Investigation of Polymer/OMMT Nanocomposites-Influence Factor and Mechanism of Substructure Morphology

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By mechanical blending method or melt extrusion method, several kinds of poymers and OMMT were selected with different mixing progress and conditions, and several polymer/OMMT nanocomposites with different substructure morphology were prepared. The properties of polymer/OMMT nanocomposites were investigated. Firstly, several types of OMMT were prepared with different layer spacing, the results of XRD and TEM showed that the OMMT with larger layer spacing would form exfoliation nanocomposites, and then the schemes explained the mechanism. The polyethylene (such as LDPE, HDPE, LLDPE) composited with the same OMMT indicated the influence of different molecular chain structure. Different morphology of PP/OMMT and EPDM/OMMT nano-composites were discussed to find the relationship of shear force effecting structure.

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89-97

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July 2020

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© 2020 Trans Tech Publications Ltd. All Rights Reserved

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[1] Fukushima.Y, S. Inagaki. Synthesis of an Intercalated Compound of Montmorillonite And 6-polyamide, J. J Inclusion Phenomenology. 15(1987)473-482.

DOI: 10.1007/bf00664105

Google Scholar

[2] Lichao Xia, Hong Wu, Shaoyun Guo. Preparation and Sound Insulation Property of LDPE / OMMT Composites, J. Polymer Materials Science & Engineering. 32(2016)119-123.

Google Scholar

[3] Kim M S, Yan J, Kang K M, et al. Soundproofing properties of polypropylene/clay/carbon nanotube nanocomposites, J. Appl. Polym. Sci. 130(2013)504-509.

DOI: 10.1002/app.39194

Google Scholar

[4] Yan J, Kim M S, Kang K M, et al. Evaluation of PP/clay composites as soundproofing material, J. Polym. Polym. Compos. 22(2014)65-72.

Google Scholar

[5] Tiwen Xu, Yihui Zhang, Yuanxi Zhang, Jianfeng Ban, Liwang Jiang, Bo Shi. Properties of styrene-butadiene rubber/montmorillonite composites modified by butadiene-vinylpyridine rubber, J. China Synthetic Rubber Industry. 42(2019)209-213.

DOI: 10.1016/j.matchemphys.2019.04.005

Google Scholar

[6] Chen Xue, Jiafeng Shen, Xiaohui Wu, Haigang Wang, Baoqing Wang, Yiqing Wang. Structure and properties of vinyl-pyridine styrene butadiene rubber/montmorillonite composites prepared by latex co-coagulating method, J. China Synthetic Rubber Industry. 41(2018)224-229.

DOI: 10.1002/pc.24270

Google Scholar

[7] Zezhen Wang, Linlin Qi, Zhaohui Chen, Qigang Deng. Preparation and application of phosphorous intumescent organic montmorillonite composites, J. Dyeing and Finishing. 17(2018)1-5.

Google Scholar

[8] L Z Zuo, W Fan, Y F Zhang, et al. Graphene/montmorillonite hybrid synergistically reinforced polyimide composite aerogels with enhanced flame retardant performance, J. Composites Science and Technology. 139(2017)57-63.

DOI: 10.1016/j.compscitech.2016.12.008

Google Scholar

[9] Chenmin Liu, Yilan You, Jiayang Dai, Guangtie Deng. Properties of PA6/OMMT Composite, J. Journal of Hunan City University:Natural Science. 26(2017)76-78.

Google Scholar

[10] Peiyao Li, Guojun Song, et al. New Toughened Polypropylene/Organophilic Montmorillonite Nanocomposites, J. Appl Polym Sci. 108(2008)2116-2121.

DOI: 10.1002/app.27753

Google Scholar

[11] Zhenbin Gao, Zheng Gu, Guojun Song, Peiyao Li, Lianzhong Zhou. The Structure and Properties of HDPE/LLDPE/OMMT Nanocomposite, J. Plastics. 40(2011)11-13.

Google Scholar

[12] Peiyao Li, Lanlan Yin, Guojun Song, et al. High-performance EPDM/Organoclay Nanocomposites by Melt Extrusion, J. Appl Clay Sci. 40(2008)38-44.

DOI: 10.1016/j.clay.2007.07.002

Google Scholar

[13] Peiyao Li, Li Wang, Guojun Song, et al. Characterization of High-performance Exfoliated Natural Rubber/Organoclay Nanocomposites, J. Appl. Polym. Sci. 109(2008)3831-3838.

DOI: 10.1002/app.28480

Google Scholar

[14] Peiyao Li, Guojun Song, Xiaoyu Yang, Li Wang, Zheng Gu, Shujing Yang. Preparation and properties of bromobutyl rubber/organophilic montmorillonite nanocomposites, J. Modern Chemical Industry. 30(2010)59-61.

Google Scholar

[15] Changdong Zhang, Li Wang, Guojun Song, Peiyao Li, Hailong Wang, Liangdong Sun. Structure and properties of nitrile rubber/polyvinyl chloride/organic montmorillonite nanocomposites prepared by mechanical blending, J. China Synthetic Rubber Industry. 32(2009)127-130.

Google Scholar

[16] Peiyao Li, Guojun Song, Liangdong Sun, Li Wang, Xiaoyu Yang, Zhenbin Gao. Investigation of properties of NR/SBR/OMMT nanocomposites, J. Chemical Industry and Engineering Progress. 28(2009)1222-1225.

Google Scholar