Modified of the Epoxy Coatings by Polyaniline

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An actual problem is searching of new pathways of increase of anticorrosion properties of an organic coating. In the field of practice and the theory of metal protection from corrosion recently there were novel trends. One of them – making and examination of the conducting polymers inhibiting corrosion of many metals. Influence of the amine hardener modified by polyaniline (PANi) on anticorrosion properties of epoxy coatings in various corrosion-active mediums was studied. The polarization studies have shown that the introduction of PANI in the epoxy polymer coating reduces the corrosion current density. Using electrochemical impedance spectroscopy has established that coatings containing of PANI, are less permeable due to its hydrophobic. It was showed, that PANi it can be used for increase of anticorrosion properties of manufacturing epoxy primer.

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271-278

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August 2019

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© 2019 Trans Tech Publications Ltd. All Rights Reserved

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[1] Yakovlev A.D. Chemistry and Technology of Coatings. HIMIZDAT, Saint Petersburg, (2008).

Google Scholar

[2] Ermilov P.I., Indeikin E.A., Tolmachev I.A. Pigments and Pigmented Coating Materials. Chimia, Leningrad, (1987).

Google Scholar

[3] Ogurtsov N.A, Shapoval G.S, Catalytic Effect of Polyaniline for Anticorrosion Protection of Mild Steel // Catalysis and Petrochemistry 9–10 (2001) 5-12.

Google Scholar

[4] Kinlen P.J., Ding Y, Silverman D.C. Corrosion Protection of Mild Steel Using Sulfonic and Phosphonic Acid-Doped Polyanilines // Corrosion 58 (2002) 490-497.

DOI: 10.5006/1.3277639

Google Scholar

[5] Kurbatov, VG, Ilyin, АA, Indeikin, EA, Anticorrosive Properties of Polyaniline Doped by Various Acids., Russian Coating Journal, (8) 34-36 (2010).

Google Scholar

[6] Kurbatov V.G., Ilyin А.A., Indeikin E.A. Influence of the Additive of Polyaniline on Anticorrosive Properties of Epoxy Coatings // Russian Coating Journal 8 (2011) 47-49.

Google Scholar

[7] Vesely D., Kalendova A., Sapurina I., Stejskal J., Kalenda P., Corrosion-Inhibition Properties of Organic Coatings with a Polyaniline Phosphate // In book 8th International conference «Advances in coatings technology»: Conference papers, (2008).

DOI: 10.1179/143307509x440578

Google Scholar

[8] Akbarinezhad E., Ebrahimi M., Faridi H.R., Corrosion Inhibition of Steel in Sodium Chloride Solution by Undoped Polyaniline Epoxy Blend Coating // Prog. Org. Coat. 64 (2009) 361-364.

DOI: 10.1016/j.porgcoat.2008.07.018

Google Scholar

[9] Armelin. E., Aleman C.,. Iribarren J.I. Anticorrosion Performances of Epoxy Coatings Modified with Polyaniline: A Comparison Between the Emeraldine Base and Salt Forms // Prog. Org. Coat. 65 (2009) 88 – 93.

DOI: 10.1016/j.porgcoat.2008.10.001

Google Scholar

[10] Kurbatov V., Ilyin А., Indeikin E.A. Physical-Mechanical Properties of Epoxy Coatings Modified by Polyaniline // Polymers Paint Colour J., 202 (2012) 44–45.

Google Scholar

[11] Gorlovskyi I.A., Indeikin E.A., Tolmachev I.A, Laboratory Workshop on Pigments and Pigmented Coating Materials. Chimia, Leningrd, 1990.).

Google Scholar

[12] Karyakina M.I. The Test Paints and Coatings. Chimia, Moskow, (1998).

Google Scholar

[13] Kurbatov V.G., Indeikin E.A. Influence of the Polyaniline Structure on the Properties of Epoxy Compounds and Materials // Russian Journal of Applied Chemistry 87 (2015) 138–142.

DOI: 10.1134/s1070427215010206

Google Scholar