Effect of TBPF Microencapsulated Ammonium Polyphosphate on the Properties of Thermoplastic Polyurethane Elastomer

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Abstract:

In our previous work, ammonium polyphosphate (APP) microcapsule with the shell of boron modified phenolic resin (BPF) was prepared, recorded as BPFAPP. However, the compatibility and the flame retardancy of BPFAPP in thermoplastic polyurethane elastomer (TPU) are still not very good due to the brittle and hard shell wall. To improve the brittleness of microcapsules shell and the property reinforcements of APP in TPU, APP was encapsulated with the tung oil and boron modified phenolic resin (TBPF) in this paper, recorded as TBPFAPP. The property reinforcements of TBPFAPP in TPU were studied. The thermogravimetry, limiting oxygen index and cone calorimetry analysis showed that TPU/TBPFAPP composite had higher char yield and better flame resistance. The tensile strength and elongation at break showed that the mechanical properties were also significantly improved due to the introduction of α-Eleostearate.

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16-21

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May 2020

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© 2020 Trans Tech Publications Ltd. All Rights Reserved

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[1] Y. Zheng, W.Z. Wang and P. Leng: Chin. J. Chem. Edu. Vol. 4(2003), p.3.

Google Scholar

[2] K.M. Zhao: Master Thesis,University of Science and Technology of China, Hefei, (2011).

Google Scholar

[3] C.C. Zhu, H.Y. Wen, G.H. Lv and J.L. Zhang: The 16th Annual Conference of China Polyurethane Industry Association, Luoyang China, July 9-12, (2012).

Google Scholar

[4] W.E. Khatib, B. Youssef, C. Bunel and B. Mortaigne: Polym. Int. Vol. 52(1) (2003), p.146.

Google Scholar

[5] H. Chen, Y.J. Luo, C.P. Chai, J. Wang, J. Li and M. Xia: J. Appl. Polym. Sci. Vol. 110(5)(2008), p.3107.

Google Scholar

[6] J.X. Ni, L.J. Chen, K.M. Zhao, Y. Hu and L. Song: Polym. Adv. Technol. Vol. 22(2011), p.1824.

Google Scholar

[7] L. Sun, Y. Qu and S. Li: Polym. Degrad. Stab. Vol. 97 (2012), p.404.

Google Scholar

[8] K. Wu, L. Song, Z.Z. Wang and Y. Hu: J. Polym. Res. Vol. 16( 2009), p.283.

Google Scholar

[9] K. Wu, Y.K. Zhang W.G. Hu,J.T. Lian and Y. Hu:Compos. Sci. Technol. Vol. 81(2013), p.17.

Google Scholar

[10] B.B. Wang, X.F. Wang, G. Tang, Y.Q. Shi, Z.W. Hu, H.D. Lu, L. Song and Y. Hu: Compos. Sci. Technol. Vol. 72(2012), p.1042.

Google Scholar

[11] Y. Zhang, B.B. Wang, H.B. Sheng, B.H. Yuan, B. Yu, G. Tang, G.X. Jie, H. Feng, Y.J. Tao and Y. Hu: RSC. Adv. Vol. 6(2016), p.85564.

Google Scholar

[12] W.Y. Gao, S.J. Wang, F.B. Meng, Y.H. Wang and H.Q. Ma: J. Appl. Polym. Sci. Vol. 133(30)(2016), p.43720(1-8).

Google Scholar

[13] J.G. Gao, Y. Liu and F. Wang:Eur. Polym. J. Vol.37(2001), p.207.

Google Scholar

[14] J.G. Gao, L.Y. Xia and Y. Liu: Polym. Degrad. Stab. Vol.83(2004), p.71.

Google Scholar

[15] Y.F. Liu, J.G. Gao and R.Z. Zhang: Polym. Degrad. Stab. Vol.77(2002), p.495.

Google Scholar

[16] A.M. Kawamoto, L.C. Pardini, M.F. Diniz, V.L. Lourenço and M.F.K. Takahashi: J. Aerosp. Technol. Manag. Vol.2 (2)(2010), p.169.

Google Scholar

[17] M.L. Wang, Y.K. Zhou, Y. Li, L.H. Zeng and Z.B. Wang: Fine. Chem. Vol.21(6)(2004), p.477.

Google Scholar

[18] Z.B. Wang, Y.K. Zhou, L. Zhao and M.L. Wang: J. Guizhou. Univ. Technol. Vol.34(1)(2005), p.48.

Google Scholar

[19] G. Yu, P.S. Lu, Y. Wang and H. Yin: Chem. Ind. Forest. Prod. Vol.14(1994), p.23.

Google Scholar

[20] Y. Li, M.L. Wang and Y.K. Zhou: Chin. J. Guangdong. Chem. Vol.37(6)(2010),p.5.

Google Scholar

[21] Q. Wang: Master Thesis, Jilin University, Changchun, (2008).

Google Scholar