6, 20114 (2016).

DOI: 10.1038/srep20114

Google Scholar