Kinetics Study Using Solvent-Free Microwave Extraction of Essential Oil from Allium sativum L.

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Extraction of Allium sativum L. using Solvent-Free Microwave Extraction (SFME) without the addition of solvents in the process has been carried out. SFME is an alternative technique and method to produce essential oil and it has several advantages in terms of product quality. In this study, the essential oil was extracted from Allium sativum used extraction time from 10 to 90 min and microwave power in the range of 300-600 W. The result showed that SFME could produce the highest yield of 0.2636 g oil/100 g fresh garlic at 450 W and 90 min. In addition, the kinetic study of SFME model appears to be the best fit to explain with second-order than first-order model. It was proved by a good correlation between the experimental data and model achieved (R2>0.99) and (RMSE=0.0021). Based on the results obtained, second-order kinetic models could actually describe the kinetics model of extraction process from Allium sativum L. using SFME.

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186-192

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April 2020

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© 2020 Trans Tech Publications Ltd. All Rights Reserved

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[1] S.H. Omar, N. A. Al-Wabel, Organosulfur compounds and possible mechanism of garlic in cancer, Saudi Pharm. J. 18 (2010) 51–58.

DOI: 10.1016/j.jsps.2009.12.007

Google Scholar

[2] J.M. Del Valle, C. Mena, M. Budinich, Extraction of garlic with supercritical CO2 and conventional organic solvents, Braz. J. Chem. Eng. 25 (2008) 535–542.

DOI: 10.1590/s0104-66322008000300011

Google Scholar

[3] F. Li, Q. Li, S. Wu, Z. Tan, Salting-out extraction of allicin from garlic (Allium sativum L.) based on ethanol/ammonium sulfate in laboratory and pilot scale, Food Chem. 217 (2017) 91–97.

DOI: 10.1016/j.foodchem.2016.08.092

Google Scholar

[4] M.T. Golmakani, M. Moayyedi, Comparison of heat and mass transfer of different microwave-assisted extraction methods of essential oil from Citrus limon (Lisbon variety) peel, Food Sci. Nutr. 3 (2015) 506–518.

DOI: 10.1002/fsn3.240

Google Scholar

[5] A. Bucić-Kojić, M. Planinić, S. Tomas, M. Bilić, D. Velić, Study of solid-liquid extraction kinetics of total polyphenols from grape seeds, J. Food Eng. 81 (2007) 236–242.

DOI: 10.1016/j.jfoodeng.2006.10.027

Google Scholar

[6] A. Farhat, A.S. Fabiano-Tixier, F. Visinoni, M. Romdhane, F. Chemat, A surprising method for green extraction of essential oil from dry spices: Microwave dry-diffusion and gravity, J. Chromatogr. A. 1217 (2010) 7345–7350.

DOI: 10.1016/j.chroma.2010.09.062

Google Scholar

[7] S. Lagergren, About the theory of so-called adsorption of soluble substances, K. Sven. Vetenskapsakademiens Handl. 24 (1898) 1–39.

Google Scholar

[8] Z. Reddad, C. Gerente, Y. Andres, P. Le Cloirec, Adsorption of several metal ions onto a low-cost biosorbent: kinetic and equilibrium studies, Environ. Sci. Technol. 36 (2002) 2067–(2073).

DOI: 10.1021/es0102989

Google Scholar

[9] Y.S. Ho, Citation review of Lagergren kinetic rate equation on adsorption reactions, Scientometrics 59 (2004) 171–177.

DOI: 10.1023/b:scie.0000013305.99473.cf

Google Scholar

[10] Y.S. Ho, H.A. Harouna-Oumarou, H. Fauduet, C. Porte, Kinetics and model building of leaching of water-soluble compounds of Tilia sapwood, Sep. Purif. Technol. 45 (2005) 169–173.

DOI: 10.1016/j.seppur.2005.03.007

Google Scholar

[11] A.C. Kimbaris, N.G. Siatis, D.J. Daferera, P.A. Tarantilis, C.S. Pappas, M.G. Polissiou, Comparison of distillation and ultrasound-assisted extraction methods for the isolation of sensitive aroma compounds from garlic ( Allium sativum ), Ultrason. Sonochem. 13 (2006) 54–60.

DOI: 10.1016/j.ultsonch.2004.12.003

Google Scholar

[12] L. Wang, C.L. Weller, Recent advances in extraction of nutraceuticals from plants, Trends Food Sci. Technol. 17 (2006) 300–312.

DOI: 10.1016/j.tifs.2005.12.004

Google Scholar

[13] Z. Hu, M. Cai, H.H. Liang, Desirability function approach for the optimization of microwave-assisted extraction of saikosaponins from Radix Bupleuri, Sep. Purif. Technol. 61 (2008) 266–275.

DOI: 10.1016/j.seppur.2007.10.016

Google Scholar

[14] S. Périno-Issartier, Zill-e-Huma, M. Abert-Vian, F. Chemat, Solvent Free Microwave-Assisted Extraction of Antioxidants from Sea Buckthorn (Hippophae rhamnoides) Food By-Products, Food Bioprocess Technol. 4 (2011) 1020–1028.

DOI: 10.1007/s11947-010-0438-x

Google Scholar

[15] M. Boukroufa, C. Boutekedjiret, L. Petigny, N. Rakotomanomana, F. Chemat, Bio-refinery of orange peels waste: A new concept based on integrated green and solvent free extraction processes using ultrasound and microwave techniques to obtain essential oil, polyphenols and pectin, Ultrason Sonochem. 24 (2015) 72–79.

DOI: 10.1016/j.ultsonch.2014.11.015

Google Scholar

[16] D.M. Patil, K.G. Akamanchi, Ultrasound-assisted rapid extraction and kinetic modelling of influential factors: Extraction of camptothecin from Nothapodytes nimmoniana plant. Ultrason Sonochem. 37 (2017) 582-591.

DOI: 10.1016/j.ultsonch.2017.02.015

Google Scholar

[17] M. Vinatoru, An overview of the ultrasonically assisted extraction of bioactive principles from herbs, Ultrason Sonochem. 8 (2001) 303–313.

DOI: 10.1016/s1350-4177(01)00071-2

Google Scholar