Effect of SiO2 Contents in TEOS-SiO2-OTES Hybrid Coating on Glass

Article Preview

Abstract:

This work aims to study the effect of SiO2 and heat treatment temperature in TEOS-SiO2-OTES film on the hydrophobic property and weathering durability. TEOS-SiO2-OTES film was prepared by sol-gel process. Tetraethylorthosilicte (TEOS) and Octyltriethoxysilane (OTES) were used to form the gel. The contents of SiO2 were varied at 0.5% 1% 3% 5% and 10% by weight. The film was deposited on a glass slide by spin coating. The hydrophobic property was studied by FTIR, UV-VIS spectroscopy, SEM, XRD and contact angle. The weathering chamber was used for studying weathering durability. The weathering condition was controlled at 50 oC and 85%RH. Moreover, the chemical resistant was also tested. The study showed that the silica contents affected the surface roughness of film. The surface roughness of film decreased with increasing amounts of SiO2.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

128-133

Citation:

Online since:

April 2019

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2019 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] S.S. Latthe, H. Imai, V. Ganesan, and A. V.Rao, 2009, Superhydrophobic silica films by sol–gel co-precursor method,, Applied Surface Science, Vol. 256, p.217–222.

DOI: 10.1016/j.apsusc.2009.07.113

Google Scholar

[2] T.Rezayi, and M.H. Entezari, 2015, Achieving to a superhydrophobic glass with high transparency by a simple sol–gel-dip-coating method,, Surface & Coatings Technology, Vol. 276, p.557–564.

DOI: 10.1016/j.surfcoat.2015.06.015

Google Scholar

[3] Y.J. Eo, D.J. Kim, and B.S. Bae, 1998, Coating of Tetraethylorthosilicate (TEOS) /Vinyltriethoxysilane (VTES) Hybrid Solution on Polymer Films, Sol-Gel Science and Technology, Vol.13, p.409–413.

Google Scholar

[4] L. de Ferri, P.P. Lottici, A. Lorenzi, A. Montenero, G. Vezzalini, 2013, Hybrid sol–gel based coatings for the protection of historical window glass,, Sol-Gel Science and Technology, Vol.66, p.253–263.

DOI: 10.1007/s10971-013-3002-0

Google Scholar

[5] B.D. Bianco, R. Bertoncello, A. Bouquillon, J.C. Dran, L.Milanese, S. Roehrs, C. Sada, and J. Salomon, Voltolina S, 2008, Investigation on sol–gel silica coatings for the protection of ancient glass: interaction with glass surface and protection efficiency,, J Non-Cryst Solids, Vol 354, p.2983–2992.

DOI: 10.1016/j.jnoncrysol.2007.12.004

Google Scholar

[6] K. Morimoto, and S. Suzuki, 1972, "Ultraviolet irradiation of poly(-alkyl acrylates) and poly(alkyl methacrylates), J Appl Polym Sci, Vol. 16, p.2947–2961.

DOI: 10.1002/app.1972.070161119

Google Scholar

[7] R.L. Feller, 1975, Speeding up photochemical deterioration,, Bull Inst R Patr Art, Vol. 15, p.135–150.

Google Scholar

[8] B. Holubova, Z.Z. Cilova, I. Kucerova, and M. Zlamal, 2015, Weatherability of Hybrid Organic-Inorganic Silica Protective Coatings on Glass,, Progress in Organic Coating, Vol.88, pp.170-180.

DOI: 10.1016/j.porgcoat.2015.07.001

Google Scholar

[9] D. Kumar, X. Wu, Q. Fu, J.W. Chye Ho, P.D. Kanhere, L. li and Z. Chen, 2015, Hydrophobic Sol-Gel Coatings Based on Polydimethylsiloxane for Self-Cleaning Applications,, Materials and Design, Vol.86, pp.855-862.

DOI: 10.1016/j.matdes.2015.07.174

Google Scholar

[10] S.A. Mahadik, M.S. Kavale, S.K. Mukherjee, and A.V. Rao, 2010, Transparent Superhydrophobic Silica Coatings on Glass by Gol-Gel method,, Applied Surface Science, Vol.257, pp.333-339.

DOI: 10.1016/j.apsusc.2010.06.062

Google Scholar

[11] M. Ramezani, M.R. Vaezi, and A. Kazedeh, 2014, Preparation of Silane-Functionalized Silica Films via Two-Step Dip Coating Sol-Gel and Evaluatiom of Their Superhydrophobic Properties,, Applied Surface Science, Vol.317, pp.147-153.

DOI: 10.1016/j.apsusc.2014.08.095

Google Scholar

[12] S.S. Latthe, H. Imai, V. Ganesan, and A.V. Rao, 2009, Superhydrophobic silica films by sol–gel co-precursor method,, Applied Surface Science, Vol. 256, p.217–222.

DOI: 10.1016/j.apsusc.2009.07.113

Google Scholar