Optimization of the Reaction of Catalytic Cycloalkylation of Phenol with Cyclohexene

Irada I. Alekperova; Zaur Z. Aghamaliyev; Firuza M. Veliyeva; Chingiz K. Rasulov

doi:10.4028/www.scientific.net/KEM.869.82

Paper Titles

Concerning the Application Possibility of Ultrasonic Welding of Textile Materials on the Basis of Synthetic Fibres in the Manufacturing Processes of Parachute Systems
p.56

Exploring the Complexation of Counterion in Novel Family of Polyelectrolytes with Unexpected Solubility Behaviour
p.61

Infrared Spectrum and Thermal Properties of LDPE, EVA and Fly Ash Composites
p.69

Morphology and Mechanical Properties of LDPE, EVA and Fly Ash Composites
p.76

Optimization of the Reaction of Catalytic Cycloalkylation of Phenol with Cyclohexene
p.82

Application of Adhesives in Cosmetology
p.88

Sealing Materials Based on Polymers
p.93

Medical Nonwovens: Effects of Radiation Sterilization on Bursting Strength
p.101

Obtaining Nanofibers Na-CMC in Mechanomagnetic Activated Water Solution for the Purpose of Reinforcing Concrete Structure
p.107

HomeKey Engineering MaterialsKey Engineering Materials Vol. 869Optimization of the Reaction of Catalytic...

Optimization of the Reaction of Catalytic Cycloalkylation of Phenol with Cyclohexene

Abstract:

The paper presents the results of studies of the reaction of the interaction of phenol with cyclohexene (CH) in the presence of a Zeolite-Y catalyst impregnated with phosphoric acid and studying the dependence on the yield and selectivity of the target product on various parameters. As a result of the study of the phenol cycloalkylation by cyclohexene, optimal conditions were found, the yield of which is 81.6 % of theory for the taken CH, and the selectivity is 94.0 % for the target product. The developed mathematical model of the processes of the interaction of phenol with cyclohexene in the form of a regression polynomial made it possible to find the optimal values of the input variables.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Key Engineering Materials (Volume 869)

Pages:

82-87

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.869.82

Citation:

Cite this paper

Online since:

October 2020

Authors:

Irada I. Alekperova, Zaur Z. Aghamaliyev*, Firuza M. Veliyeva, Chingiz K. Rasulov

Keywords:

Catalyst, Cycloalkylation, Cyclohexene, Mathematical Model, Optimization Process, Para-Cyclohexylphenol, Phenol

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] V.G. Mirzayev, Z.Z. Agamaliyev, Ch.K. Rasulov, Some peculiarities of interaction reaction of phenol with the dimerization products of C4 fraction of gasoil pyrolysis, Global Journal of Chemistry. 3 (2017) 136-142.

Google Scholar

[2] T.N. Nesterova, D.A. Chernyshov, V.A. Shalkin, Sulfonic acid cation exchange resins in the synthesis of straight chain alkylphenols, Catalysis in Industry. 8 (2016) 16-22.

DOI: 10.1134/s2070050416010086

Google Scholar

[3] I.I. Alekperova, Z.Z. Agamaliyev, F.M. Veliyeva, Ch.K. Rasulov, Optimization of phenol cycloalkylation process with cyclohexene in the presence of catalyst KU-23, Processes of petrochemistry and oil refining. 20 (2019) 424-432.

DOI: 10.4028/www.scientific.net/kem.869.82

Google Scholar

[4] A.A. Sirota, Methods and algorithms for data analysis and their modeling in MATLAB: textbook. Allowance, Publishing house BHV-Petersburg,, St.-Petersburg, (2016).

Google Scholar

[5] J. Steimel, M. Harrmann, G. Schembecker, S. Engell, Model-based conceptual design and optimization tool support for the early stage development of chemical processes under uncertainty, Computers & Chemical Engineering. 59 (2013) 63-73.

DOI: 10.1016/j.compchemeng.2013.06.017

Google Scholar