The Ternary Blends of TPS/PBAT/PLA Films: A Study on the Morphological and Mechanical Properties

Article Preview

Abstract:

This study investigated the effect of polylactic acid (PLA) on the mechanical properties and biodegradability of a ternary blend comprising of thermoplastic starch (TPS), Polybutylene adipate terephthalate (PBAT) and PLA. The binary blend (TPS/PBAT) and ternary blend (TPS/PBAT/PLA) with various contents of PLA were prepared through a twin-screw compounding using an intensive mixing screw design. In order to observe the microstructure in blends, the SEM observation revealed the two types of morphology in the blends including (1) some TPS domain that still remained immiscible in all blends and (2) the partially compatible of binary and ternary blends. For the mechanical properties of the blends, the addition of the PLA component led to an improvement of the tensile strength and modulus. For the simple soil burial test, it found that binary film was fully disintegrated within one month, whereas the ternary blend films were also broken down but still remained in small pieces of fragile films. Finally, it can be suggested that the presence of TPS brought to the biodegradation of blends in soil burial test, while incorporating with PLA led to retardation in degradation rate.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

170-175

Citation:

Online since:

September 2020

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2020 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] R. J. Zdrahala, Thermoplastic starch revisited. Structure/property relationship for dialed-in, biodegradability, Macromolecular Symposia, 123 (1997) 113–121.

DOI: 10.1002/masy.19971230112

Google Scholar

[2] H. L. Abd El-Mohdy, E. A. Hegazy, E. M. El-Nesr, and M. A. El-Wahab, Synthesis, characterization and properties of radiation-induced Starch/(EG-co-MAA) hydrogels, Arabian Journal of Chemistry, 9 (2006) S1627–S1635.

DOI: 10.1016/j.arabjc.2012.04.022

Google Scholar

[3] E. Chabrat, H. Abdillahi, A. Rouilly, and L. Rigal, Influence of citric acid and water on thermoplastic wheat flour/poly(lactic acid) blends. I: Thermal, mechanical and morphological properties, Industrial Crops and Products, 37 (2012) 238–246.

DOI: 10.1016/j.indcrop.2011.11.034

Google Scholar

[4] S. Li, J. Xia, Y. Xu, X. Yang, W. Mao, and K. Huang, Preparation and characterization of acorn starch/poly(lactic acid) composites modified with functionalized vegetable oil derivates, Carbohydrate Polymers, 142 (2006) 250–258.

DOI: 10.1016/j.carbpol.2016.01.031

Google Scholar

[5] T. Ke, S. X. Sun, and P. Seib, Blending of poly(lactic acid) and starches containing varying amylose content, Journal of Applied Polymer Science, 89 (2003) 3639–3646.

DOI: 10.1002/app.12617

Google Scholar

[6] D. L. M. Costa, Produção por extrusão de filmes de alto teor de amido termoplástico com poli (butileno adipato co-tereftalato) (PBAT). Dissertação de Mestrado (Mestrado em Ciência de Alimentos). Universidade Estadual de Londrina, Londrina. (2008).

DOI: 10.47749/t/unicamp.2019.1129409

Google Scholar

[7] J. Ren, H. Fu, T. Ren, and W. Yuan, Preparation, characterization and properties of binary and ternary blends with thermoplastic starch, poly(lactic acid) and poly(butylene adipate-co-terephthalate), Carbohydrate Polymers, 77 (2009) 576–582.

DOI: 10.1016/j.carbpol.2009.01.024

Google Scholar

[8] M. A. Shirai, J. B. Olivato, P. S. Garcia, C. M. O. Müller, M. V. E. Grossmann, and F. Yamashita, Thermoplastic starch/polyester films: Effects of extrusion process and poly (lactic acid) addition, Materials Science and Engineering: C, 33 (2013) 4112–4117.

DOI: 10.1016/j.msec.2013.05.054

Google Scholar

[9] W. Phetwarotai and D. Aht-Ong, Reactive Compatibilization of Polylactide, Thermoplastic Starch and Poly(butylene adipate-co-terephthalate) Biodegradable Ternary Blend Films, Materials Science Forum, 695 (2011) 178–181.

DOI: 10.4028/www.scientific.net/msf.695.178

Google Scholar

[10] I. Bher, Uysal Unalan, R. Auras, M. Rubino, and C. Schvezov, Toughening of Poly(lactic acid) and Thermoplastic Cassava Starch Reactive Blends Using Graphene Nanoplatelets, Polymers, 10 (2018) 95.

DOI: 10.3390/polym10010095

Google Scholar

[11] A. Winotapun et al., Development of multilayer films with improved aroma barrier properties for durian packaging application, Packaging Technology and Science, 32 (2019) 405–418.

DOI: 10.1002/pts.2452

Google Scholar

[12] V. M. Pathak and Navneet, Review on the current status of polymer degradation: a microbial approach, Bioresources and Bioprocessing, 4. (2017).

DOI: 10.1186/s40643-017-0145-9

Google Scholar