Synthesis and Photocatalytic Properties of the Bi2MoO6 and Bi2WO6 Photocatalysts

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Two different Bi-based semiconductor photocatalysts Bi2MoO6 and Bi2WO6 were synthesized by a simple one-pot hydrothermal reaction at 453 K for 10 h. The properties of the photocatalysts, including structures, morphology, light-absorption band and photoluminescence, etc were characterized by X-ray diffraction, scanning electron microscopy, UV-Vis diffuse reflectance spectrum and fluorescence spectrum. Further, their photocatalytic properties were compared by the degradation of two different organic dyes: Rhodamine B and methylene blue. It is important to note that the Bi2WO6 nanoplate structure exhibited better photocatalytic activity than the Bi2MoO6 nanowires aggregates due to its high surface area, higher light absorption and lower recombination of electron-hole pairs.

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218-223

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April 2018

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© 2018 Trans Tech Publications Ltd. All Rights Reserved

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[1] J.S. Wen, C.C. Ma, P.W. Huo, X.L. Liu, Y. Liu,X.Yao Z.F. Ma, Y.S. Yan, Construction of vesicle CdSe nano-semiconductors photocatalysts with improved photocatalytic activity: Enhanced photo induced carriers separation efficiency and mechanism insight,J.Environ. Sci.,1(2017).

DOI: 10.1016/j.jes.2016.12.023

Google Scholar

[2] T.K. Majia, D.Bagchia, P. Kara, D. Karmakar, S.K. Pal,Enhanced charge separation through modulation of defect-state in wide band-gap semiconductor for potential photocatalysis application: Ultrafast spectroscopy and computational studies." J. Photo. Photobio. A, 332(2017).

DOI: 10.1016/j.jphotochem.2016.09.017

Google Scholar

[3] Z. Huang, Q.Sun, K.L. Lv, Z.H. Zhang, M. Li, B.Li, Effect of contact interface between TiO2, and g-C3N4, on the photoreactivity of g-C3N4 /TiO2, photocatalyst: (001)vs, (101) facets of TiO2." Appl.Catal. B Environ.,164(2015) 420-427.

DOI: 10.1016/j.apcatb.2014.09.043

Google Scholar

[4] L.X. Song, J. Xia, Z. Dang, J. Yang, L.B. Wang, J.Chen, Formation, structure and physical properties of a series of a-MoO3nanocrystals: from 3D to 1D and 2D, CrystEngComm, 14 (2012) 2675-2682.

DOI: 10.1039/c2ce06567c

Google Scholar

[5] S.Dutta, S.Som, S.K. Sharma, Luminescence and photometric characterization of K+ compensated CaMoO4:Dy3+ nanophosphors, Dalton Trans., 42(2013) 9654-9661.

DOI: 10.1039/c3dt50780g

Google Scholar

[6] J.Y. Chen, X.L. Liu, H.M. Zhang, P. Liu, G.Y.Li, T.C. An, H.J. Zhao, Soft-template assisted synthesis of mesoporous CuO/Cu2O composite hollow microspheres as efficient visible-light photocatalyst, Mater. Letters, 182 (2016) 47-51.

DOI: 10.1016/j.matlet.2016.06.077

Google Scholar

[7] W.Z. Wang, M. Shang, W.Z Yin, J. Ren, L Zhou, Recent Progress on the Bismuth Containing Complex Oxide Photocatalysts, J. Inorg. Mater., 27 (2012) 11-18.

DOI: 10.3724/sp.j.1077.2012.00011

Google Scholar

[8] Y. Hu, D.Z. Li, F.Q. Sun, Y.Q. Weng, S.Y You, Y. Shao, Temperature-induced phase changes in bismuth oxides and efficient photodegradation of phenol and p-chlorophenol, J. Hazar. Mater. 301(2016) 362-370.

DOI: 10.1016/j.jhazmat.2015.09.008

Google Scholar

[9] J.Ren, W.Z. Wang, M. Shang, S.M. Sun, E.P. Gao, Heterostructured bismuth molybdate composite: preparation and improved photocatalytic activity under visible-light irradiation,ACS Appl. Mater. Interfaces, 3(2011)2529-2533.

DOI: 10.1021/am200393h

Google Scholar

[10] L. H. Hoang, N. D. Phu, P. D. Chung, P. C. Guo, X.B. Chen, W.C. Chou, Photocatalytic activity enhancement of Bi2WO6 nanoparticles by Gd-doping via microwave assisted method,J Mater. Sci: Mater. Electron., 28 (2017) 12191-12196.

DOI: 10.1007/s10854-017-7034-z

Google Scholar

[11] L.M. Reilly, G.Sankar, C. R. A. Catlow, Following the formation of γ-Phase Bi2MoO6catalyst by in Situ XRD/XAS and thermogravimetric techniques, J. Solid State Chem.,148(1999)178-185.

DOI: 10.1006/jssc.1999.8486

Google Scholar

[12] C.K .Lee, T.S. Leng, A.M. Coats, A.R. West, On possible Cu doping of Bi2WO6, J. Mater.Chem., 11 (2001) 1096-1099.

Google Scholar

[13] H. Qiong, Y.H. Ni, S.Y. Ye, Heterostructured Bi2O3/Bi2MoO6 nanocomposites: simple construction and enhanced visible-light photocatalytic performance, Rsc Advances 7(2017)27089-27099.

DOI: 10.1039/c7ra02760e

Google Scholar

[14] M. Sundararajan, L.J. Kennedy, P. Nithya, J.J. Vijaya, M. Bououdina, Visible light driven photocatalytic degradation of rhodamine B using Mg doped cobalt ferrite spinel nanoparticles synthesized by microwave combustion method, J. Phys. Chem. Solids, 108 (2017).

DOI: 10.1016/j.jpcs.2017.04.002

Google Scholar