Photopolymerization of OCDMA Dimetacrylate Initiated by 3,5-Di-tert-Butyl-o- Quinone and its Bis-O-Benzoquinone

Elnara Zhiganshina; Maxim Arsenyev; Alexey Konev; Yuri Chechet; Sergey Chesnokov

doi:10.4028/www.scientific.net/KEM.869.129

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HomeKey Engineering MaterialsKey Engineering Materials Vol. 869Photopolymerization of OCDMA Dimetacrylate...

Photopolymerization of OCDMA Dimetacrylate Initiated by 3,5-Di-tert-Butyl-o- Quinone and its Bis-O-Benzoquinone

Abstract:

The reactivity of 3,5-di-tert-butyl-o-benzoquinone and its bis-o-benzoquinone derivative in photoreduction reaction and polymerization of dimethacrylate (OCDMA) (in bulk and in the presence of 1-butanol) with using of them as photoinitiators under visible light irradiation under argon atmosphere or air were investigated. It was found that the kinetic parameters of the bis-o-quinone photoreactions have low sensitive to the presence of molecular oxygen. The high stability of the spectral characteristics of resulting polymers based on bis-o-quinones compositions for the long time was established.

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Key Engineering Materials (Volume 869)

Pages:

129-134

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.869.129

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Online since:

October 2020

Authors:

Elnara Zhiganshina*, Maxim Arsenyev, Alexey Konev, Yuri Chechet, Sergey Chesnokov

Keywords:

Dimethacrylate, Photoinitiator, Photopolymerization, Photoreduction, Quinone, Visible Radiation

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