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Vulcanization of Elastomers with Quinol Ethers of P-Benzoquinone Dioxime

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Abstract:

The article discusses the synthesis and development of the direction of vulcanization of elastomers with quinol esters of p-benzoquinone dioxime. The concept of a critical temperature Tcr which denotes noticeability of the vulcanization process of unsaturated rubbers (with k=1×10-6, s-1) is introduced. Noted the increased vulcanizational activity of quinol esters of p-quinone dioxime after nitrosoarenes addition. The reactional ability of nitrosoarenes is proportional to estimated charge value on the oxygen of the nitroso group, with lgk= 11,3+49,7 qO. Quinol esters of p-quinone dioxime are proposed to create three-dimensional rubber paintings and prints.

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Periodical:

Key Engineering Materials (Volume 899)

Pages:

479-485

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.899.479

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Online since:

September 2021

Authors:

Oleg R. Klyuchnikov*, Yaroslav O. Klyuchnikov

Keywords:

Elastomer, Nitrosoarenes, Quinol Esters of P-Benzoquinone Dioxime, Volumetric Rubber Painting, Vulcanization Reactions

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© 2021 Trans Tech Publications Ltd. All Rights Reserved

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