Mechanochemical Assisted Modification of Parawood Microcrystalline Cellulose Using Silane Coupling Agent and their Composites Properties

Patcharaporn Chuayplod; Duangdao Aht-Ong

doi:10.4028/www.scientific.net/KEM.775.57

Paper Titles

Feasibility Study of Selecting Soft Components of Body Armor
p.32

Damage Mechanism Analysis of Carbon Fiber Composites under Compressive Load
p.36

Fabrication and Stabilization of Poly(Acrylonitrile-сo-Methyl Acrylate) Nanofibers
p.43

Synthesis and Characterization of Transparent Conducting Film from Abaca Hybrid 7 Cellulose Acetate Blend and Polyaniline
p.50

Mechanochemical Assisted Modification of Parawood Microcrystalline Cellulose Using Silane Coupling Agent and their Composites Properties
p.57

Conduction in Polyaniline-Emeraldine Salt/Bentonite Composites Using Impedance Spectroscopy
p.63

Comparative Study of Compressive Strength of Epoxy Based Bio-Composites
p.68

Extracted Lignin from Rhizophora’s Black Liquor as Fluid Loss Control Additive in Water Based Drilling Mud
p.74

Lamination of Chitin-Cellulose Film and Thermoplastic Starch
p.81

HomeKey Engineering MaterialsKey Engineering Materials Vol. 775Mechanochemical Assisted Modification of Parawood...

Mechanochemical Assisted Modification of Parawood Microcrystalline Cellulose Using Silane Coupling Agent and their Composites Properties

Abstract:

Surface treated parawood microcrystalline cellulose (PW-MCC) performed under mechanochemical reaction using planetary ball milling at ambient temperature was used as a reinforcing material in polypropylene composites. Initially, PW-MCC was prepared by acid hydrolysis of parawood sawdust pulp. After that, PW-MCC was treated with vinyltrimethoxysilane at milling speed 400 rpm for 60 min. The surface composition from XPS indicated the existence of silicon atom on silane-treated PW-MCC. The thermal stability of PW-MCC was also improved and SEM micrograph revealed rough surface after modification reaction. The untreated PW-MCC and treated PW-MCC were applied to prepare polypropylene composites at 5-30 wt% loading content without a compatibilizer. The results demonstrated that silane-treated PW-MCC/PP composites enhanced tensile strength, thermal stability and water resistance of the composites.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Key Engineering Materials (Volume 775)

Pages:

57-62

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.775.57

Citation:

Cite this paper

Online since:

August 2018

Authors:

Patcharaporn Chuayplod, Duangdao Aht-Ong*

Keywords:

Composites, Microcrystalline Cellulose, Polypropylene, Silane, Surface Modification

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] S. Spoljaric, K. Genovese, R. Shanks, Polypropylene-microcrystalline cellulose composites with enhanced compatibility and properties, Appl. Sci. Manuf. 40 (2009) 791-799.

DOI: 10.1016/j.compositesa.2009.03.011

Google Scholar

[2] A,M, Adel, Z.H,A. El-Wahab, A.A. Ibrahim, M. Al-Shemy, Characterization of microcrystalline cellulose prepared from lignocellulose materials. Part II: Physicochemical properties, Carbohydr Polymer 83 (2011) 676-687.

DOI: 10.1016/j.carbpol.2010.08.039

Google Scholar

[3] M.N. Ichazo, C. Albano, J. González, R. Perera, M.V. Candal, Polypropylene/wood flour composites: treatments and properties, Composite. Structure. 54 (2001) 207-214.

DOI: 10.1016/s0263-8223(01)00089-7

Google Scholar

[4] N. Lu, S. Oza S, Thermal stability and thermos-mechanical properties of hemp-high density polyethylene composites: Effect of two different chemical modifications, Compos B. Eng. 44 (2013) 484-490.

DOI: 10.1016/j.compositesb.2012.03.024

Google Scholar

[5] M.K. Thakur, R.K. Gupta, V.K. Thakur, Surface modification of cellulose using silane coupling agent, Carbohydr. Polymer. 111 (2014) 849-855.

DOI: 10.1016/j.carbpol.2014.05.041

Google Scholar

[6] Q. Lu, W. Lin, L. Tang, S. Wang, X. Chen, B. Huang, A mechanochemical approach to manufacturing bamboo cellulose nanocrystals, J. Mater. Sci. 50 (2015) 611-619.

DOI: 10.1007/s10853-014-8620-6

Google Scholar

[7] H. Jeske, A. Schirp, F. Cornelius, Development of a thermogravimetric analysis (TGA) method for quantitative analysis of wood flour and polypropylene in wood plastic composites (WPC), Thermochim. Acta. 543 (2012) 165-171.

DOI: 10.1016/j.tca.2012.05.016

Google Scholar

[8] F. Zhou, G. Cheng, B. Jiang, Effect of silane treatment on microstructure of sisal fibers, Appl. Surf. Sci. 292 (2014) 806-812.

DOI: 10.1016/j.apsusc.2013.12.054

Google Scholar

[9] L. Fang, L. Chang, W. Guo, Y. Chen, Z. Wang, Influence of silane surface modification of veneer on interfacial adhesion of wood–plastic plywood, Appl. Surf. Sci. 288 (2014) 682– 689.

DOI: 10.1016/j.apsusc.2013.10.098

Google Scholar