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HomeKey Engineering MaterialsKey Engineering Materials Vol. 779A Three-Dimensional Metal-Organic Framework...

A Three-Dimensional Metal-Organic Framework Displaying Guest-Dependent Spin-Crossover Behaviour

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Abstract:

A new three-dimensional metal-organic complex, [{Fe (NCSe)₂}₃(TPB)₄]x(guest), was prepared with the ligand of TPB (1,3,5-tris (4-pyridyl) benzene). The X-ray single crystal diffraction studied in 100 K and 173 K shown the change of bonds and angles of the framework. The guest exchange and magnetic properties indicated that the 3D framework can be responsible to the solvent guest molecules and shows guest-dependent spin-crossover behaviour.

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Periodical:

Key Engineering Materials (Volume 779)

Pages:

110-114

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.779.110

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Online since:

September 2018

Authors:

Feng Shao, Jia-Jia Zhuang, Gang Luo, Ke Zhang, Chang Jiang Li, Hai Feng Zhu, Jia Ping Tong*

Keywords:

Guest-Dependent, Metal-Organic Frameworks, Spin-Crossover

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© 2018 Trans Tech Publications Ltd. All Rights Reserved

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