Effect of Zeolite on Mechanical and Barrier Properties of PBAT Films for Life Extension of Agricultural Products

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In this research, the biodegradable film of poly (butylene adipate-co-terephthalate) (PBAT) would be used as the polymer matrix. The influence of zeolite (as the filler) type and content were investigated on the mechanical and barrier properties of film packaging. Zeolite was treated with (3-aminopropyl) trimethoxy silane. Films were produced by cast film extruder. Effects of different types of zeolite (5A and 13X) as well as zeolite loading (1-5 wt%) on mechanical properties and permeability of gases (oxygen, carbon dioxide and water vapor) of PBAT composites films have been extensively studied. Tensile properties of PBAT incorporated with zelolite 5A are higher than the one with zeolite 13X. In addition, increasing zeolite content into PBAT film is likely to improve Young’s modulus with the sacrifices of both tensile strength and percentage of elongation at break of PBAT film. For barrier properties, PBAT/zeolite 5A possessed lower permeation both of oxygen and carbon dioxide gases than PBAT/zeolite 13X. The effect of zeolite content plays a major role on oxygen and carbon dioxide permeability of composite films. PBAT/zeolite composite film could certainly extend the ripening period of Homthong bananas for approximately longer than one week.

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176-181

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September 2020

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© 2020 Trans Tech Publications Ltd. All Rights Reserved

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[1] Information on http://dataservices.mof.go.th/Dataservices/IETopExport.

Google Scholar

[2] S. Phattarateera, P. Threepopnatkul, C. Kulsetthanchalee, Comparative performance of coupling agent and compatibilizer on polystylene/zeolite composites, Chiang Mai J. Sci. 40 (2013) 1035-1045.

Google Scholar

[3] B.P. Chang, H.M. Akil, R.M. Nasir, Mechanical and tribological properties of zeolite-reinforced UHMWPE composite for implant application, Procedia Eng. 68 (2013) 88-94.

DOI: 10.1016/j.proeng.2013.12.152

Google Scholar

[4] D.A. Kajtár, C. Kenyó, Interfacial interactions and reinforcement in thermoplastics/zeolite composites, Compos. Part B-Eng. 114 (2017) 386-394.

DOI: 10.1016/j.compositesb.2016.12.015

Google Scholar

[5] P. Threepopnatkul, K. Wongsuton, C. Jaiaue, N. Rakkietwinai and C. Kulsetthanchalee, Thermal and barrier properties of poly(butylene adipate-co-terephthalate) incorporated with zeolite doped potassium ion for packaging film, IOP Conf. Ser. Mater. Sci. Eng. 773 (2020) 012042.

DOI: 10.1088/1757-899x/773/1/012042

Google Scholar

[6] P.R.C. Correia, I.G. Ramos, A.C. Viana, A.J.S. Mascarenhas, A.E.G. Santana, H.F. Goulart, J.I. Druzian, Development of composite membrane PBAT: Zeolite Y for application as rhynchophorol release system. J. Appl. Polym. Sci. 135 (2017) 45757.

DOI: 10.1002/app.45757

Google Scholar

[7] B. Dounia, B. Abdelkader, G. Yves, K. Hamid, New nanocomposite design from zeolite and poly(lactic acid). Ind. Crops Prod. 72 (2015) 107-118.

Google Scholar

[8] Y. Li, H-M. Guan, T-S. Chung and S. Kulprathipanja, Effects of novel silanemodification of zeolite surface on polymer chain rigidification and partial poreblockage in polyethersulfone (PES)–zeolite A mixed matrix membranes, J. Membr. Sci., 275 (2006) 17-28.

DOI: 10.1016/j.memsci.2005.08.015

Google Scholar

[9] K.-M. Kim, H-T. Oh, S-J. Lim, K. Ho, Y. Park, C-H. Lee, Adsorption Equilibria of Water Vapor on Zeolite 3A, Zeolite 13X, and Dealuminated Y Zeolite. J. Chem. Eng. Data, 61 (2016) 1547–1554.

DOI: 10.1021/acs.jced.5b00927

Google Scholar