Key Engineering Materials Vol. 810

Abstract: The contribution is aimed at corrosion propertied and wettability of basic graded of stainless steel commonly used in medicine as a standard for construction of instruments and other applications. Samples of AISI 304 (1.4301) steel were chemical passivated by nitric acid and tested for corrosion resistance in environment of sodium hypochlorite (NaClO), which is commonly used for basic disinfection of surfaces or devices in hospital facilities. It was found that chemical passivation of stainless steel surface increases its corrosion resistance and lower corrosion rate. Passivation layer also shows more polarization resistance. The wettability of passivated surface was measured by sessile drop method. Wettability itself determinates effectivity of disinfection process as the surfaces with lower contact angle may be cleaned and disinfected with more efficiency. It was proofed that chemical passivation increases wettability by lowering contact angle of treated surface.

Abstract: Quasi-cleavage facets have been detected in the stress corrosion cracking fracture of type 304 and type 316 austenitic stainless steels under an environment containing chloride. Their morphology and crystal orientation were analyzed. In both steels the cold-worked material (CW) showed higher crack propagation rate than annealed one (ST), where the variation of the propagated crystal planes of the CW was higher than that of the ST, and the {111} facet was detected in the CW. Then the CW reveals higher possibilities to choose a low energy crack path rather than the ST. The rearrangement and multiply of {111} dislocation arrays may introduce the {111} transgranular cracking in the CW, and the combining duplex {111} slip operations may result in the {110} facet.

Abstract: The paper describes effect of hydrogen on mechanical properties and fracture characteristics of two types of C-Mn-Si TRIP steel; laboratory prepared steel TRIP 800 and commercially manufactured steel TRIP 780. TRIP steels are very promising materials thanks to their combination of a very good strength and toughness. However, these steels can be embrittled by hydrogen during technological operations related to galvanizing. That is why the knowledge of effects of hydrogen on the properties and fracture characteristics of the TRIP steels is of particular importance. In the presented study, effects of hydrogen were studied by tensile tests after electrolytical hydrogen charging. Electrolytical hydrogen charging was performed in 0.05 M solution of sulfuric acid with addition of potassium thiocyanate to promote hydrogen absorption. Hydrogen provoked embrittlement in both steel variants and changed their fracture micromechanism. Hydrogen embrittlement manifested itself mainly by a loss of plasticity. Index of hydrogen embrittlement, expressed on the basic of a relative drop of elongation to fracture, reached values about 77 % for the steel variant TRIP 800, resp. 83 % for the steel variant TRIP 780. No significant difference was observed between two steel variants studied. Concerning fractographic characteristics, steels containing hydrogen displayed quasi-cleavage fracture mostly on the edges of the sample and around elongated non-metallic inclusions.

Abstract: Wear of materials in rail/wheel industry is closely related to the cyclic creep. This contribution presents main results of experimental testing on R7T wheel steel. The cyclic creep is investigated under non-proportional loading conditions simulating a line rolling contact case. McDowell extrapolation was successfully applied to the calculation of twist. Cyclic material model MAKOC and MAKOC with memory surface were used for cyclic creep prediction. The plasticity model is based on AbdelKarim-Ohno kinematic hardening and Calloch isotropic hardening rules. Second material model was extended with Jiang-Sehitoglu memory surface, which is introduced in stress space. Material models were successfully used for predicting accumulation of shear strain.

Abstract: This paper deals with the formation and decomposition of Widmanstätten austenite during solidification of the thin belt-casted strip made of a grain oriented electrical steel (GOES). Solidification of liquid steel starts with the formation of d-ferrite. Cooling in the delta + gama phase field results in the formation of a small fraction of Widmanstätten austenite by displacive transformation accompanied by carbon partition. Widmanstätten austenite laths have an orientation relationship with the ferrite grain into which they grow. Furthermore, they form a flat low energy interface along the ferrite grain boundary. In order to minimize the interfacial energy, ferrite grain boundaries in the vicinity of flat austenite/ferrite interface facets are forced to migrate which results in straightening of these grain boundaries. If parallel Widmanstätten austenite laths form in two adjacent ferrite grains, zig–zag ferrite grain boundaries arise. Precipitation of sulphides along ferrite/austenite interfaces make it possible to study the early stages of austenite decomposition under the delta + gama phase field. It starts with the formation of epitaxial ferrite accompanied by further partitioning of carbon into remaining austenite. The growth of epitaxial ferrite into the flat ferrite/austenite interface facets along ferrite grain boundaries results in a wavy shape of these ferrite grain boundaries. Finally austenite transforms either to pearlite or to plate martensite.

Abstract: Predicting the residual life of a structure is an essential issue in structure management. Many researchers have used different methods to predict structure lifetimes, such as the creep rupture test. However, this test is costly and time-consuming, and since it is also destructive, an unused specimen must be tested rather than an actual specimen in use. The instrumented indentation test (IIT), on the other hand, is easier and faster than conventional test methods, most important of all, it is a non-destructive method to obtain mechanical properties that can be performed on the actual structure in use. In this study, we obtained mechanical properties of a SA213-T23 tube material for a thermal power plant degraded for 1~2,000 hours at high temperature. and observed the degradation by analyzing the microstructure. We found a relation between the Larson-Miller Parameter (LMP) and degradation tensile properties considering the temperature and degradation time and suggested a method to predict the residual life by applying a failure criterion. Also, we confirmed that our interaction formula and the residual life are reasonable by comparison with statistical rupture time data from materials that have in fact degraded.

Abstract: In order to study the plastic deformation mechanism of AZ31 magnesium alloy, in situ texture measurement during uniaxial tensile deformation is conducted by using neutron diffraction. The specimen is prepared from a rolled sheet so that the deformation axis is parallel to the rolling direction. By increasing strain, the alignment of <10-10> along the tensile axis is strengthened, which is due to the activation of the prism slip system. The basal pole concentration at the prior sheet normal direction is slightly decreased by the deformation and the new texture component is formed at the transvers direction. This can be understood by activation of the {10-12} tension twinning. These results indicate that the tension twinning plays an important role even when the tensile deformation is applied parallel to the basal plane.

Abstract: In this paper, recently developed ternary FeAl20Si20 (wt.%) alloy with promising high-temperature oxidation and wear resistance was prepared by mechanical alloying in a high-energy ball mill. The possibility to speed-up the mechanical alloying process by replacing aluminium (and partly silicon) elemental powder by the pre-alloyed powder (AlSi30) with relatively fine dispersion of Si in the Al-Si eutectic was examined. The microstructure, phase composition and mechanical properties after various time of mechanical alloying were characterized. The effect of using the pre-alloyed powders on kinetics of mechanical alloying is compared with the results obtained on batches prepared from elemental powders.

Abstract: The architectured metallic materials are a class of composite materials that combines two or more metals/alloys with a specific spatial ordering (architecture). The main goal behind the preparation of such materials is to obtain properties that are not achievable by a single material. The internal architecture thus creates an extra degree of freedom in materials design. Based on theoretical considerations three aluminum alloy structures containing square, triangle and sinusoidal iron beam patterns have been prepared by a cold spray deposition technique. Strength properties difference and good bonding of the reinforcing Fe structure to the Al matrix has been found to be important for effective improvement of final properties. Incorporating about 30 vol. % structured iron beams into the Al matrix resulted in a macroscopic performance of the architectured multimaterial similar to Ti alloys.

Abstract: Excellent creep strength of the ODS steels is associated with an attractive interaction between dislocations and oxides. The aim of this study is to explore the Fe-Al-O and Fe-Al-Cr-Y-O systems with high oxygen content (up to 1.5 wt %) represented by alumina or yttria oxides (up to 5 vol. %) to identify the potentials of the new generation of ODS alloys. The basic material is prepared from Fe and 10 or 11 wt. % of Al. Theoretical models showed stability of Al oxides even above 1000°C, while practical results show coarsening with time at these temperatures. Stability of Y oxides is about 200°C higher, so there is a potential to have stable creep resistant alloy in range of 1000-1200°C.