Electrochemical Treatment of Graphene

Alexander Usikov; Mikhail V. Puzyk; Sergey Novikov; Iosif Barash; Oleg Medvedev; Alexander Roenkov; Andrey Goryachkin; Sergey P. Lebedev; Alexander V. Zubov; Yuri Makarov; Alexander A. Lebedev

doi:10.4028/www.scientific.net/KEM.799.197

Paper Titles

Enhancement of Hydrogen Storage in Metals by Using a New Technique in Severe Plastic Deformations
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Characteristics and Photocatalytic Activity of Sm Doped ZnO Nanoparticles
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Comparative Investigation of the Graphene-on-Silicon Carbide and CVD Graphene as a Basis for Biosensor Application
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3D Alumina-Graphene Hybrid Nanofibers as a Binder‐Free Cathode for Rechargeable Li‐S Batteries
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Electrochemical Treatment of Graphene
p.197

Mathematical Model to Study the Impact Response of a Viscoelastic Auxetic Plate
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Contact Stiffness Parameters for Finite Element Modeling of Contact
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Applying the Fractal Analysis Methods for the Study of the Mechanisms of Deformation and Destruction of Polymeric Material Samples Affected by Tensile Stresses
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Dynamic Analysis of a Viscoelastic Nanobeam
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HomeKey Engineering MaterialsKey Engineering Materials Vol. 799Electrochemical Treatment of Graphene

Electrochemical Treatment of Graphene

Abstract:

Treatment of graphene/SiC dies in inorganic electrolytes (KOH, KCl and Na₂SO₄) is discussed. An electrochemical method based on the cyclic voltammetry in a conventional three-electrode cell with Ag/AgCl reference electrode, a platinum counter electrode, and the graphene/SiC dies as working electrode (anode) is used for the treatment. It was observed either partial oxidation of graphene or its complete dissolution with the formation of CO₂. The treatment performed resulted in the deterioration of the graphene films and change of the graphene-die resistivity depending on the range of the scanning potential applied to the graphene/SiC dies.

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Periodical:

Key Engineering Materials (Volume 799)

Pages:

197-202

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.799.197

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Online since:

April 2019

Authors:

Alexander Usikov*, Mikhail V. Puzyk, Sergey Novikov, Iosif Barash, Oleg Medvedev, Alexander Roenkov, Andrey Goryachkin, Sergey P. Lebedev, Alexander V. Zubov, Yuri Makarov, Alexander A. Lebedev

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Cyclic Voltammetry, Electrolysis in Inorganic Electrolytes, Graphene, Scanning Electron Microscopy

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References

[1] A.V. Eletskii, I.M. Iskandarova, A.A. Knizhnik, D.N. Krasikov, Graphene: fabrication methods and thermophysical properties, Phys-Usp+ 54 (2011) 227-258.

DOI: 10.3367/ufne.0181.201103a.0233

Google Scholar

[2] K.S. Novoselov, A.K. Geim, S.V. Morozov, D. Jiang, Y. Zhang, S.V. Dubonos, I.V. Grigorieva, A.A. Firsov, Electric Field Effect in Atomically Thin Carbon Films, Science 306 (2004) 666-669.

DOI: 10.1126/science.1102896

Google Scholar

[3] Y. Wu, Y.-M. Lin, A.A. Bol, K.A. Jenkins, F. Xia, D.B. Farmer, Y. Zhu, P. Avouris, High-frequency, scaled graphene transistors on diamond-like carbon, Nature 472 (2011) 74-78.

DOI: 10.1038/nature09979

Google Scholar

[4] F. Schedin, A.K. Geim, S.V. Morozov, E.W. Hill, P. Blake, M.I. Katsnelson, K.S. Novoselov, Detection of individual gas molecules adsorbed on graphene, Nature Mater. 6 (2007) 652-655.

DOI: 10.1038/nmat1967

Google Scholar

[5] A.A. Lebedev, V.Y. Davydov, D.P. Litvin, S.N. Novikov, Y.N. Makarov, V.B. Klimovich, M.P. Samoilovich, Graphene-based biosensors, Techn. Phys. Lett. 42 (2016) 729-732.

DOI: 10.1134/s1063785016070233

Google Scholar

[6] D. Kireev, S. Seyock, M. Ernst, V. Maybeck, B. Wolfrum, A. Offenhäusser, Versatile Flexible Graphene Multielectrode Arrays, Biosensors 7 (2017) 1-9.

DOI: 10.3390/bios7010001

Google Scholar

[7] V. Georgakilas, M. Otyepka, A.B. Bourlinos, V. Chandra, N. Kim, K.C. Kemp, P. Hobza, R. Zboril, K.S. Kim, Functionalization of graphene: covalent and non-covalent approaches, derivatives and applications, Chem. Rev. 112 (2012) 6156-6214.

DOI: 10.1021/cr3000412

Google Scholar

[8] Z. Tehrani, G. Burwell, M.A. Mohd Azmi, A. Castaing, R. Rickman, J. Almarashi, P. Dunstan, A. Miran Beigi, S.H. Doak, O.J. Guy, Generic epitaxial graphene biosensors for ultrasensitive detection of cancer risk biomarker, 2D Mater. 1 (2014) 025004.

DOI: 10.1088/2053-1583/1/2/025004

Google Scholar

[9] V.Yu. Davydov, D.Yu. Usachov, S.P. Lebedev, A.N. Smirnov, V.S. Levitskii, I.A. Eliseyev, P.A. Alekseev, M.S. Dunaevskiy, O.Yu. Vilkov, A.G. Rybkin, A.A. Lebedeva, Study of the Crystal and Electronic Structure of Graphene Films Grown on 6H-SiC (0001), Semiconductors+ 51 (2017) 1072-1080.

DOI: 10.1134/s1063782617080073

Google Scholar

[10] Y. Matsuda, W.-Q. Deng, W.A. Goddard, Contact Resistance for End-Contacted, Metal-Graphene and Metal-Nanotube Interfaces from Quantum Mechanics, J. Phys. Chem. C 114 (2010) 17845-17850.

DOI: 10.1021/jp806437y

Google Scholar

[11] J. Borysiuk, R. Bożek, W. Strupiński, A. Wysmołek, K. Grodecki, R. Stępniewski, J.M. Baranowski, Transmission electron microscopy and scanning tunneling microscopy investigations of graphene on 4H-SiC(0001), J. Appl. Physics 105 (2009) 023503.

DOI: 10.1063/1.3065481

Google Scholar

[12] S. Kopylov, A. Tzalenchuk, S. Kubatkin, V. Fal'ko1, Charge transfer between epitaxial graphene and silicon carbide, Appl. Phys. Lett. 97 (2010) 112109.

DOI: 10.1063/1.3487782

Google Scholar

[13] Y.-P. Lin, Y. Ksari, J.-M. Themlin, Hydrogenation of the buffer-layer graphene on 6H-SiC (0001): A possible route for the engineering of graphene-based devices, Nano Res. 8 (2015) 839-850.

DOI: 10.1007/s12274-014-0566-0

Google Scholar