Vulcanization of Elastomers with Quinol Ethers of P-Benzoquinone Dioxime

Oleg R. Klyuchnikov; Yaroslav O. Klyuchnikov

doi:10.4028/www.scientific.net/KEM.899.479

Paper Titles

Influence of Spinneret Dimensional Parameters on Gas Separation Properties of Polysulfone Hollow Fiber Membranes
p.451

New Express Method of Non-Destructive Controlling of the Porous Structure of Asymmetric Membranes
p.456

Electrophysical Parameters of Nanofilled Polymer Composites Based on Polyethylene
p.463

Features of the Polymethyl Methacrylate Destruction Process by Various Types of Dynamic Loading
p.473

Vulcanization of Elastomers with Quinol Ethers of P-Benzoquinone Dioxime
p.479

Analysis of Residual Stresses in a Polymer Cylinder when it is Stopped and then Cooled in a Nonlinear and Linearized Problem Settings
p.486

Composite Cerium Oxide Nanoparticles - Containing Polysaccharide Hydrogel as Effective Agent for Burn Wound Healing
p.493

Atomic Force Microscopy of the Local Electrical Properties of Bilayer Polyaniline-Polystyrene/P(VDF-TrFE) Composite
p.506

Strength Characteristics of 3D-Printed PETG-Based Products Optimization
p.512

HomeKey Engineering MaterialsKey Engineering Materials Vol. 899Vulcanization of Elastomers with Quinol Ethers of...

Vulcanization of Elastomers with Quinol Ethers of P-Benzoquinone Dioxime

Abstract:

The article discusses the synthesis and development of the direction of vulcanization of elastomers with quinol esters of p-benzoquinone dioxime. The concept of a critical temperature T_cr which denotes noticeability of the vulcanization process of unsaturated rubbers (with k=1×10^-6, s^-1) is introduced. Noted the increased vulcanizational activity of quinol esters of p-quinone dioxime after nitrosoarenes addition. The reactional ability of nitrosoarenes is proportional to estimated charge value on the oxygen of the nitroso group, with lgk= 11,3+49,7 qO. Quinol esters of p-quinone dioxime are proposed to create three-dimensional rubber paintings and prints.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Key Engineering Materials (Volume 899)

Pages:

479-485

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.899.479

Citation:

Cite this paper

Online since:

September 2021

Authors:

Oleg R. Klyuchnikov*, Yaroslav O. Klyuchnikov

Keywords:

Elastomer, Nitrosoarenes, Quinol Esters of P-Benzoquinone Dioxime, Volumetric Rubber Painting, Vulcanization Reactions

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] A. Zharkov, A. Yaskin. Pioneers of domestic rocketry. Biysky Vestnik. 4 (2013) 41. (Rus).

Google Scholar

[2] D.I. Dementyeva, I.S. Kononov, R.G. Mamashev, V.A. Kharitonov, Introduction to energy-rich materials technology: textbook, Biysk, Publishing house of Alt. stat. tech. un-ty, 2009, 254 P. (Rus).

Google Scholar

[3] A.V. Yaskin, Design and development of solid fuel rocket engines: a tutorial, Alt. stat. tech. un-ty, BTI, Biysk, Publishing house of Alt. stat. tech. un-ty, 2010, 200 P. (Rus).

Google Scholar

[4] B.M. Anikeev, Yu.N. Odintsov. Development at NII-9 SRTT, an industrial technology for the manufacture of charges from them and designs of charges for the cruise propulsion systems of strategic missiles 8K98, 8K98P. From the history of the domestic gunpowder industry: Creation of the first solid-fuel intercontinental missile. Moscow, TSNIINTIKPK, 1997, pp.81-87. (Rus).

Google Scholar

[5] B.V. Pevchenko, V.V. Sidorov, V.N. Mashkovtsev, A.A. Korchagin. Rus. Patent 2621789. Method for producing mixed firm rocket fuel. (2017) Bull. 16.

Google Scholar

[6] V.V. Zorik, V.F. Komarov, S.F. Zorik, G.V. Korolev. Quinolide esters - new vulcanizing agents of butyl rubber. Kauchuk i Rezina. 6 (1978) 15-19. (Rus).

Google Scholar

[7] E. Muller, L. Kurt. // Z. Naturforsch. 11 (1953) 694–695.

Google Scholar

[8] E. Muller, R. Mayer, B. Narr, A. Schick, K. Scheffler. Lieb. Ann. Chem., 1 (1961) 645.

Google Scholar

[9] Z.A. Dobronravova, L.G. Ardatova, E.V. Rudnev. USSR Patent 558907 (1977).

Google Scholar

[10] Z.A. Dobronravova, V.I. Meshcheryakov, Yu.E. Prishchenko, L.D. Gavrilov, L.I. Vereshchagin. Zhurnal Organicheskoi Khimii. 5 (1980) 1034-1039. (Rus).

Google Scholar

[11] I.B. Tsvetkovsky, A.B. Korennaya, N.V. Andreeva. Kauchuk i Rezina. 7 (1991) 11–15. (Rus).

Google Scholar

[12] O.R. Klyuchnikov, Ya.O. Klyuchnikov, I.O. Klyuchnikov, V.S. Klyuchnikova. Rus. Patent 2575652. Klyuchnikov(s) hardenable plasticine. (2016) Bull. 5.

Google Scholar